GB1365589A - Epoxidation of unsaturated compounds - Google Patents
Epoxidation of unsaturated compoundsInfo
- Publication number
- GB1365589A GB1365589A GB743172A GB743172A GB1365589A GB 1365589 A GB1365589 A GB 1365589A GB 743172 A GB743172 A GB 743172A GB 743172 A GB743172 A GB 743172A GB 1365589 A GB1365589 A GB 1365589A
- Authority
- GB
- United Kingdom
- Prior art keywords
- epoxidized
- feb
- catalyst
- alkyl radical
- hydroperoxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title abstract 3
- 238000006735 epoxidation reaction Methods 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 3
- -1 organometallic chelate complex Chemical class 0.000 abstract 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 abstract 2
- 239000003446 ligand Substances 0.000 abstract 2
- 239000005725 8-Hydroxyquinoline Substances 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- SXKZKXJASFWSJA-UHFFFAOYSA-N N-(furan-2-ylmethyl)-N-phenylhydroxylamine Chemical compound C(C1=CC=CO1)N(O)C1=CC=CC=C1 SXKZKXJASFWSJA-UHFFFAOYSA-N 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- VDEUYMSGMPQMIK-UHFFFAOYSA-N benzhydroxamic acid Chemical compound ONC(=O)C1=CC=CC=C1 VDEUYMSGMPQMIK-UHFFFAOYSA-N 0.000 abstract 1
- 239000013522 chelant Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 abstract 1
- YLYIXDZITBMCIW-UHFFFAOYSA-N n-hydroxy-n-phenylbenzamide Chemical compound C=1C=CC=CC=1N(O)C(=O)C1=CC=CC=C1 YLYIXDZITBMCIW-UHFFFAOYSA-N 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- VVRQVWSVLMGPRN-UHFFFAOYSA-N oxotungsten Chemical class [W]=O VVRQVWSVLMGPRN-UHFFFAOYSA-N 0.000 abstract 1
- 229960003540 oxyquinoline Drugs 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 150000003222 pyridines Chemical class 0.000 abstract 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 229910001930 tungsten oxide Inorganic materials 0.000 abstract 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 abstract 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 abstract 1
- 229910001935 vanadium oxide Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
- B01J2231/72—Epoxidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/64—Molybdenum
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT2073571 | 1971-02-18 | ||
| IT2269071A IT984547B (it) | 1971-04-02 | 1971-04-02 | Perfezionamento ai sistemi catali tici selettivi per processi di epossidazione delle olefine con idroperossidi e relativi sistemi catalitici perfezionati |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1365589A true GB1365589A (en) | 1974-09-04 |
Family
ID=26327639
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB743172A Expired GB1365589A (en) | 1971-02-18 | 1972-02-17 | Epoxidation of unsaturated compounds |
Country Status (7)
| Country | Link |
|---|---|
| BE (1) | BE779477A (OSRAM) |
| DE (1) | DE2207506A1 (OSRAM) |
| FR (1) | FR2125327B1 (OSRAM) |
| GB (1) | GB1365589A (OSRAM) |
| LU (1) | LU64789A1 (OSRAM) |
| NL (1) | NL7202143A (OSRAM) |
| SU (1) | SU475767A3 (OSRAM) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0138624A3 (en) * | 1983-10-18 | 1985-06-26 | Bp Chemicals Limited | Organo metallic complexes and the use thereof in epoxidation of olefins |
| US5017712A (en) * | 1984-03-09 | 1991-05-21 | Arco Chemical Technology, Inc. | Production of hydrocarbon-soluble salts of molybdenum for epoxidation of olefins |
| PT107601A (pt) * | 2014-04-14 | 2015-10-14 | Cofac Cooperativa De Formação E Animação Cultural Crl | Oxo-complexos de vanádio(iv-v) com ligandos derivados de salicilaldeído-2-hidroxibenzoil-hidrazona e 8-hidroxiquinolina ou 1,10-fenantrolina e sua aplicação como catalisadores para a oxidação peroxidativa, assistida por micro-ondas e sem adição de solvente, de álcoois secundários a cetonas |
| CN111704633A (zh) * | 2020-07-08 | 2020-09-25 | 万华化学集团股份有限公司 | 一种Mo催化剂及其在制备9,10-环氧-1,5-环十二碳二烯中的应用 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8307976D0 (en) * | 1983-03-23 | 1983-04-27 | Bp Chem Int Ltd | Epoxidation of olefins |
-
1972
- 1972-02-08 FR FR7204106A patent/FR2125327B1/fr not_active Expired
- 1972-02-16 LU LU64789D patent/LU64789A1/xx unknown
- 1972-02-17 BE BE779477A patent/BE779477A/xx unknown
- 1972-02-17 DE DE19722207506 patent/DE2207506A1/de active Pending
- 1972-02-17 GB GB743172A patent/GB1365589A/en not_active Expired
- 1972-02-17 SU SU1747094A patent/SU475767A3/ru active
- 1972-02-18 NL NL7202143A patent/NL7202143A/xx unknown
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0138624A3 (en) * | 1983-10-18 | 1985-06-26 | Bp Chemicals Limited | Organo metallic complexes and the use thereof in epoxidation of olefins |
| US5017712A (en) * | 1984-03-09 | 1991-05-21 | Arco Chemical Technology, Inc. | Production of hydrocarbon-soluble salts of molybdenum for epoxidation of olefins |
| PT107601A (pt) * | 2014-04-14 | 2015-10-14 | Cofac Cooperativa De Formação E Animação Cultural Crl | Oxo-complexos de vanádio(iv-v) com ligandos derivados de salicilaldeído-2-hidroxibenzoil-hidrazona e 8-hidroxiquinolina ou 1,10-fenantrolina e sua aplicação como catalisadores para a oxidação peroxidativa, assistida por micro-ondas e sem adição de solvente, de álcoois secundários a cetonas |
| PT107601B (pt) * | 2014-04-14 | 2018-08-09 | Cofac Coop De Formacao E Animacao Cultural Crl | Oxo-complexo de vanádio(v) com ligandos 8-hidroxiquinolina e derivado de salicilaldeído-2-hidroxibenzoil-hidrazona e sua aplicação como catalisador para a oxidação peroxidativa, assistida por micro-ondas e sem adição de solvente, de álcoois secundários a cetonas |
| CN111704633A (zh) * | 2020-07-08 | 2020-09-25 | 万华化学集团股份有限公司 | 一种Mo催化剂及其在制备9,10-环氧-1,5-环十二碳二烯中的应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2207506A1 (de) | 1972-09-07 |
| FR2125327B1 (OSRAM) | 1974-06-28 |
| SU475767A3 (ru) | 1975-06-30 |
| LU64789A1 (OSRAM) | 1972-07-04 |
| NL7202143A (OSRAM) | 1972-08-22 |
| BE779477A (fr) | 1972-06-16 |
| FR2125327A1 (OSRAM) | 1972-09-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |