GB1365351A - Process for preparing vinyl acetate - Google Patents
Process for preparing vinyl acetateInfo
- Publication number
- GB1365351A GB1365351A GB4901771A GB4901771A GB1365351A GB 1365351 A GB1365351 A GB 1365351A GB 4901771 A GB4901771 A GB 4901771A GB 4901771 A GB4901771 A GB 4901771A GB 1365351 A GB1365351 A GB 1365351A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl acetate
- acetic acid
- pyrolysis
- oct
- prepared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
- C07C67/297—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1365351 Vinyl acetate HALCON INTERNATIONAL Inc 21 Oct 1971 [22 Oct 1970] 49017/71 Heading C2C Vinyl acetate is prepared by the vapour phase pyrolysis of ethylene glycol diacetate. The feedstock is passed at a mass velocity of at least 200 lbs./hr./sq. foot of pyrolysis zone cross-sectional area. A temperature of 435‹ to 560‹ C. with a residence time of between 0À1 and 200 seconds is used. The ethylene glycol diacetate is prepared by esterification or by the reaction of ethylene, oxygen and acetic acid in the presence of halogen in the presence of a metal cation such as tellurum, manganese, copper, cobalt or chromium. Catalysts such as activated alumina, vanadia, molybdena, magnesia, alkaline earth pyrophosphates, zinc oxide and cobalt molybdate may be present during the pyrolysis. By-product acetic acid and acetone can be separated and acetic acid may be recycled to the diacetate preparation.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US8322170A | 1970-10-22 | 1970-10-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1365351A true GB1365351A (en) | 1974-09-04 |
Family
ID=22176957
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4901771A Expired GB1365351A (en) | 1970-10-22 | 1971-10-21 | Process for preparing vinyl acetate |
Country Status (7)
Country | Link |
---|---|
JP (1) | JPS5729458B1 (en) |
BE (1) | BE774143A (en) |
DE (1) | DE2152788C3 (en) |
FR (1) | FR2109737A5 (en) |
GB (1) | GB1365351A (en) |
IT (1) | IT939576B (en) |
NL (1) | NL150097B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6992212B2 (en) | 2001-08-07 | 2006-01-31 | Basf Aktiengesellschaft | Felxible method for the common production of formic acid, a carboxylic acid having at least two carbon atoms, and/or the derivatives of the same |
-
1971
- 1971-09-06 FR FR7132076A patent/FR2109737A5/fr not_active Expired
- 1971-10-14 IT IT5347571A patent/IT939576B/en active
- 1971-10-15 NL NL7114196A patent/NL150097B/en not_active IP Right Cessation
- 1971-10-19 BE BE774143A patent/BE774143A/en unknown
- 1971-10-21 GB GB4901771A patent/GB1365351A/en not_active Expired
- 1971-10-22 DE DE19712152788 patent/DE2152788C3/en not_active Expired
- 1971-10-22 JP JP8387471A patent/JPS5729458B1/ja active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6992212B2 (en) | 2001-08-07 | 2006-01-31 | Basf Aktiengesellschaft | Felxible method for the common production of formic acid, a carboxylic acid having at least two carbon atoms, and/or the derivatives of the same |
Also Published As
Publication number | Publication date |
---|---|
IT939576B (en) | 1973-02-10 |
NL7114196A (en) | 1972-04-25 |
BE774143A (en) | 1972-04-19 |
DE2152788C3 (en) | 1980-07-10 |
JPS5729458B1 (en) | 1982-06-23 |
FR2109737A5 (en) | 1972-05-26 |
DE2152788A1 (en) | 1972-04-27 |
DE2152788B2 (en) | 1979-10-18 |
NL150097B (en) | 1976-07-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB1420058A (en) | Propylene oxide recovery | |
GB1373230A (en) | Process for producing terephthalic acid | |
GB1408640A (en) | Catalyst recycle | |
US3917682A (en) | Production of acetic acid by oxidation of butenes | |
GB1365351A (en) | Process for preparing vinyl acetate | |
US4010171A (en) | Process for preparing tetrahydrofuran | |
GB1423030A (en) | Process for producing dl-tartaric acid | |
US3373189A (en) | Vapor phase process for producing vinyl acetate from ethylene | |
US4011244A (en) | Process for preparing tetrahydrofuran | |
GB1343685A (en) | Process for preparing olefin oxides | |
US2881214A (en) | Process for the conversion of acrolein and methacrolein to the corresponding unsaturated acids | |
US3403177A (en) | Pretreatment of catalyst used in the production of acrylic acid and acrolein | |
UA8349A1 (en) | Process for preparation of terephthalic acid | |
US2846468A (en) | Recovery of terephthalic acid | |
GB1015003A (en) | Production of ketones | |
GB1189091A (en) | Process for the Manufacture of Carboxylic Acids and Unsaturated Esters of Carboxylic Acids | |
GB1266391A (en) | ||
GB1179905A (en) | Process for the production of acetic acid. | |
GB1382278A (en) | Treatment of terephthalic acid reaction products | |
GB1165442A (en) | Process for the Production of Acetic Acid by Catalytic Gas Phase Oxidation of Butenes | |
US3960971A (en) | Process for preparing allylic alcohols | |
US3642907A (en) | Acetonylacetone and para-cresol by oxidation of methacrolein dimer | |
GB1248010A (en) | Process for preparing vinyl acetate | |
GB1249571A (en) | Process for the preparation of p-tert. butylphenol | |
GB1354561A (en) | Polyester preparation |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
PCNP | Patent ceased through non-payment of renewal fee |