GB1365351A - Process for preparing vinyl acetate - Google Patents

Process for preparing vinyl acetate

Info

Publication number
GB1365351A
GB1365351A GB4901771A GB4901771A GB1365351A GB 1365351 A GB1365351 A GB 1365351A GB 4901771 A GB4901771 A GB 4901771A GB 4901771 A GB4901771 A GB 4901771A GB 1365351 A GB1365351 A GB 1365351A
Authority
GB
United Kingdom
Prior art keywords
vinyl acetate
acetic acid
pyrolysis
oct
prepared
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4901771A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Halcon International Inc
Original Assignee
Halcon International Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Halcon International Inc filed Critical Halcon International Inc
Publication of GB1365351A publication Critical patent/GB1365351A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/28Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/297Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1365351 Vinyl acetate HALCON INTERNATIONAL Inc 21 Oct 1971 [22 Oct 1970] 49017/71 Heading C2C Vinyl acetate is prepared by the vapour phase pyrolysis of ethylene glycol diacetate. The feedstock is passed at a mass velocity of at least 200 lbs./hr./sq. foot of pyrolysis zone cross-sectional area. A temperature of 435‹ to 560‹ C. with a residence time of between 0À1 and 200 seconds is used. The ethylene glycol diacetate is prepared by esterification or by the reaction of ethylene, oxygen and acetic acid in the presence of halogen in the presence of a metal cation such as tellurum, manganese, copper, cobalt or chromium. Catalysts such as activated alumina, vanadia, molybdena, magnesia, alkaline earth pyrophosphates, zinc oxide and cobalt molybdate may be present during the pyrolysis. By-product acetic acid and acetone can be separated and acetic acid may be recycled to the diacetate preparation.
GB4901771A 1970-10-22 1971-10-21 Process for preparing vinyl acetate Expired GB1365351A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US8322170A 1970-10-22 1970-10-22

Publications (1)

Publication Number Publication Date
GB1365351A true GB1365351A (en) 1974-09-04

Family

ID=22176957

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4901771A Expired GB1365351A (en) 1970-10-22 1971-10-21 Process for preparing vinyl acetate

Country Status (7)

Country Link
JP (1) JPS5729458B1 (en)
BE (1) BE774143A (en)
DE (1) DE2152788C3 (en)
FR (1) FR2109737A5 (en)
GB (1) GB1365351A (en)
IT (1) IT939576B (en)
NL (1) NL150097B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6992212B2 (en) 2001-08-07 2006-01-31 Basf Aktiengesellschaft Felxible method for the common production of formic acid, a carboxylic acid having at least two carbon atoms, and/or the derivatives of the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6992212B2 (en) 2001-08-07 2006-01-31 Basf Aktiengesellschaft Felxible method for the common production of formic acid, a carboxylic acid having at least two carbon atoms, and/or the derivatives of the same

Also Published As

Publication number Publication date
IT939576B (en) 1973-02-10
NL7114196A (en) 1972-04-25
BE774143A (en) 1972-04-19
DE2152788C3 (en) 1980-07-10
JPS5729458B1 (en) 1982-06-23
FR2109737A5 (en) 1972-05-26
DE2152788A1 (en) 1972-04-27
DE2152788B2 (en) 1979-10-18
NL150097B (en) 1976-07-15

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Legal Events

Date Code Title Description
PS Patent sealed
732 Registration of transactions, instruments or events in the register (sect. 32/1977)
732 Registration of transactions, instruments or events in the register (sect. 32/1977)
PCNP Patent ceased through non-payment of renewal fee