GB1362071A - Process for carrying out gas/liquid exothermic reactions - Google Patents
Process for carrying out gas/liquid exothermic reactionsInfo
- Publication number
- GB1362071A GB1362071A GB3803071A GB3803071A GB1362071A GB 1362071 A GB1362071 A GB 1362071A GB 3803071 A GB3803071 A GB 3803071A GB 3803071 A GB3803071 A GB 3803071A GB 1362071 A GB1362071 A GB 1362071A
- Authority
- GB
- United Kingdom
- Prior art keywords
- gas
- bed
- liquid
- rate
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/06—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by conversion of non-aromatic six-membered rings or of such rings formed in situ into aromatic six-membered rings, e.g. by dehydrogenation
- C07C37/07—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by conversion of non-aromatic six-membered rings or of such rings formed in situ into aromatic six-membered rings, e.g. by dehydrogenation with simultaneous reduction of C=O group in that ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0285—Heating or cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0292—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds with stationary packing material in the bed, e.g. bricks, wire rings, baffles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/067—Heating or cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
- C07C29/175—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of an oxo group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
- C07C29/38—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones
- C07C29/42—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones with compounds containing triple carbon-to-carbon bonds, e.g. with metal-alkynes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00026—Controlling or regulating the heat exchange system
- B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
- B01J2208/0007—Pressure measurement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00026—Controlling or regulating the heat exchange system
- B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
- B01J2208/00088—Flow rate measurement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00256—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles in a heat exchanger for the heat exchange medium separate from the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
- B01J2208/00283—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant liquids
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00548—Flow
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/182—Details relating to the spatial orientation of the reactor horizontal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/185—Details relating to the spatial orientation of the reactor vertical
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/187—Details relating to the spatial orientation of the reactor inclined at an angle to the horizontal or to the vertical plane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1362071 Catalytic reactions BADISCHE ANILIN- & SODA-FABRIK AG 13 Aug 1971 [14 Aug 1970] 38030/71 Heading B1F [Also in Division C2] In a process for carrying out an exothermic reaction between a gas and a liquid in the presence of a catalytic fixed bed with improved space-time yields and improved removal of heat, the gas and liquid are passed concurrently downwardly through a reactor containing the fixed bed, and downwardly through the fixed bed in the form of transition flow referred to below by passing the gas and liquid concurrently downwardly through the fixed bed so as to cause a pressure difference #p to be set up between the upper and lower ends of the bed, and controlling the rate of the reaction so as to maintain the ratio of the rate by volume of gas fed to the bed to the rate by volume of off gas produced from the reaction after correcting to N.T.P., at from 4:1 to 100:1, the gas fed to the bed being at least partly consumed during the reaction and the rate of flow, F, of the liquid through the bed being at such a value t that, at a constant rate of feeding the gas to the bed, the change of pressure difference #p with respect to changes in liquid flow rate i.e. d(#P)/dF, is at least twice as great when F equals t as when F equals l, being a liquid flow rate which causes at least predominantly laminar flow of the liquid through the bed, and the value t not being great enough to cause pulsing of pressure differences #p. The transition flow is as defined in A.I. Ch. E. Journal, Vol. 10 (1964) pp 952-953. In Example 1, in which butynediol is formed from formaldehyde and acetylene, column 1, Fig. 2, is packed with pelleted supported catalyst comprising 85% by weight of silica gel, 12% by weight of CuO and 3% by weight of Bi, 37% aqueous formaldehyde is introduced at 11a, at 1 litre/hr, acetylene at 5 atm guage is fed through 9a at 120 litres/hr (S.T.P.) so that the pressure differential between gas feed to the column and the off gas is 0.3 atm. gauge. Product is withdrawn at 15. In Ex. 2, 2-ethyhexanol-1 is prepared by hydrogenation of 2-ethylhexen-2-al-1, and in Ex. 3 trimethylhydroquinone is prepared by the hydrogenation of trimethyl-p-benzoquinone in isobutanol.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19702040501 DE2040501C3 (en) | 1970-08-14 | 1970-08-14 | Process for carrying out exothermic reactions between a gas and a liquid |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1362071A true GB1362071A (en) | 1974-07-30 |
Family
ID=5779798
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3803071A Expired GB1362071A (en) | 1970-08-14 | 1971-08-13 | Process for carrying out gas/liquid exothermic reactions |
Country Status (8)
Country | Link |
---|---|
JP (1) | JPS5812053B1 (en) |
BE (1) | BE771317A (en) |
CA (1) | CA951496A (en) |
CH (1) | CH557197A (en) |
DE (1) | DE2040501C3 (en) |
FR (1) | FR2104350A5 (en) |
GB (1) | GB1362071A (en) |
NL (1) | NL147950B (en) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5093535A (en) * | 1987-12-02 | 1992-03-03 | Davy Mckee (London) Limited | Catalytic hydrogenation process |
GR1002882B (en) * | 1997-01-23 | 1998-03-24 | . | Method and arrangement for induced pulsing flow in trickle bed columns. |
US6262317B1 (en) | 1996-10-10 | 2001-07-17 | Basf Aktiengesellschaft | Process for preparing 1,4-butanediol by catalytic hydrogenation of 1,4-butinediol |
WO2006086067A3 (en) * | 2005-02-04 | 2008-05-08 | Exxonmobil Chem Patents Inc | Fixed bed reactor |
US7388116B2 (en) | 2006-06-06 | 2008-06-17 | Basf Aktiengesellschaft | Hydrogenation of methylolalkanals |
US7462747B2 (en) | 2007-01-05 | 2008-12-09 | Basf Aktiengesellschaft | Process for preparing polyalcohols from formaldehyde having a low formic acid content |
US7572941B2 (en) | 2005-09-06 | 2009-08-11 | Basf Aktiengesellschaft | Method for the separation of polymeric by-products from 1,4-butynediol |
US7605292B2 (en) | 2005-09-06 | 2009-10-20 | Basf Aktiengesellschaft | Method for the separation of polymeric by-products from 1,4-butynediol |
US8575401B2 (en) | 2008-12-09 | 2013-11-05 | Basf Se | Method for purifying crude polymethylols |
US8884076B2 (en) | 2008-12-09 | 2014-11-11 | Basf Se | Method for preparing polymethylols |
US8933277B2 (en) | 2009-01-12 | 2015-01-13 | Basf Se | Process for preparing polymethylols |
US10717692B2 (en) | 2016-10-14 | 2020-07-21 | Johnson Matthey Davy Technologies Limited | Process for the production of 2-alkylalkanol |
US11312674B2 (en) | 2018-04-13 | 2022-04-26 | Johnson Matthey Davy Technologies Limited | Process for making a feed of normal butanol, iso-butanol and 2-alkyl alkanol |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE13874T1 (en) * | 1981-08-20 | 1985-07-15 | Davy Mckee London | HYDRATION PROCESS. |
SE0301102D0 (en) | 2003-04-14 | 2003-04-14 | Tetra Laval Holdings & Finance | Method in connection with the production of an apckaging laminate thus produced and a packaging container manufactures from the packaging laminate |
DE10317543A1 (en) | 2003-04-16 | 2004-11-04 | Basf Ag | Process for the hydrogenation of methylolalkanals |
WO2008098620A1 (en) | 2007-02-15 | 2008-08-21 | Basf Se | Method for the production of 1,4-butanediol |
JP2013526506A (en) | 2010-05-12 | 2013-06-24 | ビーエーエスエフ ソシエタス・ヨーロピア | Method for producing neopentyl glycol |
WO2012143309A1 (en) | 2011-04-19 | 2012-10-26 | Basf Se | Method for producing neopentyl glycol |
WO2013026758A1 (en) | 2011-08-23 | 2013-02-28 | Basf Se | Process for preparing neopentyl glycol |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1210768B (en) * | 1956-09-27 | 1966-02-17 | Exxon Research Engineering Co | Process for the production of isopropyl alcohol and diisopropyl ether by the addition of water to propylene |
DE1291729B (en) * | 1967-06-14 | 1969-04-03 | Rheinpreussen Ag | Process for the hydration of lower olefins to alcohols and ethers |
-
1970
- 1970-08-14 DE DE19702040501 patent/DE2040501C3/en not_active Expired
-
1971
- 1971-07-22 CH CH1083771A patent/CH557197A/en not_active IP Right Cessation
- 1971-08-13 GB GB3803071A patent/GB1362071A/en not_active Expired
- 1971-08-13 CA CA120,568,A patent/CA951496A/en not_active Expired
- 1971-08-13 FR FR7129731A patent/FR2104350A5/fr not_active Expired
- 1971-08-13 NL NL7111211A patent/NL147950B/en not_active IP Right Cessation
- 1971-08-13 JP JP6109371A patent/JPS5812053B1/ja active Granted
- 1971-08-13 BE BE771317A patent/BE771317A/en not_active IP Right Cessation
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5093535A (en) * | 1987-12-02 | 1992-03-03 | Davy Mckee (London) Limited | Catalytic hydrogenation process |
US6262317B1 (en) | 1996-10-10 | 2001-07-17 | Basf Aktiengesellschaft | Process for preparing 1,4-butanediol by catalytic hydrogenation of 1,4-butinediol |
GR1002882B (en) * | 1997-01-23 | 1998-03-24 | . | Method and arrangement for induced pulsing flow in trickle bed columns. |
US7851221B2 (en) | 2005-02-04 | 2010-12-14 | Exxonmobilchemical Patents Inc. | Fixed bed reactor |
US7422904B2 (en) | 2005-02-04 | 2008-09-09 | Exxonmobil Chemical Patents Inc. | Method of operating a fixed bed reactor under predetermined hydraulic conditions |
WO2006086067A3 (en) * | 2005-02-04 | 2008-05-08 | Exxonmobil Chem Patents Inc | Fixed bed reactor |
US7572941B2 (en) | 2005-09-06 | 2009-08-11 | Basf Aktiengesellschaft | Method for the separation of polymeric by-products from 1,4-butynediol |
US7605292B2 (en) | 2005-09-06 | 2009-10-20 | Basf Aktiengesellschaft | Method for the separation of polymeric by-products from 1,4-butynediol |
US7388116B2 (en) | 2006-06-06 | 2008-06-17 | Basf Aktiengesellschaft | Hydrogenation of methylolalkanals |
US7462747B2 (en) | 2007-01-05 | 2008-12-09 | Basf Aktiengesellschaft | Process for preparing polyalcohols from formaldehyde having a low formic acid content |
US8575401B2 (en) | 2008-12-09 | 2013-11-05 | Basf Se | Method for purifying crude polymethylols |
US8884076B2 (en) | 2008-12-09 | 2014-11-11 | Basf Se | Method for preparing polymethylols |
US8933277B2 (en) | 2009-01-12 | 2015-01-13 | Basf Se | Process for preparing polymethylols |
US10717692B2 (en) | 2016-10-14 | 2020-07-21 | Johnson Matthey Davy Technologies Limited | Process for the production of 2-alkylalkanol |
US11312674B2 (en) | 2018-04-13 | 2022-04-26 | Johnson Matthey Davy Technologies Limited | Process for making a feed of normal butanol, iso-butanol and 2-alkyl alkanol |
Also Published As
Publication number | Publication date |
---|---|
FR2104350A5 (en) | 1972-04-14 |
DE2040501A1 (en) | 1972-02-17 |
CH557197A (en) | 1974-12-31 |
BE771317A (en) | 1972-02-14 |
CA951496A (en) | 1974-07-23 |
JPS5812053B1 (en) | 1983-03-05 |
NL7111211A (en) | 1972-02-16 |
NL147950B (en) | 1975-12-15 |
DE2040501C3 (en) | 1984-01-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |