GB1360140A - Methods of and means for determining the calorific value of combustible gases - Google Patents

Methods of and means for determining the calorific value of combustible gases

Info

Publication number
GB1360140A
GB1360140A GB1923672A GB1923672A GB1360140A GB 1360140 A GB1360140 A GB 1360140A GB 1923672 A GB1923672 A GB 1923672A GB 1923672 A GB1923672 A GB 1923672A GB 1360140 A GB1360140 A GB 1360140A
Authority
GB
United Kingdom
Prior art keywords
flame temperature
maximum
temperature
gas
switch
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1923672A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PRECISIONS MACHINE PRODUCTS IN
Original Assignee
PRECISIONS MACHINE PRODUCTS IN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US00243595A priority Critical patent/US3777562A/en
Application filed by PRECISIONS MACHINE PRODUCTS IN filed Critical PRECISIONS MACHINE PRODUCTS IN
Priority to GB1923672A priority patent/GB1360140A/en
Priority to NLAANVRAGE7206076,A priority patent/NL178721C/en
Priority to DE2222073A priority patent/DE2222073C2/en
Publication of GB1360140A publication Critical patent/GB1360140A/en
Expired legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N25/00Investigating or analyzing materials by the use of thermal means
    • G01N25/20Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity
    • G01N25/22Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity on combustion or catalytic oxidation, e.g. of components of gas mixtures
    • G01N25/28Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity on combustion or catalytic oxidation, e.g. of components of gas mixtures the rise in temperature of the gases resulting from combustion being measured directly
    • G01N25/30Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity on combustion or catalytic oxidation, e.g. of components of gas mixtures the rise in temperature of the gases resulting from combustion being measured directly using electric temperature-responsive elements
    • G01N25/32Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity on combustion or catalytic oxidation, e.g. of components of gas mixtures the rise in temperature of the gases resulting from combustion being measured directly using electric temperature-responsive elements using thermoelectric elements

Abstract

1360140 Automatic control of temperature PRECISION MACHINE PRODUCTS Inc 25 April 1972 19236/72 Heading G3R [Also in Division G1] To determine the calorific value of a combustible gas, the gas is mixed with a combustionsupporting gas and the resulting mixture is burnt, the temperature of the burned gases being monitored, and the volume ratio of the gases is adjusted until the maximum flame temperature is attained, the ratio corresponding to the maximum flame temperature being proportional to the calorific value of the combustible gas for a given test apparatus. In Fig.1, air and combustible gas supplies are controlled by respective valves 9, 10 and measured by respective flow meters 11, 12 before being mixed in a duct 8 leading to a Meker burner 2. A thermocouple 15 in the burner flame is connected to a controller 16 which actuates one of the valves 9, 10 to automatically achieve and maintain maximum flame temperature. As shown in Figs.1 and 5, the valve 9 is actuated by a reversible D.C. motor 60 energized via single pole double throw relay switches 67, 68 in the controller 16. The switches 67, 68 form parts of alarm switching units 65, 66 respectively. The threshold value of unit 65 is slightly higher than that of unit 66. The units 65, 66 are connected in series with a constant current source 79 giving a current between the threshold values of the units, and a double pole double throw relay switch 77. Oscillators 85, 86 supply positive and negative pulse trains respectively, one or other pulse train being superimposed on the constant current according to the setting of the switch 77. When the E.M.F. of the thermocouple 15 is increasing, the output of a differentiating circuit 81 is such that the switch 77 remains in its existing position so that a train of positive or negative pulses acts on the units 65, 66 to effect intermittent opening or closing movements of the valve 9, to continue the rise in flame temperature. After the flame temperature has passed its maximum, the output signal of the circuit 81 reverses the switch 77 to connect the other oscillator to the control current to reverse the movement of the valve 9 so that the flame temperature re-approaches its maximum. A further reversal occurs each time the maximum is passed. In a modification Fig. 2 (not shown), a small pulsed air-flow is added to the mixed gases supplied to the burner, causing small perturbations in the flame temperature except when the maximum flame temperature exists. The controller 16' Fig. 6 in this system includes a pulse amplitude measuring circuit 122 which actuates a double pole double throw relay switch 115 controlling the motor 110 to approach the zero perturbation condition, and hence the maximum flame temperature. In a further modification Fig. 3 (not shown), two burners are used, the gas supply to one being slightly restricted. At the critical combustion ratio (the gas volume ratio for maximum flame temperature) there is a characteristic temperature difference between the thermocouples 25, 25' Fig.7 in the two flames, a controller 26 acting to achieve and maintain this value. A voltage to current converter 109 with a linear characteristic receives the E.M.F. difference between the thermocouples and controls alarm switching units 95, 96.
GB1923672A 1972-04-13 1972-04-25 Methods of and means for determining the calorific value of combustible gases Expired GB1360140A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US00243595A US3777562A (en) 1972-04-13 1972-04-13 Methods of and means for determining the calorific value of combustible gases
GB1923672A GB1360140A (en) 1972-04-13 1972-04-25 Methods of and means for determining the calorific value of combustible gases
NLAANVRAGE7206076,A NL178721C (en) 1972-04-13 1972-05-05 METHOD AND APPARATUS FOR DETERMINING THE CALORIC VALUE OF NATURAL GAS
DE2222073A DE2222073C2 (en) 1972-04-13 1972-05-05 Device for determining the calorific value of combustible gases

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US24359572A 1972-04-13 1972-04-13
GB1923672A GB1360140A (en) 1972-04-13 1972-04-25 Methods of and means for determining the calorific value of combustible gases
NLAANVRAGE7206076,A NL178721C (en) 1972-04-13 1972-05-05 METHOD AND APPARATUS FOR DETERMINING THE CALORIC VALUE OF NATURAL GAS
DE2222073A DE2222073C2 (en) 1972-04-13 1972-05-05 Device for determining the calorific value of combustible gases

Publications (1)

Publication Number Publication Date
GB1360140A true GB1360140A (en) 1974-07-17

Family

ID=27431485

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1923672A Expired GB1360140A (en) 1972-04-13 1972-04-25 Methods of and means for determining the calorific value of combustible gases

Country Status (4)

Country Link
US (1) US3777562A (en)
DE (1) DE2222073C2 (en)
GB (1) GB1360140A (en)
NL (1) NL178721C (en)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4062236A (en) * 1976-05-03 1977-12-13 Precision Machine Products, Inc. Method of and means for accurately measuring the calorific value of combustible gases
EP0031145B1 (en) * 1979-12-20 1985-01-16 Honeywell Inc. Method and apparatus for determining the volumetric heat content of gaseous fuels
US4315430A (en) * 1980-02-21 1982-02-16 Honeywell Inc. Gas calorific content analyzing apparatus
US4351614A (en) * 1980-03-19 1982-09-28 Eaton Corporation Method of and apparatus for continually monitoring the heating value of a fuel gas using a combustibility meter
JPS56141546A (en) * 1980-04-07 1981-11-05 Yamatake Honeywell Co Ltd Calorific value measuring device
JPS56141541A (en) * 1980-04-07 1981-11-05 Yamatake Honeywell Co Ltd Calorific value measuring device
US5115687A (en) * 1981-06-10 1992-05-26 Badger Meter, Inc. Method and apparatus for taking a proportional sample of flowing gas in a line
US4396299A (en) * 1981-06-10 1983-08-02 Precision Machine Products, Inc. Method and apparatus for determining total energy flow in a gas line
US5016482A (en) * 1981-06-10 1991-05-21 Clingman Jr William H Method of taking a proportional sample of flowing gas in a line
US4415278A (en) * 1982-02-08 1983-11-15 Honeywell Inc. Method for operating a gas analyzing system and apparatus utilizing the same
US4530247A (en) * 1983-03-15 1985-07-23 Northwest Natural Gas Company Timed gas metering and distribution system
US4527435A (en) * 1983-11-21 1985-07-09 Precision Machine Products, Inc. Channeled plug proportional flow sampler
US4613482A (en) * 1983-12-23 1986-09-23 The Foxboro Company Constant temperature heating value measurement apparatus
US5224776A (en) * 1989-02-24 1993-07-06 Precision Measurement, Inc. Instrument and method for heating value measurement by stoichiometric combustion
US5100244A (en) * 1989-05-02 1992-03-31 Precision Measurement, Inc. Gas calorimeter and method of measuring the calorific value of fuel gases
US5323657A (en) * 1991-11-04 1994-06-28 Badger Meter, Inc. Volumetric flow corrector and method
US5201581A (en) * 1991-11-18 1993-04-13 Badger Meter, Inc. Method and apparatus for measuring mass flow and energy content using a linear flow meter
US5226728A (en) * 1991-11-04 1993-07-13 Badger Meter, Inc. Method and apparatus for measuring mass flow and energy content using a differential pressure meter
US5288149A (en) * 1992-03-12 1994-02-22 Panametrics, Inc. Gas calorimeter and wobbe index meter
US5357809A (en) * 1993-04-14 1994-10-25 Badger Meter, Inc. Volumetric flow corrector having a densitometer
US5748492A (en) * 1995-05-24 1998-05-05 Badger Meter, Inc. Measuring heating value using catalytic combustion
US5759862A (en) * 1995-05-24 1998-06-02 Badger Meter, Inc. Measuring heating value using catalytic combustion
US7905656B2 (en) * 2007-09-20 2011-03-15 Beijing Union University Differential passive calorimeter
GB2474569B (en) * 2007-10-31 2012-04-11 Anubiz Bvba Apparatus and method for determining stoichiometric molar flow ratio for oxidation of a fuel
EP2690358A4 (en) 2011-03-24 2014-09-17 Olympus Corp Illuminating system
JP5781968B2 (en) * 2012-03-27 2015-09-24 アズビル株式会社 Calorific value measuring system and calorific value measuring method
CN109270120B (en) * 2018-11-08 2023-12-22 浙江大学 Heat measuring device and system for on-line measurement of calorific value of pulverized coal

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1205704A (en) * 1915-03-31 1916-11-21 New Jersey Zinc Co Continuous gas-calorimeter.
US2052181A (en) * 1930-08-06 1936-08-25 Brown Instr Co Flame propagation analyzer
US2120791A (en) * 1934-12-12 1938-06-14 Cutler Hammer Inc Method of and apparatus for determining the heating value of combustible gaseous fluids
US3393562A (en) * 1964-11-17 1968-07-23 Harry B. Breedlove Calorimeter apparatus

Also Published As

Publication number Publication date
NL7206076A (en) 1973-11-07
DE2222073A1 (en) 1973-11-15
NL178721C (en) 1986-05-01
DE2222073C2 (en) 1985-09-12
NL178721B (en) 1985-12-02
US3777562A (en) 1973-12-11

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE20 Patent expired after termination of 20 years