GB1347858A - Process for the preparation of allyl acetate - Google Patents

Process for the preparation of allyl acetate

Info

Publication number
GB1347858A
GB1347858A GB3512671A GB3512671A GB1347858A GB 1347858 A GB1347858 A GB 1347858A GB 3512671 A GB3512671 A GB 3512671A GB 3512671 A GB3512671 A GB 3512671A GB 1347858 A GB1347858 A GB 1347858A
Authority
GB
United Kingdom
Prior art keywords
allyl acetate
noble metal
july
present
propylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3512671A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Farbwerke Hoechst AG filed Critical Hoechst AG
Publication of GB1347858A publication Critical patent/GB1347858A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00176—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles outside the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2208/00274—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant vapours

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1347858 Allyl acetate FARBWERKE HOECHST AG 27 July 1971 [31 July 1970] 35126/71 Heading C2C Allyl acetate is prepared by heating acetic acid, propylene and oxygen in the gaseous phase in the presence of carbon dioxide and a noble metal or noble metal catalyst. The propylene concentration of the reaction gas is below 50% and 0À2 to 5À0 fold amount of propane is present. A temperature of 140‹ to 250‹ C. and 1 to 10 atmospheres pressure is used and platinum, palladium, ruthenium, rhodium, iridium and osmium may be the noble metal. Cadmium, gold, bismuth, copper and manganese, and alkali or alkaline earth metal salts may be present. Silicic acid, aluminium oxide or aluminium silicate may be the support.
GB3512671A 1970-07-31 1971-07-27 Process for the preparation of allyl acetate Expired GB1347858A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2038120A DE2038120C3 (en) 1970-07-31 1970-07-31 Process for the production of allyl acetate

Publications (1)

Publication Number Publication Date
GB1347858A true GB1347858A (en) 1974-02-27

Family

ID=5778528

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3512671A Expired GB1347858A (en) 1970-07-31 1971-07-27 Process for the preparation of allyl acetate

Country Status (15)

Country Link
AT (1) AT321873B (en)
AU (1) AU456851B2 (en)
BE (1) BE770681A (en)
BG (1) BG19127A3 (en)
BR (1) BR7104836D0 (en)
CS (1) CS161915B2 (en)
DE (1) DE2038120C3 (en)
ES (1) ES393606A1 (en)
FR (1) FR2099396A5 (en)
GB (1) GB1347858A (en)
LU (1) LU63628A1 (en)
NL (1) NL7110265A (en)
PL (1) PL82098B1 (en)
SU (1) SU466652A3 (en)
ZA (1) ZA714936B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3855280A (en) * 1972-12-08 1974-12-17 Celanese Corp Process for producing an alkenyl alkanoate from an olefin and a carboxylic acid

Also Published As

Publication number Publication date
DE2038120C3 (en) 1979-11-22
NL7110265A (en) 1972-02-02
SU466652A3 (en) 1975-04-05
BE770681A (en) 1972-01-31
BR7104836D0 (en) 1973-04-05
AU456851B2 (en) 1975-01-16
BG19127A3 (en) 1975-04-30
PL82098B1 (en) 1975-10-31
FR2099396A5 (en) 1972-03-10
ES393606A1 (en) 1973-08-01
LU63628A1 (en) 1973-02-05
CS161915B2 (en) 1975-06-10
AU3176171A (en) 1973-02-01
DE2038120A1 (en) 1972-02-10
ZA714936B (en) 1972-04-26
AT321873B (en) 1975-04-25

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee