GB1329334A - Preparation of ethylene polymer wax - Google Patents
Preparation of ethylene polymer waxInfo
- Publication number
- GB1329334A GB1329334A GB1803171A GB1803171A GB1329334A GB 1329334 A GB1329334 A GB 1329334A GB 1803171 A GB1803171 A GB 1803171A GB 1803171 A GB1803171 A GB 1803171A GB 1329334 A GB1329334 A GB 1329334A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethylene
- solvent
- compound
- polymerization
- wax
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/023—On to modified polymers, e.g. chlorinated polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/06—Oxidation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/46—Reaction with unsaturated dicarboxylic acids or anhydrides thereof, e.g. maleinisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/50—Partial depolymerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
1329334 Waxy ethylene polymers MITSUI PETROCHEMICAL INDUSTRIES Ltd 28 May 1971 [29 May 1970 30 May 1970 (2)] 18031/71 Heading C3P Waxes, i.e. polymers having a viscosity average molecular weight of 400 to 20,000 and a softening point of 80-135‹ C. (other physical properties being specified) are obtained by polymerizing ethylene in the presence of hydrogen and optionally an α-olefin, in solution in a saturated hydrocarbon diluent or in the molten wax itself, using a catalyst comprising (a) a halogen compound of titanium or vanadium supported on a hydrocarbon-insoluble magnesium compound, and (b) an organoaluminium compound, the amount of aluminium in component (b) being 1-100 atoms per atom of Ti or V and being 0À01 to 10 milliequivalents per litre of polymerization solvent. The polymerization is carried out at a temperature at which the wax is molten and a pressure of 20-100 kg/cm.<SP>2</SP> gauge when a hydrocarbon solvent is used or 5-100 kg./cm.<SP>2</SP> when the solvent is molten wax. The molar composition of the vapour phase, excluding solvent vapour, is 3-90% hydrogen, 0-35% α-olefin and the remainder ethylene. The catalyst carrier may be activated by treatment with a Lewis base (ethanol being exemplified) before treatment with the Ti or V compound. Exemplified catalysts are (a) TiCl 4 or VOCl 3 supported on MgO, Mg(OH) 2 , hydrated or anhydrous MgCl 2 , or coprecipitated MgO-Al 2 O 3 , with (b) Et 3 Al or i-Bu 3 Al. Continuous polymerization of ethylene, alone or in the presence of propylene or butene-1, in hexane is described. The waxes may be modified by oxidation, preferably by passing air through the molten wax at 130-200‹ C., and the oxidized products may be reacted with maleic acid or its derivatives, e.g. the dimethyl or dioctyl ester or the anhydride.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4559970A JPS5440594B1 (en) | 1970-05-29 | 1970-05-29 | |
JP4604770A JPS4837991B1 (en) | 1970-05-30 | 1970-05-30 | |
JP4604670A JPS4841710B1 (en) | 1970-05-30 | 1970-05-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1329334A true GB1329334A (en) | 1973-09-05 |
Family
ID=27292287
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1803171A Expired GB1329334A (en) | 1970-05-29 | 1971-05-28 | Preparation of ethylene polymer wax |
Country Status (5)
Country | Link |
---|---|
CA (1) | CA987847A (en) |
DE (1) | DE2126725C3 (en) |
FR (1) | FR2092165B1 (en) |
GB (1) | GB1329334A (en) |
NL (1) | NL152567B (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0021700A1 (en) * | 1979-06-11 | 1981-01-07 | Mitsui Petrochemical Industries, Ltd. | Process for preparing ethylene polymer wax |
US5498809A (en) | 1992-12-17 | 1996-03-12 | Exxon Chemical Patents Inc. | Polymers derived from ethylene and 1-butene for use in the preparation of lubricant dispersant additives |
US5554310A (en) | 1992-12-17 | 1996-09-10 | Exxon Chemical Patents Inc. | Trisubstituted unsaturated polymers |
US5883196A (en) * | 1995-05-24 | 1999-03-16 | Basf Aktiengesellschaft | Preparation of polyalkenylsuccinic acid derivatives and their use as fuel and lubricant additives |
US5917100A (en) * | 1993-01-07 | 1999-06-29 | Clariant Gmbh | Process for producing low molecular-weight poly-1-olefins |
WO2008061826A1 (en) * | 2006-11-25 | 2008-05-29 | Evonik Degussa Gmbh | Method for the production of synthetic polyethylene waxes with high crystallinity and low viscosity |
US7563849B2 (en) | 1999-06-17 | 2009-07-21 | Mitsui Chemicals, Inc. | Ethylene (co) polymer and its use |
EP3730553A1 (en) * | 2019-04-26 | 2020-10-28 | Thai Polyethylene Co., Ltd. | Composition comprising an oxidized polyethylene wax, a color masterbatch comprising the same,a product comprising the color masterbatch and the use of the color masterbatch |
CN113563498A (en) * | 2021-08-12 | 2021-10-29 | 朱孝恒 | Polyethylene wax production method |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1089588A (en) * | 1976-04-26 | 1980-11-11 | Robert L. Elliott | Oil-soluble addition products of an ethylene-olefin copolymer and anionically polymerizable monomer having utility as multifunctional v.i. improvers for lubricating oils |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB869492A (en) * | 1960-03-21 | 1961-05-31 | Shell Res Ltd | Improvements in or relating to the low-pressure polymerisation of olefinic compoundsand catalysts therefor |
FR1384630A (en) * | 1962-10-02 | 1965-01-08 | Scholven Chemie Ag | Process for the preparation of waxes, from ethylene and products conforming to those obtained by said process or similar process |
FR1375127A (en) * | 1963-08-01 | 1964-10-16 | Solvay | Process for the polymerization and copolymerization of olefins |
FR85522E (en) * | 1964-03-03 | 1965-08-27 | Solvay | Process for the polymerization and copolymerization of olefins |
US3400110A (en) * | 1963-08-01 | 1968-09-03 | Solvay | Polymerization of olefins in the presence of a catalyst comprising an organometallic compound and the reaction product of a transition metal compound and a hydroxychloride of a bivalent metal |
DE1645411B2 (en) * | 1965-03-25 | 1974-02-07 | Veba-Chemie Ag, 4660 Gelsenkirchenbuer | Process for the production of polyethylene waxes |
FR1516800A (en) * | 1966-10-21 | 1968-03-15 | Solvay | Process for the polymerization and copolymerization of olefins. |
CA920299A (en) * | 1968-08-01 | 1973-01-30 | Mitsui Petrochemical Industries | Process for the polymerization and/or copolymerization of olefins with use of ziegler-type catalytsts supported on carrier |
FR1582942A (en) * | 1968-08-26 | 1969-10-10 | ||
GB1189038A (en) * | 1968-09-11 | 1970-04-22 | Mitsui Petrochemical Ind | Novel Process for the Polymerisation of Ethylene and Novel Catalyst for use therein |
SE411907B (en) * | 1968-10-09 | 1980-02-11 | Montedison Spa | SET AND CATALYST FOR POLYMERIZATION OF ONE OR ITS MIXTURES WITH ALFAOLEFINES |
-
1971
- 1971-05-28 DE DE2126725A patent/DE2126725C3/en not_active Expired
- 1971-05-28 GB GB1803171A patent/GB1329334A/en not_active Expired
- 1971-05-28 NL NL717107392A patent/NL152567B/en not_active IP Right Cessation
- 1971-05-28 CA CA114,279A patent/CA987847A/en not_active Expired
- 1971-06-01 FR FR7119710A patent/FR2092165B1/fr not_active Expired
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4418184A (en) | 1979-06-11 | 1983-11-29 | Mitsui Petrochemical Industries, Ltd. | Process for preparation of ethylene polymer wax |
EP0021700A1 (en) * | 1979-06-11 | 1981-01-07 | Mitsui Petrochemical Industries, Ltd. | Process for preparing ethylene polymer wax |
US5498809A (en) | 1992-12-17 | 1996-03-12 | Exxon Chemical Patents Inc. | Polymers derived from ethylene and 1-butene for use in the preparation of lubricant dispersant additives |
US5554310A (en) | 1992-12-17 | 1996-09-10 | Exxon Chemical Patents Inc. | Trisubstituted unsaturated polymers |
US5663130A (en) | 1992-12-17 | 1997-09-02 | Exxon Chemical Patents Inc | Polymers derived from ethylene and 1-butene for use in the preparation of lubricant dispersant additives |
US6030930A (en) | 1992-12-17 | 2000-02-29 | Exxon Chemical Patents Inc | Polymers derived from ethylene and 1-butene for use in the preparation of lubricant disperant additives |
US5917100A (en) * | 1993-01-07 | 1999-06-29 | Clariant Gmbh | Process for producing low molecular-weight poly-1-olefins |
US5883196A (en) * | 1995-05-24 | 1999-03-16 | Basf Aktiengesellschaft | Preparation of polyalkenylsuccinic acid derivatives and their use as fuel and lubricant additives |
US7687579B2 (en) | 1999-06-17 | 2010-03-30 | Mitsui Chemicals, Inc. | Ethylene (co) polymer and its use |
US7563849B2 (en) | 1999-06-17 | 2009-07-21 | Mitsui Chemicals, Inc. | Ethylene (co) polymer and its use |
WO2008061826A1 (en) * | 2006-11-25 | 2008-05-29 | Evonik Degussa Gmbh | Method for the production of synthetic polyethylene waxes with high crystallinity and low viscosity |
CN101589072B (en) * | 2006-11-25 | 2012-07-11 | 霍尼韦尔国际公司 | Method for the production of synthetic polyethylene waxes with high crystallinity and low viscosity |
US9403923B2 (en) | 2006-11-25 | 2016-08-02 | Honeywell International Inc. | Process for preparing synthetic polyethylene waxes having a high crystallinity and low viscosity |
EP3730553A1 (en) * | 2019-04-26 | 2020-10-28 | Thai Polyethylene Co., Ltd. | Composition comprising an oxidized polyethylene wax, a color masterbatch comprising the same,a product comprising the color masterbatch and the use of the color masterbatch |
WO2020216605A1 (en) * | 2019-04-26 | 2020-10-29 | Thai Polyethylene Co., Ltd. | Composition comprising an oxidized polyethylene wax, a color masterbatch comprising the same, a product comprising the color masterbatch and the use of the color masterbatch |
CN113383042A (en) * | 2019-04-26 | 2021-09-10 | 泰国聚乙烯有限公司 | Composition comprising oxidized polyethylene wax, color masterbatch comprising same, product comprising color masterbatch and use of color masterbatch |
CN113563498A (en) * | 2021-08-12 | 2021-10-29 | 朱孝恒 | Polyethylene wax production method |
Also Published As
Publication number | Publication date |
---|---|
CA987847A (en) | 1976-04-20 |
DE2126725C3 (en) | 1983-04-21 |
NL152567B (en) | 1977-03-15 |
DE2126725B2 (en) | 1978-07-06 |
FR2092165B1 (en) | 1974-03-22 |
NL7107392A (en) | 1971-12-01 |
FR2092165A1 (en) | 1972-01-21 |
DE2126725A1 (en) | 1972-01-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PE20 | Patent expired after termination of 20 years |