GB1327744A - Fluorinated oil-and water-repellent and dry soil resistant polymers - Google Patents

Fluorinated oil-and water-repellent and dry soil resistant polymers

Info

Publication number
GB1327744A
GB1327744A GB254071A GB254071A GB1327744A GB 1327744 A GB1327744 A GB 1327744A GB 254071 A GB254071 A GB 254071A GB 254071 A GB254071 A GB 254071A GB 1327744 A GB1327744 A GB 1327744A
Authority
GB
United Kingdom
Prior art keywords
water
parts
soil resistant
repellent
jan
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB254071A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB1327744A publication Critical patent/GB1327744A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C08F220/24—Esters containing halogen containing perhaloalkyl radicals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/911—Emulsifying agents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2164—Coating or impregnation specified as water repellent
    • Y10T442/2172—Also specified as oil repellent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2164—Coating or impregnation specified as water repellent
    • Y10T442/2189—Fluorocarbon containing

Abstract

1327744 Fluorine-containing acrylic copolymers E I DU PONT DE NEMOURS & CO 19 Jan 1971 [29 Jan 1970] 2540/71 Heading C3P An oil- and water-repellant and soil resistant aqueous emulsion copolymer contains 100 parts of a mixture of (a) 70-95 parts of and (b) 30-5 parts of ethyl or methyl acrylate where R f is a perfluoroalkyl group of 4-14 carbons. There may optionally be present up to 1 part of hydroxyethyl acrylate or methacrylate and/or N-methylol acrylamide or methacrylamide. Preferably Rf is a commercial mixture containing C 4 , C 6 , C 8 , C 10 and C 12 constituents. The polymers are formed in aqueous emulsion using a cationic emulsifier, e.g. dimethyl octadecylamine acetate, a water soluble azo-initiator e.g. azo-bis-isobutyramidine hydrochloride and dodecylmercaptan. The emulsions are applied to fabrics and dried.
GB254071A 1970-01-29 1971-01-19 Fluorinated oil-and water-repellent and dry soil resistant polymers Expired GB1327744A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US696270A 1970-01-29 1970-01-29

Publications (1)

Publication Number Publication Date
GB1327744A true GB1327744A (en) 1973-08-22

Family

ID=21723489

Family Applications (1)

Application Number Title Priority Date Filing Date
GB254071A Expired GB1327744A (en) 1970-01-29 1971-01-19 Fluorinated oil-and water-repellent and dry soil resistant polymers

Country Status (8)

Country Link
US (1) US3645990A (en)
BE (1) BE762088A (en)
CA (1) CA959595A (en)
CH (1) CH547831A (en)
DE (1) DE2104267C3 (en)
FR (1) FR2077395B1 (en)
GB (1) GB1327744A (en)
NL (1) NL7101232A (en)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3706594A (en) * 1971-02-22 1972-12-19 Us Agriculture Fibrous substrate treated with copolymers of fluoroalkyl ethers and maleic anhydride
US4013627A (en) * 1972-09-20 1977-03-22 E. I. Du Pont De Nemours And Company Oil and water repellent polymer containing onium groups
US3880949A (en) * 1973-05-03 1975-04-29 Thiokol Chemical Corp Inherently mold-releasable mold or casting composition
US3879490A (en) * 1973-05-03 1975-04-22 Thiokol Corp Inherently mold-releasable mold or casting composition
US4007305A (en) * 1974-12-23 1977-02-08 Basf Wyandotte Corporation Method of imparting nondurable soil release and soil repellency properties to textile materials
DE2609462C3 (en) * 1976-03-08 1979-11-29 Hoechst Ag, 6000 Frankfurt Perfluoroalkyl ethyl acrylate copolymers
US4127711A (en) * 1977-03-31 1978-11-28 E. I. Du Pont De Nemours And Company Fluorine-containing terpolymers
JPS608068B2 (en) * 1978-09-28 1985-02-28 ダイキン工業株式会社 Water and oil repellent
JPS5845275A (en) * 1981-09-10 1983-03-16 Daikin Ind Ltd Acrylic adhesive
US4529658A (en) * 1982-10-13 1985-07-16 Minnesota Mining And Manufacturing Company Fluorochemical copolymers and ovenable paperboard and textile fibers treated therewith
US4525423A (en) * 1982-10-13 1985-06-25 Minnesota Mining And Manufacturing Company Fluorochemical copolymers and ovenable paperboard and textile fibers treated therewith
US4474982A (en) * 1982-10-13 1984-10-02 Minnesota Mining And Manufacturing Company 1-Halomethyl-2-alkoxyethyl acrylates and methacrylates
JPH06228534A (en) * 1993-02-01 1994-08-16 Daikin Ind Ltd Water and oil repellent and stainproofing agent
US5539072A (en) * 1993-03-26 1996-07-23 W. L. Gore & Associates, Inc. Fabric laminates
US6492001B1 (en) * 1996-08-07 2002-12-10 Hi-Tex, Inc. Treated textile fabric
US6251210B1 (en) * 1996-08-07 2001-06-26 Hi-Tex, Inc. Treated textile fabric
US6196708B1 (en) 1998-05-14 2001-03-06 Donaldson Company, Inc. Oleophobic laminated articles, assemblies of use, and methods
KR20030022265A (en) * 2000-07-07 2003-03-15 밀리켄 앤드 캄파니 Textile substrates having improved durable water repellency and soil release and method for producing same
JP4552294B2 (en) * 2000-08-31 2010-09-29 ソニー株式会社 Content distribution system, content distribution method, information processing apparatus, and program providing medium
US7468333B2 (en) * 2003-01-10 2008-12-23 Milliken & Company Wash-durable, liquid repellent, and stain releasing polyester fabric substrates
US7485588B2 (en) * 2003-01-10 2009-02-03 Yunzhang Wang Method for making textile substrates having layered finish structure for improving liquid repellency and stain release
US6899923B2 (en) * 2003-01-10 2005-05-31 Milliken & Company Methods for imparting reversibly adaptable surface energy properties to target surfaces
US7407899B2 (en) * 2003-01-10 2008-08-05 Milliken & Company Textile substrates having layered finish structure for improving liquid repellency and stain release
US7173081B2 (en) * 2003-08-12 2007-02-06 Hexion Specialty Chemicals, Inc. Processes to produce water-dispersible polyester stabilized fluoroalkyl compositions
US7189780B2 (en) * 2003-08-12 2007-03-13 Hexion Specialty Chemicals, Inc. Processes to produce water-dispersible polyester stabilized, acid-treated, fluoroalkyl compositions
US7186769B2 (en) * 2003-08-12 2007-03-06 Hexion Specialty Chemicals, Inc. Water-dispersible polyester stabilized fluoroalkyl compositions
US7101924B2 (en) * 2003-08-12 2006-09-05 Hexion Specialty Materials, Inc. Water-dispersible polyester stabilized, acid-treated, fluoroalkyl compositions
US7531219B2 (en) * 2005-07-21 2009-05-12 Hi-Tex, Inc. Treated textile fabric
WO2008103532A2 (en) * 2007-02-23 2008-08-28 Invista Technologies S.Ar.L. A new stain resistant barrier fabric
JP5439743B2 (en) * 2007-10-11 2014-03-12 ユニマテック株式会社 Water and oil repellent
US20100130085A1 (en) * 2008-11-25 2010-05-27 Invista North America S.A R.L. Moisture-vapor-breathable and liquid-impermissible structures, moisture-vapor-breathable and liquid-impermissible upholstery structures and methods of making moisture-vapor-breathable and liquid-impermissible structures
US9364859B2 (en) * 2011-07-28 2016-06-14 Kimberly-Clark Worldwide, Inc. Superhydrophobic surfaces
AU2016206650A1 (en) 2015-01-14 2017-08-10 Gregory Van Buskirk Improved fabric treatment method for stain release

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3459696A (en) * 1965-06-24 1969-08-05 Du Pont Water-repellent compositions

Also Published As

Publication number Publication date
DE2104267C3 (en) 1974-07-25
BE762088A (en) 1971-07-01
DE2104267B2 (en) 1973-12-20
FR2077395B1 (en) 1974-03-01
CA959595A (en) 1974-12-17
US3645990A (en) 1972-02-29
NL7101232A (en) 1971-08-02
CH547831A (en) 1974-04-11
DE2104267A1 (en) 1971-08-05
FR2077395A1 (en) 1971-10-22

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee