GB1317769A - Process for preparing benzoate esters - Google Patents

Process for preparing benzoate esters

Info

Publication number
GB1317769A
GB1317769A GB3764570A GB3764570A GB1317769A GB 1317769 A GB1317769 A GB 1317769A GB 3764570 A GB3764570 A GB 3764570A GB 3764570 A GB3764570 A GB 3764570A GB 1317769 A GB1317769 A GB 1317769A
Authority
GB
United Kingdom
Prior art keywords
carbon atoms
benzoate esters
glycol
reaction
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3764570A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of GB1317769A publication Critical patent/GB1317769A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C07C69/78Benzoic acid esters
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/08Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1317769 Preparation of benzoate esters DOW CHEMICAL CO 4 Aug 1970 [4 Aug 1969] 37645/70 Heading C2C A process for the preparation of benzoate esters by the reaction of a benzoic acid or a benzoic acid having no more than three inert substituents, i.e. C 1-10 alkyl, C 1-10 alkoxy and CF 3 with an alcohol which is an alkylene or polyalkylene glycol or an aliphatic monoether of said glycol of up to 10 carbon atoms, a glycol monoaryl ether of up to 14 carbon atoms, a polyol having at least three -OH groups of up to 10 carbon atoms or an alkanol, aralkanol or alkenol of 4 to 20 carbon atoms, at 180‹ to 350‹ C. in the absence of air or oxygen and under conditions minimizing contact of the resulting ester and water comprises utilizing at least 1À1 moles of the acid for each hydroxyl equivalent and carrying out the reaction in the absence of a catalyst. The examples describe the preparation of benzoate esters by the reaction of benzoic acid with glycerol, 2- phenoxyethanol, benzyl alcohol and dipropylene glycol.
GB3764570A 1969-08-04 1970-08-04 Process for preparing benzoate esters Expired GB1317769A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US84741069A 1969-08-04 1969-08-04

Publications (1)

Publication Number Publication Date
GB1317769A true GB1317769A (en) 1973-05-23

Family

ID=25300558

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3764570A Expired GB1317769A (en) 1969-08-04 1970-08-04 Process for preparing benzoate esters

Country Status (5)

Country Link
BE (1) BE754330A (en)
DE (1) DE2038727A1 (en)
FR (1) FR2057843A5 (en)
GB (1) GB1317769A (en)
NL (1) NL7011137A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4273696A (en) * 1977-11-30 1981-06-16 Imperial Chemical Industries Limited Polyvinylchloride compositions containing phenoxy alkanol dicarboxylic acid ester plasticizers

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4273696A (en) * 1977-11-30 1981-06-16 Imperial Chemical Industries Limited Polyvinylchloride compositions containing phenoxy alkanol dicarboxylic acid ester plasticizers

Also Published As

Publication number Publication date
NL7011137A (en) 1971-02-08
DE2038727A1 (en) 1971-02-18
BE754330A (en) 1971-02-03
FR2057843A5 (en) 1971-05-21

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees