GB1311246A - Additives for the preparation of clear impact resistant vinyl chloride polymer compositions - Google Patents

Additives for the preparation of clear impact resistant vinyl chloride polymer compositions

Info

Publication number
GB1311246A
GB1311246A GB2497171A GB2497171A GB1311246A GB 1311246 A GB1311246 A GB 1311246A GB 2497171 A GB2497171 A GB 2497171A GB 2497171 A GB2497171 A GB 2497171A GB 1311246 A GB1311246 A GB 1311246A
Authority
GB
United Kingdom
Prior art keywords
copolymer
acrylate
vinyl
butylene glycol
glycol dimethacrylate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2497171A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Stauffer Chemical Co
Original Assignee
Stauffer Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Stauffer Chemical Co filed Critical Stauffer Chemical Co
Publication of GB1311246A publication Critical patent/GB1311246A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
    • C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
    • C08F259/06—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinylidene chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/08—Homopolymers or copolymers of vinylidene chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1311246 Acrylate ester copolymer compositions STAUFFER CHEMICAL Co 19 April 1971 [15 April 1970] 24971/71 Headings C3G and C3P Impact resistant thermoplastic polymers comprise a vinyl chloride polymer and a copolymer of (1) at least one C 1-12 alkyl acrylates and (2) benzyl acrylate or vinylidene chloride, optionally grafted with a methyl methacrylate polymer. The copolymer components may be so selected that the refractive index thereof is equal to that of the rigid polymer whereby clear compositions may be obtained. The copolymers may also contain other monomers, e.g. vinyl esters, esters of unsaturated acids, amides, nitriles, vinyl ethers and vinyl aromatic compounds; and cross-linking agents, e.g. glycol dimethacrylates, allyl acrylate, allyl methacrylate, divinyl benzene, divinyloxyethyl ether and diallyl adipate; and the methyl methacrylate may be graft copolymerized with ethyl acrylate. The rigid polymer may be a vinyl chloride polymer or copolymer with a minor proportion of at least one ethyl enically unsaturated comonomer, and the additive may be incorporated by coagulating or spray drying mixed latices, or by forming the rigid polymer by emulsion or suspension polymerization in a latex of the additive copolymer. Many examples are given describing the suspension polymerization of vinyl chloride in the presence of latices of copolymers of butyl acrylate and vinylidene chloride with and without butylene glycol dimethacrylate and styrene, copolymers of 2- ethylhexyl acrylate, vinylidene chloride and butylene glycol dimethacrylate, and copolymers of butyl acrylate, benzyl acrylate and optionally butylene glycol dimethacrylate; and the blending of vinyl chloride/vinyl acetate copolymer with butyl acrylate/vinylidene chlorride/butylene glycol dimethacrylate copolymer, and of polyvinyl chloride with a graft copolymer of methyl methacrylate and ethyl acrylate on a butyl acrylate/vinylidene chloride/butylene glycol dimethacrylate copolymer.
GB2497171A 1970-04-15 1971-04-19 Additives for the preparation of clear impact resistant vinyl chloride polymer compositions Expired GB1311246A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US2889770A 1970-04-15 1970-04-15

Publications (1)

Publication Number Publication Date
GB1311246A true GB1311246A (en) 1973-03-28

Family

ID=21846115

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2497171A Expired GB1311246A (en) 1970-04-15 1971-04-19 Additives for the preparation of clear impact resistant vinyl chloride polymer compositions

Country Status (6)

Country Link
BE (1) BE765705A (en)
CA (1) CA954646A (en)
DE (1) DE2118205A1 (en)
FR (1) FR2089655A5 (en)
GB (1) GB1311246A (en)
NL (1) NL7105042A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2584078B1 (en) * 1985-06-28 1987-11-20 Norsolor Sa COMPOSITIONS FOR THE MODIFICATION OF THERMOPLASTIC POLYMERS AND THEIR MANUFACTURING METHOD

Also Published As

Publication number Publication date
CA954646A (en) 1974-09-10
BE765705A (en) 1971-10-14
FR2089655A5 (en) 1972-01-07
DE2118205A1 (en) 1971-10-28
NL7105042A (en) 1971-10-19

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee