GB1299012A - Process for producing cationic synthetic latices - Google Patents

Process for producing cationic synthetic latices

Info

Publication number
GB1299012A
GB1299012A GB7125/70A GB712570A GB1299012A GB 1299012 A GB1299012 A GB 1299012A GB 7125/70 A GB7125/70 A GB 7125/70A GB 712570 A GB712570 A GB 712570A GB 1299012 A GB1299012 A GB 1299012A
Authority
GB
United Kingdom
Prior art keywords
basic
monomer
latices
cationic
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB7125/70A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Gas Chemical Co Inc
Original Assignee
Mitsubishi Gas Chemical Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Gas Chemical Co Inc filed Critical Mitsubishi Gas Chemical Co Inc
Publication of GB1299012A publication Critical patent/GB1299012A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52—Amides or imides
    • C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F20/60—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing nitrogen in addition to the carbonamido nitrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1299012 Cationic polymer latices MITSUBISHI GAS CHEMICAL CO Inc 13 Feb 1970 [25 Feb 1969] 7125/70 Heading C3P Stable aqueous cationic polymer latices are prepared by (a) effecting emulsion polymerization in an aqueous medium of a monomeric composition comprising (I) at least one basic N-containing monomer selected from esters of the formula CH 2 =CR 3 -COO(CH 2 ) n -NR 1 R 2 (where R 1 and R 2 individually represent H or an alkyl or hydroxyalkyl group having up to 4 C atoms, R 3 is H or methyl and n is 2 or 3) and amides of the formula CH 2 =CR 3 -CONH- (CH 2 ) n -NR 1 R 2 (where R 1 , R 2 , R 3 and n are as defined above) and (II) at least one monoethylenically unsaturated monomer which contains no basic N and/or a conjugated diene monomer which contains no basic N, the amount of monomer component (I) being from 2-10% by weight of the entire monomeric composition and the latter composition being used in a proportion of from 50-80 parts per 100 parts by weight of water, said polymerization being conducted in the presence of at least one nonionic and/or cationic surface-active agent and by means of a persulphate, inorganic peroxide or organic peroxide initiator or a redox catalyst system at a temperature of from- 5‹ to 100‹ C.; and (b) adding to the polymer dispersion so formed, preferably in an amount equivalent to that of the basic N-containing monomer, a reagent which is capable of forming a salt with the basic N-containing groups present in the polymer. The monomer (II) may be, for example, styrene or a derivative thereof, an alky or hydroxyalkyl (meth)acrylate, vinyl acetate or propionate, vinyl or vinylidene chloride, butadiene or isoprene. The salt-forming reagent in (b) may be a benzyl or alkyl halide, a dialkyl sulphate, an alkyl monochloroacetate, a mineral acid or a water-soluble aliphatic monocarboxylic acid. The cationic latices are useful as binders in the production of coated or impregnated paper, beater-sized paper, non-woven or printed fabrics, sheet-formed asbestos &c.
GB7125/70A 1969-02-25 1970-02-13 Process for producing cationic synthetic latices Expired GB1299012A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1360469 1969-02-25

Publications (1)

Publication Number Publication Date
GB1299012A true GB1299012A (en) 1972-12-06

Family

ID=11837813

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7125/70A Expired GB1299012A (en) 1969-02-25 1970-02-13 Process for producing cationic synthetic latices

Country Status (2)

Country Link
DE (1) DE2008643A1 (en)
GB (1) GB1299012A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000008077A1 (en) * 1998-08-07 2000-02-17 Reichhold, Inc. Novel latex compositions for deposition on various substrates
US7781498B2 (en) 2003-07-03 2010-08-24 Mallard Creek Polymers, Inc. Cationic latex as a carrier for bioactive ingredients and methods for making and using the same
US7981946B2 (en) 2003-07-03 2011-07-19 Mallard Creek Polymers, Inc. Antimicrobial and antistatic polymers and methods of using such polymers on various substrates
US8393334B2 (en) 2008-06-02 2013-03-12 Philip Morris Usa Inc. Smoking article with transparent section
US8785519B2 (en) 2006-08-24 2014-07-22 Mallard Creek Polymers, Inc. Anionic latex as a carrier for bioactive ingredients and methods for making and using the same
US9220725B2 (en) 2006-08-24 2015-12-29 Mallard Creek Polymers, Inc. Cationic latex as a carrier for bioactive ingredients and methods for making and using the same
US11134684B2 (en) 2005-08-24 2021-10-05 Purdue Research Foundation Method of using hydrophilized bactericidal polymers
US11421084B2 (en) 2017-05-27 2022-08-23 Poly Group LLC Dispersible antimicrobial complex and coatings therefrom
US11680116B2 (en) 2017-06-16 2023-06-20 Poly Group LLC Polymeric antimicrobial surfactant

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4031138A (en) * 1976-03-18 1977-06-21 Texaco Development Corporation Stable substituted acrylamides or methacrylamides
JPS5620009A (en) * 1979-07-27 1981-02-25 Asahi Chem Ind Co Ltd New acryl copolymer, production thereof, coating obtained therefrom and use of the coating

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000008077A1 (en) * 1998-08-07 2000-02-17 Reichhold, Inc. Novel latex compositions for deposition on various substrates
US7781498B2 (en) 2003-07-03 2010-08-24 Mallard Creek Polymers, Inc. Cationic latex as a carrier for bioactive ingredients and methods for making and using the same
US7981946B2 (en) 2003-07-03 2011-07-19 Mallard Creek Polymers, Inc. Antimicrobial and antistatic polymers and methods of using such polymers on various substrates
US11134684B2 (en) 2005-08-24 2021-10-05 Purdue Research Foundation Method of using hydrophilized bactericidal polymers
US11459415B2 (en) 2005-08-24 2022-10-04 Purdue Research Foundation Method of using hydrophilized bactericidal polymers
US8785519B2 (en) 2006-08-24 2014-07-22 Mallard Creek Polymers, Inc. Anionic latex as a carrier for bioactive ingredients and methods for making and using the same
US9220725B2 (en) 2006-08-24 2015-12-29 Mallard Creek Polymers, Inc. Cationic latex as a carrier for bioactive ingredients and methods for making and using the same
US8393334B2 (en) 2008-06-02 2013-03-12 Philip Morris Usa Inc. Smoking article with transparent section
US11421084B2 (en) 2017-05-27 2022-08-23 Poly Group LLC Dispersible antimicrobial complex and coatings therefrom
US11760844B2 (en) 2017-05-27 2023-09-19 Poly Group LLC Dispersible antimicrobial complex and coatings therefrom
US11680116B2 (en) 2017-06-16 2023-06-20 Poly Group LLC Polymeric antimicrobial surfactant

Also Published As

Publication number Publication date
DE2008643A1 (en) 1970-09-03

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee