GB1297985A - - Google Patents

Info

Publication number
GB1297985A
GB1297985A GB1297985DA GB1297985A GB 1297985 A GB1297985 A GB 1297985A GB 1297985D A GB1297985D A GB 1297985DA GB 1297985 A GB1297985 A GB 1297985A
Authority
GB
United Kingdom
Prior art keywords
reaction
june
added
alkylene oxide
reaction mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1297985A publication Critical patent/GB1297985A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/24—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran
    • C07C67/26—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran with an oxirane ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1297985 Hydroxy alkyl acrylates and methacrylates MITSUBISHI GAS CHEMICAL CO Inc 4 June 1970 [5 June 1969] 27093/70 Heading C2C In the preparation of hydroxyalkyl acrylate or methacrylate by reacting the acid with an alkylene oxide in the presence of a polymerization inhibitor and a catalyst comprising at least one trivalent iron compound at least one divalent tin compound soluble in the reaction mixture is added to the reaction mixture during or after the reaction to prevent or reduce the formation of diesters. The product is distilled to recover the ester. The tin compound may be added to terminate the reaction or after cooling and degassing to remove the alkylene oxide. Conventional polymerization inhibitors may be used and examples describe the use of ethylene, propylene or butylene oxides.
GB1297985D 1969-06-05 1970-06-04 Expired GB1297985A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4440969 1969-06-05

Publications (1)

Publication Number Publication Date
GB1297985A true GB1297985A (en) 1972-11-29

Family

ID=12690698

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1297985D Expired GB1297985A (en) 1969-06-05 1970-06-04

Country Status (3)

Country Link
DE (1) DE2027444A1 (en)
FR (1) FR2049943A5 (en)
GB (1) GB1297985A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005054356A1 (en) * 2003-12-03 2005-06-16 Basf Aktiengesellschaft Superabsorber that comprises at least one sterically hindered monovalent and/or polyvalent phenol

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3592970B2 (en) * 1999-10-07 2004-11-24 株式会社日本触媒 Method for purifying hydroxyalkyl (meth) acrylate

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005054356A1 (en) * 2003-12-03 2005-06-16 Basf Aktiengesellschaft Superabsorber that comprises at least one sterically hindered monovalent and/or polyvalent phenol

Also Published As

Publication number Publication date
DE2027444C3 (en) 1974-10-03
DE2027444B2 (en) 1974-02-14
DE2027444A1 (en) 1970-12-17
FR2049943A5 (en) 1971-03-26

Similar Documents

Publication Publication Date Title
GB1369563A (en) Polyacrylate resin compositions
GB1129096A (en) Polyester polyols and process for forming same
GB1528576A (en) Lubricants for cold working of aluminium
GB1173668A (en) Phosphate Polyhydroxy Compounds, Compositions containing the same and Scale Inhibiting use thereof
GB1513414A (en) Surface treating agent for processing of metals
GB1302999A (en)
GB1297985A (en)
GB1297986A (en)
GB1368232A (en) Azetidino-thiazolidine compounds
GB1317656A (en) Process for producing flame retardant thermosettable resins
GB1480580A (en) Transesterification of esters of acrylic or methacrylic acids
JPS5461284A (en) Copolymer emulsion and pressure-sensitive adhesive containing the same
JPS51141808A (en) Process for preparation of reactive carboxylic acid divalent metal com plexes
JPS51133227A (en) Preparation of 2-hydroxyalkyl (meth)acrylate
GB1304987A (en)
GB1164361A (en) Aqueous Emulsions of Vinyl-Type Copolymers
BE772158A (en) ESTERS OF ALPHA, BETA-UNSATURATED ACIDS AS BINDING AGENTS FOR POLYMERS CONTAINING AN ALKALINE METAL
GB1355529A (en) Acrylonitrile copolymers
ES407563A1 (en) Coating materials for enteric medicaments
GB1374360A (en) Transesterification of quinoxaline-2-carboxylic acid esters
GB1001715A (en) Process for the manufacture of dispersions of homo-and copolymers of acrylic acid esters and methacrylic acid esters having positively charged latex particles
GB1140087A (en) Esters of itaconic acid
FR2018870A1 (en) Mercaptoalkyl esters of phenol carboxylic acids (i) - useful as polymer stabilisers
GB1343409A (en) Preparation of l-a-hydrazino-beta-phenylpropionic acid compounds
ES340783A1 (en) Addition copolymers for use in surface coating compositions and compositions containing these copolymers

Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee