GB1304987A - - Google Patents
Info
- Publication number
- GB1304987A GB1304987A GB2332171*A GB2332171A GB1304987A GB 1304987 A GB1304987 A GB 1304987A GB 2332171 A GB2332171 A GB 2332171A GB 1304987 A GB1304987 A GB 1304987A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- itaconic
- sodium
- citraconic
- maleic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/30—Compositions for temporarily or permanently fixing teeth or palates, e.g. primers for dental adhesives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- A61K6/889—Polycarboxylate cements; Glass ionomer cements
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/90—Compositions for taking dental impressions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
Landscapes
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Veterinary Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Dental Preparations (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1304987 Water-soluble acrylic copolymer dental cements PENNWALT CORP 19 April 1971 [10 March 1970] 23321/71 Heading C3P Dental cements comprise (1) zinc oxide and (2) water-soluble acrylic copolymers of molecular weight 20,000 to 75,000 and containing 10 to 90 mole per cent of acrylic acid units, 0 to 5 mole per cent of C 1-8 alkyl acrylate units and the balance of units of glutaconic, aconitic, citraconic, mesaconic, itaconic, fumaric, maleic or tiglic acid. The copolymers may be prepared by copolymerization in aqueous media in the presence of a peroxide or redox catalyst, and solutions of the polymers in water and/or mono- or polyhydric alcohols may be mixed with zinc oxide to give dental cements, which may also contain magnesium, silicon, bismuth, barium, calcium or aluminium oxides, barium sulphate, sodium fluoride, calcium tungstate, sodium chloride, sodium iodide, sodium sulphate or sodium phosphate. In examples acrylic acid is copolymerized with (1) itaconic acid and (2) itaconic and maleic acids in the presence of ammonium persulphate, with (3) citraconic acid in the presence of hydrogen peroxide, ferrous sulphate and ascorbic acid, with (4) itaconic acid in the presence of potassium persulphate and sodium bisulphite, and with (5) glutaconic acid, mesaconic acid, aconitic acid, citraconic acid, tiglic acid, itaconic acid/maleic acid, itaconic acid/butyl acrylate, itaconic acid/ 2-ethylhexyl acrylate, citraconic acid/aconitic acid/maleic acid, glutaconic acid/itaconic acid/ ethyl acrylate and citraconic acid/itaconic acid/ methyl acrylate; the products being converted to dental cements by mixing with 90 : 10 zinc oxide/magnesium oxide containing small amounts of aluminium oxide, barium sulphate and calcium tungstate.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US1831970A | 1970-03-10 | 1970-03-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1304987A true GB1304987A (en) | 1973-01-31 |
Family
ID=21787331
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2332171*A Expired GB1304987A (en) | 1970-03-10 | 1971-04-19 |
Country Status (6)
Country | Link |
---|---|
JP (1) | JPS546838B1 (en) |
CH (1) | CH529559A (en) |
DE (1) | DE2110665C2 (en) |
FR (1) | FR2084344A5 (en) |
GB (1) | GB1304987A (en) |
SE (1) | SE375690B (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5624976A (en) * | 1994-03-25 | 1997-04-29 | Dentsply Gmbh | Dental filling composition and method |
US5876210A (en) | 1994-04-22 | 1999-03-02 | Dentsply G.M.B.H. | Dental polymer product |
US5998499A (en) | 1994-03-25 | 1999-12-07 | Dentsply G.M.B.H. | Liquid crystalline (meth)acrylate compounds, composition and method |
US6369164B1 (en) | 1993-05-26 | 2002-04-09 | Dentsply G.M.B.H. | Polymerizable compounds and compositions |
EP2070507A1 (en) * | 2007-12-14 | 2009-06-17 | Dentsply DeTrey GmbH | Hardening composition |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2101889C2 (en) * | 1971-01-15 | 1982-01-28 | ESPE Fabrik pharmazeutischer Präparate GmbH, 8031 Seefeld | Mixing component for medical silicate cements |
DE2101939C3 (en) * | 1971-01-15 | 1980-01-31 | Espe Fabrik Pharmazeutischer Praeparate Gmbh, 8031 Seefeld | Compounds hardening by adding zinc oxide |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3055873A (en) * | 1960-07-27 | 1962-09-25 | Pfizer & Co C | Preparation of polyitaconic acid |
US3308067A (en) * | 1963-04-01 | 1967-03-07 | Procter & Gamble | Polyelectrolyte builders and detergent compositions |
US3493500A (en) * | 1966-10-20 | 1970-02-03 | Dow Chemical Co | Acrylic acid polymers |
-
1971
- 1971-03-04 CH CH318871A patent/CH529559A/en not_active IP Right Cessation
- 1971-03-05 DE DE2110665A patent/DE2110665C2/en not_active Expired
- 1971-03-09 FR FR7108047A patent/FR2084344A5/fr not_active Expired
- 1971-03-09 SE SE7103023A patent/SE375690B/xx unknown
- 1971-03-10 JP JP1254271A patent/JPS546838B1/ja active Pending
- 1971-04-19 GB GB2332171*A patent/GB1304987A/en not_active Expired
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6339114B1 (en) | 1993-05-26 | 2002-01-15 | Dentsply Detrey Gmbh | Liquid crystalline (meth)acrylate compounds, composition and method |
US6369164B1 (en) | 1993-05-26 | 2002-04-09 | Dentsply G.M.B.H. | Polymerizable compounds and compositions |
US5624976A (en) * | 1994-03-25 | 1997-04-29 | Dentsply Gmbh | Dental filling composition and method |
US5998499A (en) | 1994-03-25 | 1999-12-07 | Dentsply G.M.B.H. | Liquid crystalline (meth)acrylate compounds, composition and method |
US5876210A (en) | 1994-04-22 | 1999-03-02 | Dentsply G.M.B.H. | Dental polymer product |
EP2070507A1 (en) * | 2007-12-14 | 2009-06-17 | Dentsply DeTrey GmbH | Hardening composition |
WO2009077113A2 (en) * | 2007-12-14 | 2009-06-25 | Dentsply Detrey Gmbh | Hardening composition |
WO2009077113A3 (en) * | 2007-12-14 | 2009-09-17 | Dentsply Detrey Gmbh | Hardening composition |
JP2011506367A (en) * | 2007-12-14 | 2011-03-03 | デンツプライ デトレイ ゲー.エム.ベー.ハー. | Curing composition |
US20110071233A1 (en) * | 2007-12-14 | 2011-03-24 | Gordon Blackwell | Hardening composition |
US8440740B2 (en) | 2007-12-14 | 2013-05-14 | Dentsply International Inc. | Dental glass compositions utilizing a glass ionomer and an acidic copolymer |
AU2008337890B2 (en) * | 2007-12-14 | 2014-02-06 | Dentsply Detrey Gmbh | Hardening composition |
Also Published As
Publication number | Publication date |
---|---|
DE2110665C2 (en) | 1984-06-07 |
SE375690B (en) | 1975-04-28 |
JPS546838B1 (en) | 1979-04-02 |
DE2110665A1 (en) | 1971-09-23 |
CH529559A (en) | 1972-10-31 |
FR2084344A5 (en) | 1971-12-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |