GB1291191A - Process for the isomerization and disproportioning of methyl phenols - Google Patents

Process for the isomerization and disproportioning of methyl phenols

Info

Publication number
GB1291191A
GB1291191A GB94370A GB94370A GB1291191A GB 1291191 A GB1291191 A GB 1291191A GB 94370 A GB94370 A GB 94370A GB 94370 A GB94370 A GB 94370A GB 1291191 A GB1291191 A GB 1291191A
Authority
GB
United Kingdom
Prior art keywords
isomerization
disproportioning
dimethylphenol
methyl
phenol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB94370A
Inventor
Matthias Thoma
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chemische Werke Lowi GmbH
Original Assignee
Chemische Werke Lowi GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemische Werke Lowi GmbH filed Critical Chemische Werke Lowi GmbH
Priority to GB94370A priority Critical patent/GB1291191A/en
Publication of GB1291191A publication Critical patent/GB1291191A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by exchange of hydrocarbon groups, which may be substituted, from the same of other compounds, e.g. transalkylation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1291191 Isomerization and disproportionation of methyl phenol CHEMISCHE WEEK LOWI GmbH 8 Jan 1970 943/70 Heading C2C A process for the conversion to cresols of methylphenols with more than one methyl substituent, in the liquid phase, comprises heating the methylated phenols in the presence of phenol with an aluminium phenolate, -methylate or aluminium oxide catalyst at 340-400‹ C. over a period of hours at a pressure of 15-50 atmospheres. In the examples, 2,6-dimethylphenol and 2,4,6-trimethylphenol are demethylated to orthocresol and 2,4-dimethylphenol.
GB94370A 1970-01-08 1970-01-08 Process for the isomerization and disproportioning of methyl phenols Expired GB1291191A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB94370A GB1291191A (en) 1970-01-08 1970-01-08 Process for the isomerization and disproportioning of methyl phenols

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB94370A GB1291191A (en) 1970-01-08 1970-01-08 Process for the isomerization and disproportioning of methyl phenols

Publications (1)

Publication Number Publication Date
GB1291191A true GB1291191A (en) 1972-10-04

Family

ID=9713245

Family Applications (1)

Application Number Title Priority Date Filing Date
GB94370A Expired GB1291191A (en) 1970-01-08 1970-01-08 Process for the isomerization and disproportioning of methyl phenols

Country Status (1)

Country Link
GB (1) GB1291191A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4060560A (en) * 1976-03-26 1977-11-29 Continental Oil Company Disproportionation of xylenols with phenol to form cresols
US4071566A (en) * 1976-01-22 1978-01-31 Continental Oil Company Preparation of cresols and xylenols from tetramethylphenols and pentamethylphenol
US4547593A (en) * 1984-03-26 1985-10-15 Ethyl Corporation Preparation of (hydrocarbylthio)phenols

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4071566A (en) * 1976-01-22 1978-01-31 Continental Oil Company Preparation of cresols and xylenols from tetramethylphenols and pentamethylphenol
US4060560A (en) * 1976-03-26 1977-11-29 Continental Oil Company Disproportionation of xylenols with phenol to form cresols
US4547593A (en) * 1984-03-26 1985-10-15 Ethyl Corporation Preparation of (hydrocarbylthio)phenols
JPS60218370A (en) * 1984-03-26 1985-11-01 エシル　コーポレーシヨン Manufacture of (hydrocarbylthio)phenol
JPS6340782B2 (en) * 1984-03-26 1988-08-12 Ethyl Corp

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees