GB1291191A - Process for the isomerization and disproportioning of methyl phenols - Google Patents
Process for the isomerization and disproportioning of methyl phenolsInfo
- Publication number
- GB1291191A GB1291191A GB94370A GB94370A GB1291191A GB 1291191 A GB1291191 A GB 1291191A GB 94370 A GB94370 A GB 94370A GB 94370 A GB94370 A GB 94370A GB 1291191 A GB1291191 A GB 1291191A
- Authority
- GB
- United Kingdom
- Prior art keywords
- isomerization
- disproportioning
- dimethylphenol
- methyl
- phenol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by exchange of hydrocarbon groups, which may be substituted, from the same of other compounds, e.g. transalkylation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1291191 Isomerization and disproportionation of methyl phenol CHEMISCHE WEEK LOWI GmbH 8 Jan 1970 943/70 Heading C2C A process for the conversion to cresols of methylphenols with more than one methyl substituent, in the liquid phase, comprises heating the methylated phenols in the presence of phenol with an aluminium phenolate, -methylate or aluminium oxide catalyst at 340-400‹ C. over a period of hours at a pressure of 15-50 atmospheres. In the examples, 2,6-dimethylphenol and 2,4,6-trimethylphenol are demethylated to orthocresol and 2,4-dimethylphenol.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB94370A GB1291191A (en) | 1970-01-08 | 1970-01-08 | Process for the isomerization and disproportioning of methyl phenols |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB94370A GB1291191A (en) | 1970-01-08 | 1970-01-08 | Process for the isomerization and disproportioning of methyl phenols |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1291191A true GB1291191A (en) | 1972-10-04 |
Family
ID=9713245
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB94370A Expired GB1291191A (en) | 1970-01-08 | 1970-01-08 | Process for the isomerization and disproportioning of methyl phenols |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1291191A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4060560A (en) * | 1976-03-26 | 1977-11-29 | Continental Oil Company | Disproportionation of xylenols with phenol to form cresols |
US4071566A (en) * | 1976-01-22 | 1978-01-31 | Continental Oil Company | Preparation of cresols and xylenols from tetramethylphenols and pentamethylphenol |
US4547593A (en) * | 1984-03-26 | 1985-10-15 | Ethyl Corporation | Preparation of (hydrocarbylthio)phenols |
-
1970
- 1970-01-08 GB GB94370A patent/GB1291191A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4071566A (en) * | 1976-01-22 | 1978-01-31 | Continental Oil Company | Preparation of cresols and xylenols from tetramethylphenols and pentamethylphenol |
US4060560A (en) * | 1976-03-26 | 1977-11-29 | Continental Oil Company | Disproportionation of xylenols with phenol to form cresols |
US4547593A (en) * | 1984-03-26 | 1985-10-15 | Ethyl Corporation | Preparation of (hydrocarbylthio)phenols |
JPS60218370A (en) * | 1984-03-26 | 1985-11-01 | エシル コーポレーシヨン | Manufacture of (hydrocarbylthio)phenol |
JPS6340782B2 (en) * | 1984-03-26 | 1988-08-12 | Ethyl Corp |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PLNP | Patent lapsed through nonpayment of renewal fees |