GB1111751A - Process for the arylalkylation of phenols - Google Patents
Process for the arylalkylation of phenolsInfo
- Publication number
- GB1111751A GB1111751A GB3766A GB3766A GB1111751A GB 1111751 A GB1111751 A GB 1111751A GB 3766 A GB3766 A GB 3766A GB 3766 A GB3766 A GB 3766A GB 1111751 A GB1111751 A GB 1111751A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phenols
- reaction
- styrene
- arylalkylation
- aralkene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002989 phenols Chemical class 0.000 title abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- GEVPUGOOGXGPIO-UHFFFAOYSA-N oxalic acid;dihydrate Chemical compound O.O.OC(=O)C(O)=O GEVPUGOOGXGPIO-UHFFFAOYSA-N 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
- C07C37/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon unsaturated bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Phenols are aralkylated by heating with an aralkene in presence of 0.2-4 wt. per cent of catalyst consisting solely of oxalic acid dihydrate, and distilling off unused starting materials and the reaction products. Examples describe the reaction of phenol with styrene or alphamethylstyrene, and the reaction of resorcinol with styrene.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3766A GB1111751A (en) | 1966-01-03 | 1966-01-03 | Process for the arylalkylation of phenols |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3766A GB1111751A (en) | 1966-01-03 | 1966-01-03 | Process for the arylalkylation of phenols |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1111751A true GB1111751A (en) | 1968-05-01 |
Family
ID=9697265
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3766A Expired GB1111751A (en) | 1966-01-03 | 1966-01-03 | Process for the arylalkylation of phenols |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1111751A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4320235A (en) | 1979-12-14 | 1982-03-16 | Basf Aktiengesellschaft | Preparation of 1-(aralkyl)-2-naphthols |
US4950810A (en) * | 1988-03-30 | 1990-08-21 | Yoshitomi Pharmaceutical Industries, Ltd. | Selective process for preparting 2,4- or 3,6-di-substituted phenol compounds |
WO2009009481A3 (en) * | 2007-07-06 | 2009-02-26 | Chemtura Corp | Liquid styrenated phenolic compositions and processes for forming same |
US7902280B2 (en) | 2007-02-26 | 2011-03-08 | Chemtura Corporation | Liquid styrenated phenolic compositions and processes for forming same |
-
1966
- 1966-01-03 GB GB3766A patent/GB1111751A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4320235A (en) | 1979-12-14 | 1982-03-16 | Basf Aktiengesellschaft | Preparation of 1-(aralkyl)-2-naphthols |
US4950810A (en) * | 1988-03-30 | 1990-08-21 | Yoshitomi Pharmaceutical Industries, Ltd. | Selective process for preparting 2,4- or 3,6-di-substituted phenol compounds |
US7902280B2 (en) | 2007-02-26 | 2011-03-08 | Chemtura Corporation | Liquid styrenated phenolic compositions and processes for forming same |
WO2009009481A3 (en) * | 2007-07-06 | 2009-02-26 | Chemtura Corp | Liquid styrenated phenolic compositions and processes for forming same |
RU2470067C2 (en) * | 2007-07-06 | 2012-12-20 | Кемтура Корпорейшн | Liquid composition of styrene-containing phenol compounds and methods for production thereof |
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