GB1285197A - Liquid hydrocarbon fuels - Google Patents

Liquid hydrocarbon fuels

Info

Publication number
GB1285197A
GB1285197A GB49834/69A GB4983469A GB1285197A GB 1285197 A GB1285197 A GB 1285197A GB 49834/69 A GB49834/69 A GB 49834/69A GB 4983469 A GB4983469 A GB 4983469A GB 1285197 A GB1285197 A GB 1285197A
Authority
GB
United Kingdom
Prior art keywords
polymer
ethyl hexyl
vinyl
hexyl acrylate
groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB49834/69A
Inventor
Desmond Wilfrid John Osmond
Norman Douglas Patrick Smith
Frederick Andrew Waite
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE757347D priority Critical patent/BE757347R/en
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB49834/69A priority patent/GB1285197A/en
Priority to CA094,700A priority patent/CA1005985A/en
Priority to IE1271/70A priority patent/IE34616B1/en
Priority to ZA706749A priority patent/ZA706749B/en
Priority to DE2049495A priority patent/DE2049495C3/en
Priority to JP45088412A priority patent/JPS5015003B1/ja
Priority to NL7014833A priority patent/NL7014833A/xx
Priority to FR707036668A priority patent/FR2066925B2/fr
Priority to CH1497870A priority patent/CH552050A/en
Priority to ES384400A priority patent/ES384400A2/en
Publication of GB1285197A publication Critical patent/GB1285197A/en
Priority to US05/349,942 priority patent/US4002436A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/146—Macromolecular compounds according to different macromolecular groups, mixtures thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/20—Organic compounds containing halogen
    • C10L1/206—Organic compounds containing halogen macromolecular compounds
    • C10L1/207—Organic compounds containing halogen macromolecular compounds containing halogen with or without hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/20—Organic compounds containing halogen
    • C10L1/206—Organic compounds containing halogen macromolecular compounds
    • C10L1/208—Organic compounds containing halogen macromolecular compounds containing halogen, oxygen, with or without hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/236—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2462—Organic compounds containing sulfur, selenium and/or tellurium macromolecular compounds
    • C10L1/2468—Organic compounds containing sulfur, selenium and/or tellurium macromolecular compounds obtained by reactions involving only carbon to carbon unsaturated bonds; derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/26—Organic compounds containing phosphorus
    • C10L1/2666—Organic compounds containing phosphorus macromolecular compounds
    • C10L1/2675—Organic compounds containing phosphorus macromolecular compounds obtained by reactions involving only carbon to carbon unsaturated bonds; derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

1285197 Liquid hydrocarbon fuels IMPERIAL CHEMICAL INDUSTRIES Ltd 2 Oct 1970 [10 Oct 1969] 49834/69 Heading C5G The tendency of hydrocarbon fuels of flash point at least 90‹ F. and suitable for aircraft gas turbines to particulate dissemination on shock is reduced by the presence, in solution in the fuel, of polymer of viscosity average molecular weight greater than 10<SP>6</SP> or of intrinsic viscosity greater than 2À5 dls./gm in a concentration such that there is molecular overlap of the polymer molecules in the liquid; the polymer containing polar groups which form inter-molecular associative bonds arising from electrostatic attraction between polar and/or dipolar charges in the polar groups and the energy of the bonds being at least that corresponding to the energy of hydrogen bonds formed in the liquid hydrocarbon fuel between -OH groups of ROH reacting with -O- groups of ROR<SP>1</SP> (where R and R<SP>1</SP> are alkyl) but less than that of a typical C-C co-valent bond. Suitable polymers are free radical addition or condensation polymers and contain at least 10 polar groups per molecule of polymer and are used in an amount to provide 10<SP>-7</SP>-10<SP>-4</SP> gm moles of polar groups per gram of fuel. In the examples the polymers used are copolymers of 2-ethyl hexyl acrylate with acrylic acid, acrylonitrile or hydroxyethyl methacrylate; of C 12-14 alkyl methacrylate, vinyl octoate or vinyl isobutylene ether with acrylic acid; polystyrene of molecular weight 2 x 10<SP>6</SP> alkylated with octene-1 and then treated with oleum to introduce sulphonic acid groups into the polymer and which can be converted to the sodium salt by treatment with sodium methoxide; copolymer of 2-ethyl hexyl acrylate with vinyl pyridine which can be used together with acid-containing polymer solutions or heated with propane sultone, #-propiolactone, or benzyl chloride; copolymer of 2-ethyl hexyl acrylate and vinyl chlor-acetate which can be heated with triethylamine; or copolymer of 2-ethyl hexyl acrylate and glycidyl acrylate which is reacted with sulphuric or phosphoric acid, and then with calcium octoates to produce the calcium salt.
GB49834/69A 1969-10-10 1969-10-10 Liquid hydrocarbon fuels Expired GB1285197A (en)

Priority Applications (12)

Application Number Priority Date Filing Date Title
BE757347D BE757347R (en) 1969-10-10 PROCEDURE FOR PREVENTING THE SPILLAGE OF A
GB49834/69A GB1285197A (en) 1969-10-10 1969-10-10 Liquid hydrocarbon fuels
CA094,700A CA1005985A (en) 1969-10-10 1970-10-02 Polymer solution
IE1271/70A IE34616B1 (en) 1969-10-10 1970-10-02 Liquid hydrocarbon fuels
ZA706749A ZA706749B (en) 1969-10-10 1970-10-05 Polymer solution
DE2049495A DE2049495C3 (en) 1969-10-10 1970-10-08 Liquid gas turbine aircraft fuel
JP45088412A JPS5015003B1 (en) 1969-10-10 1970-10-09
NL7014833A NL7014833A (en) 1969-10-10 1970-10-09
FR707036668A FR2066925B2 (en) 1969-10-10 1970-10-09
CH1497870A CH552050A (en) 1969-10-10 1970-10-09 HYDROCARBON FUEL.
ES384400A ES384400A2 (en) 1969-10-10 1970-10-10 Liquid hydrocarbon fuels
US05/349,942 US4002436A (en) 1969-10-10 1973-04-11 Polymer solution

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB49834/69A GB1285197A (en) 1969-10-10 1969-10-10 Liquid hydrocarbon fuels

Publications (1)

Publication Number Publication Date
GB1285197A true GB1285197A (en) 1972-08-09

Family

ID=10453726

Family Applications (1)

Application Number Title Priority Date Filing Date
GB49834/69A Expired GB1285197A (en) 1969-10-10 1969-10-10 Liquid hydrocarbon fuels

Country Status (11)

Country Link
JP (1) JPS5015003B1 (en)
BE (1) BE757347R (en)
CA (1) CA1005985A (en)
CH (1) CH552050A (en)
DE (1) DE2049495C3 (en)
ES (1) ES384400A2 (en)
FR (1) FR2066925B2 (en)
GB (1) GB1285197A (en)
IE (1) IE34616B1 (en)
NL (1) NL7014833A (en)
ZA (1) ZA706749B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0019390A1 (en) * 1979-05-10 1980-11-26 Imperial Chemical Industries Plc Modification of a hydrocarbon fuel by dissolving in it a specified copolymer of tert-butylstyrene in conjunction with a hydroxylic liquid and an amino compound
US4770814A (en) * 1983-08-31 1988-09-13 The Dow Chemical Company Shear stable antimisting formulations
US4880565A (en) * 1983-08-31 1989-11-14 The Dow Chemical Company Fluorine containing viscoelastic surfactants

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59105087A (en) * 1982-12-01 1984-06-18 ザ・ダウ・ケミカル・カンパニ− Mist generation control additive for hydrocarbon fluid

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0019390A1 (en) * 1979-05-10 1980-11-26 Imperial Chemical Industries Plc Modification of a hydrocarbon fuel by dissolving in it a specified copolymer of tert-butylstyrene in conjunction with a hydroxylic liquid and an amino compound
US4770814A (en) * 1983-08-31 1988-09-13 The Dow Chemical Company Shear stable antimisting formulations
US4880565A (en) * 1983-08-31 1989-11-14 The Dow Chemical Company Fluorine containing viscoelastic surfactants

Also Published As

Publication number Publication date
FR2066925B2 (en) 1973-01-12
DE2049495B2 (en) 1974-01-03
DE2049495A1 (en) 1971-04-29
BE757347R (en) 1971-04-09
JPS5015003B1 (en) 1975-06-02
NL7014833A (en) 1971-04-14
CH552050A (en) 1974-07-31
CA1005985A (en) 1977-03-01
ES384400A2 (en) 1973-03-01
IE34616L (en) 1971-04-10
ZA706749B (en) 1971-07-28
DE2049495C3 (en) 1974-08-08
FR2066925A2 (en) 1971-08-13
IE34616B1 (en) 1975-06-25

Similar Documents

Publication Publication Date Title
US3723375A (en) Novel anhydride interpolymers
ES2053711T3 (en) SOLID POLYMERIC ELECTROLYTE AND ELECTROCHEMICAL GENERATORS THAT CONTAIN IT.
GB1122397A (en) Polymer dispersion and dispersants
GB1277767A (en) Method of preparing bead-type polymers
GB1318241A (en) Distillate fuel oil containing wax crystal modifiers
ATE57956T1 (en) USE OF ALKOXYLATED POLYMERISATS CONTAINING CARBOXYL GROUPS IN DETERGENTS.
GB1337288A (en) Polymer solution
FI860373A (en) Preparation of a graft copolymer compatibilizer useful as an oil additive
GB1285197A (en) Liquid hydrocarbon fuels
GB725980A (en) Improvements in or relating to an insoluble anion-exchange resin
KR880000484A (en) Graft Polymers of Polyphenylene Ether
ES2219418T3 (en) PROCEDURE FOR OBTAINING HYDROSOLUBBLE POLYMERS, WHICH CONTAIN SIDE CHAINS OF POLYCHYLENGLYCOLIC ETERS.
GB646713A (en) Process for imidizing polyacrylamides
US3340238A (en) Method for producing polymers of vinyl aromatic sulfonates characterized useful as flocculants
US4002436A (en) Polymer solution
GB1143404A (en) Polymer dispersion
MX3287E (en) IMPROVED PROCEDURE FOR PREPARING VESICULATED POLY ESTER RESIN GRANULES
Harwood et al. Imposed polyelectrolyte behavior of poly (m-phenyleneisophthalamide) in LiCl/dimethylacetamide
GB886823A (en) Compositions for the production of articles having high impact and notch impact strength
GB1196248A (en) Aqueous Solids Dispersions
US3308102A (en) Polysulfone flocculants
SU682531A1 (en) Copolymer of methacrylic acid, sodium methacrylate, alkylated and non-alkylated alkylaminoalkyl(meth)acrylate as waterproofing agent
SU151818A1 (en) The method of producing copolymers
GB995283A (en) Treatment of n-vinylpyrrolidinone polymers
Kurenkov et al. Radical copolymerization of sodium 2-acrylamido-2-methylpropane sulfonate and sodium acrylate in water-alcohol solutions

Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years