GB1282887A - Acylation of nitrogen-containing products - Google Patents

Acylation of nitrogen-containing products

Info

Publication number
GB1282887A
GB1282887A GB30409/69A GB3040969A GB1282887A GB 1282887 A GB1282887 A GB 1282887A GB 30409/69 A GB30409/69 A GB 30409/69A GB 3040969 A GB3040969 A GB 3040969A GB 1282887 A GB1282887 A GB 1282887A
Authority
GB
United Kingdom
Prior art keywords
diamine
oxide
ethylene
propylene
acids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB30409/69A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lubrizol Corp
Original Assignee
Lubrizol Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lubrizol Corp filed Critical Lubrizol Corp
Publication of GB1282887A publication Critical patent/GB1282887A/en
Expired legal-status Critical Current

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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/18—Use of additives to fuels or fires for particular purposes use of detergents or dispersants for purposes not provided for in groups C10L10/02 - C10L10/16
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D247/00—Heterocyclic compounds containing rings having two nitrogen atoms as the only ring hetero atoms, according to more than one of groups C07D229/00 - C07D245/00
    • C07D247/02—Heterocyclic compounds containing rings having two nitrogen atoms as the only ring hetero atoms, according to more than one of groups C07D229/00 - C07D245/00 having the nitrogen atoms in positions 1 and 3
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    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/221—Organic compounds containing nitrogen compounds of uncertain formula; reaction products where mixtures of compounds are obtained
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    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
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    • C10M2203/02—Well-defined aliphatic compounds
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    • C10M2203/02—Well-defined aliphatic compounds
    • C10M2203/022—Well-defined aliphatic compounds saturated
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives

Abstract

1282887 Polyolefin derivatives LUBRIZOL CORP 16 June 1969 [3 July 1968] 30409/69 Heading C3P [Also in Divisions C4-C5] Polyolefin derivatives suitable as dispersants for lubricating and fuel oils may be prepared by reacting (I) polyolefin substituted mono- or polycarboxylic acylating agents with (II) not more than one mole per equivalent of I of where R is an organic radical of valence n + 1 or, where n is 1, may be a direct linkage, and n is 1 to 3; X<SP>1</SP> and X<SP>11</SP> are independently O= or R 1 N=; when X<SP>1</SP> is O = then Y is or where m is 0 or 1 to 8; when X<SP>1</SP> is R 1 N= then R 1 is -(R<SP>11</SP>-NR<SP>1</SP>)m-R<SP>11</SP>-NR<SP>1</SP>R<SP>1</SP> and Y is -NR<SP>1</SP>-(R<SP>11</SP>-NR<SP>1</SP>) m -R<SP>11</SP>-NR<SP>1</SP>R<SP>1</SP> or R 1 and Y together form where q is 0 or 1 to 8; when X<SP>11</SP> is O = then Z is O-M<SP>+</SP>, halo, alkoxy or Y as defined when X<SP>1</SP> is O = and M<SP>+</SP> is the cation of an amine; when X<SP>11</SP> R 1 N = then Z and R 1 are as Y and R 1 when X<SP>1</SP> is R 1 N=; when X<SP>1</SP> and X<SP>11</SP> are both O= and R separates the attached groups by 2 or 3 carbon atoms then Y and Z taken together can be where R<SP>1</SP> is hydrogen, C 1-10 hydrocarbyl or -(R<SP>11</SP>-O) r -H where r is 1 to 10, the reactant containing at least one such group per molecule; and R<SP>11</SP> is C 1-10 hydrocarbylene. Preferred reactants (I) are derived from maleic and fumaric acids and maleic anhydride; and polypropylene, polyisobutylene or propylene/isobutylene copolymers and their chlorinated derivatives; and preferred reactants (II) are derived from alkylene dicarboxylic acids and alkylene polyamines containing at least one hydroxy-alkyl group, or alkylene polyamines and an alkylene oxide or epihalohydrin. The products may be after treated with aliphatic acids, aliphatic aldehydes or epoxides. Many suitable starting materials are specified and examples describe the preparation of products from (T) polyisobutenyl succinic anhydride, polypropenyl succinic anhydride, polyisobutenyl acrylic acid and isobutylene/propylene copolymer substituted succinic anhydride; (II) reaction products of adipic, malonic, glutaric, sebacic, terephthalic, diglycolic, iminodiacetic, 1,4-phenylene diacetic and azelaic acids with N- hydroxyethyl ethylene diamine, N-hydroxypropyl propylene diamine, N- hydroxypropyl ethylene diamine, N-(4-hydroxyoctyl) ethylene diamine, N-(3-hydroxy-heptyl) tetramethylene diamine, N - (3 - hydroxypentyl) trimethylene diamine, N - (2 - hydroxyheptyl) tetramethylene diamine, N - (2 - hydroxy - 2 - phenylethyl) ethylene diamine, N - (2 - tolyl - 3- hydroxypropyl) propylene diamine, and reaction products of ethylene diamine/ethylene oxide, tetraethylene pentamine/ethylene oxide, diethylene triamine/triethylene tetramine-/ethylene oxide/propylene oxide, tetraethylene pentamine/epichlorohydrin, ethylene polyamines/ propylene oxide, diethylene triamine/styrene oxide and triethylene tetramine/styrene oxide; optionally post-reacted with propylene oxide, formic acid, formaldehyde and butyraldehyde.
GB30409/69A 1968-07-03 1969-06-16 Acylation of nitrogen-containing products Expired GB1282887A (en)

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US87558069A 1969-11-10 1969-11-10

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FR2012253A1 (en) 1970-03-13

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