GB1281508A - Production of uranium dioxide - Google Patents

Production of uranium dioxide

Info

Publication number
GB1281508A
GB1281508A GB30139/70A GB3013970A GB1281508A GB 1281508 A GB1281508 A GB 1281508A GB 30139/70 A GB30139/70 A GB 30139/70A GB 3013970 A GB3013970 A GB 3013970A GB 1281508 A GB1281508 A GB 1281508A
Authority
GB
United Kingdom
Prior art keywords
uranium
steam
hydrogen
moles
hexafluoride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB30139/70A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CBS Corp
Original Assignee
Westinghouse Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Westinghouse Electric Corp filed Critical Westinghouse Electric Corp
Publication of GB1281508A publication Critical patent/GB1281508A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G43/00Compounds of uranium
    • C01G43/01Oxides; Hydroxides
    • C01G43/025Uranium dioxide
    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21CNUCLEAR REACTORS
    • G21C3/00Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
    • G21C3/42Selection of substances for use as reactor fuel
    • G21C3/58Solid reactor fuel Pellets made of fissile material
    • G21C3/62Ceramic fuel
    • G21C3/623Oxide fuels
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/62Submicrometer sized, i.e. from 0.1-1 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/10Solid density
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/12Surface area
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/80Compositional purity
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00Energy generation of nuclear origin
    • Y02E30/30Nuclear fission reactors

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Plasma & Fusion (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

1281508 Uranium dioxide from hexafluoride WESTINGHOUSE ELECTRIC CORP 22 June 1970 [18 July 1969] 30139/70 Heading C1A A process for converting uranium hexafluoride to uranium dioxide comprises reacting uranium hexafluoride with steam and hydrogen in the molar proportion of 1:2-8:1-8 respectively in a fluidized bed containing uranyl fluoride and uranium oxide and heated at 475-600‹ C., mixing the reaction products, comprising UO 2 F 2 and U 3 O 8 , with additional steam and hydrogen to provide 4-12 moles steam and 1-6 moles hydrogen per mole of uranium in a second fluidized bed heated at 575-650‹ C., passing the reaction products to a third fluidized bed and reacting with further steam and hydrogen to provide 2-11 moles steam and 0À5-6 moles hydrogen per mole of uranium, and heating at 575-650‹ C.: the uranium dioxide so formed is capable of being formed into pellets having a density of 90-96% of theoretical; recovery is greater than 99À9% uranium. The residual fluorine content may be 0À011-0À015% wt. If desired for a higher purity product a fourth and subsequent fluid bed can be employed under conditions similar to that in the third bed. Reference has been directed by the Comptroller to Specification 1,210,057.
GB30139/70A 1969-07-18 1970-06-22 Production of uranium dioxide Expired GB1281508A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US84306269A 1969-07-18 1969-07-18

Publications (1)

Publication Number Publication Date
GB1281508A true GB1281508A (en) 1972-07-12

Family

ID=25288982

Family Applications (1)

Application Number Title Priority Date Filing Date
GB30139/70A Expired GB1281508A (en) 1969-07-18 1970-06-22 Production of uranium dioxide

Country Status (11)

Country Link
AT (1) AT301488B (en)
BE (1) BE753410A (en)
CA (1) CA926583A (en)
CH (1) CH546207A (en)
DE (1) DE2033433A1 (en)
ES (1) ES381726A1 (en)
FI (1) FI51166C (en)
FR (1) FR2051856B1 (en)
GB (1) GB1281508A (en)
NL (1) NL7010016A (en)
SE (1) SE357948B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5723100A (en) * 1994-06-03 1998-03-03 British Nuclear Fuels Plc Uranium oxide production

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4020146A (en) * 1969-07-18 1977-04-26 Westinghouse Electric Corporation Production of uranium dioxide
US3808145A (en) * 1971-11-03 1974-04-30 Gen Electric Ceramic defluorination and reduction process
US4053559A (en) * 1976-06-14 1977-10-11 Westinghouse Electric Corporation Production of uranium dioxide
DE2951451A1 (en) * 1979-12-20 1981-07-16 Alkem Gmbh, 6450 Hanau METHOD FOR PRODUCING NUCLEAR FUEL OXIDS

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5723100A (en) * 1994-06-03 1998-03-03 British Nuclear Fuels Plc Uranium oxide production

Also Published As

Publication number Publication date
NL7010016A (en) 1971-01-20
CA926583A (en) 1973-05-22
AT301488B (en) 1972-09-11
FI51166B (en) 1976-08-02
ES381726A1 (en) 1972-11-16
FR2051856A1 (en) 1971-04-09
CH546207A (en) 1974-02-28
BE753410A (en) 1970-12-16
DE2033433A1 (en) 1971-02-04
FI51166C (en) 1976-11-10
SE357948B (en) 1973-07-16
FR2051856B1 (en) 1974-08-09

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee