GB1277541A - Bleaching method and product thereof - Google Patents
Bleaching method and product thereofInfo
- Publication number
- GB1277541A GB1277541A GB20329/70A GB2032970A GB1277541A GB 1277541 A GB1277541 A GB 1277541A GB 20329/70 A GB20329/70 A GB 20329/70A GB 2032970 A GB2032970 A GB 2032970A GB 1277541 A GB1277541 A GB 1277541A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkali metal
- molar
- april
- maintain
- hydrogen peroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004061 bleaching Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 4
- 229910052783 alkali metal Inorganic materials 0.000 abstract 3
- -1 alkali metal formaldehyde sulphoxylates Chemical class 0.000 abstract 3
- 239000002738 chelating agent Substances 0.000 abstract 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- MTCFGRXMJLQNBG-REOHCLBHSA-N (2S)-2-Amino-3-hydroxypropansäure Chemical compound OC[C@H](N)C(O)=O MTCFGRXMJLQNBG-REOHCLBHSA-N 0.000 abstract 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 abstract 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract 1
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 abstract 1
- 239000000908 ammonium hydroxide Substances 0.000 abstract 1
- 229960005070 ascorbic acid Drugs 0.000 abstract 1
- 235000010323 ascorbic acid Nutrition 0.000 abstract 1
- 239000011668 ascorbic acid Substances 0.000 abstract 1
- 239000002585 base Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 239000007853 buffer solution Substances 0.000 abstract 1
- 239000013522 chelant Substances 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 229910001448 ferrous ion Inorganic materials 0.000 abstract 1
- 210000004209 hair Anatomy 0.000 abstract 1
- 239000012266 salt solution Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/08—Preparations for bleaching the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/51—Chelating agents
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Birds (AREA)
- Emergency Medicine (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Cosmetics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
Abstract
1277541 Bleaching GILLETTE CO 28 April 1970 [29 April 1969] 20329/70 Heading D1P Hair or wool is bleached by first impregnating it with an aqueous solution containing 0.05-0.15 molar dissolved ferrous salt and a dissolved chelating agent with a concentration of 0.2-5 times the molar concentration of the salt at 20C to the boiling point of the solution and then contacting it with aqueous hydrogen peroxide at pH 8-11. The chelating agent has a chelate formation constant (K ma ) with ferrous ion such that log K ma , is 2-8 and the total ionic strength of the solution is 0.5-2.5. The ferrous salt solution may also contain 0.005-0.05 molar reducing agent e.g., alkali metal formaldehyde sulphoxylates, alkali metal sulphites and alkali metal thiosulphates. Preferably in the impregnating stage a buffer system is included to maintain the pH between 3.5-6 and to maintain the total ionic strength above the minimum desired level. Examples of the chelating agents used are ascorbic acid, citric acid, serine and ethylene diamine. In the bleaching stage the fibres are maintained in contact with an aqueous solution containing 1-6 % hydrogen peroxide by weight and adjusted to pH 8-11 by a suitable base preferably ammonium hydroxide at 20-60C.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US82030769A | 1969-04-29 | 1969-04-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1277541A true GB1277541A (en) | 1972-06-14 |
Family
ID=25230447
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB20329/70A Expired GB1277541A (en) | 1969-04-29 | 1970-04-28 | Bleaching method and product thereof |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3632295A (en) |
| DE (1) | DE2021099C3 (en) |
| FR (1) | FR2040414A7 (en) |
| GB (1) | GB1277541A (en) |
| IT (1) | IT1016004B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110424147A (en) * | 2019-06-20 | 2019-11-08 | 许昌学院 | A kind of method of the Shuan oxygen water Piao Bai treatment oil human hair of simple green high-efficient |
| CN110565357A (en) * | 2019-06-11 | 2019-12-13 | 邵阳阳光发品有限公司 | Method for bleaching human hair fibers by complexing catalysis |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4145183A (en) * | 1975-12-19 | 1979-03-20 | E. I. Du Pont De Nemours And Company | Method for the oxidative treatment of textiles with activated peroxygen compounds |
| DE2704905A1 (en) * | 1977-02-05 | 1978-08-10 | Henkel Kgaa | PRODUCTS FOR BLACHING HAIR |
| US4302199A (en) * | 1980-12-29 | 1981-11-24 | The Procter & Gamble Company | Hair dyeing method |
| FR2529921A1 (en) * | 1982-07-07 | 1984-01-13 | Rech Participation Ste Norm | PROCESS FOR ANTI-FELT TREATMENT OF KERATIN FIBERS, COMPRISING BASIC OXIDATION CATALYZED BY A METALLIC SALT, AND FIBERS THUS OBTAINED |
| GB8311865D0 (en) * | 1983-04-29 | 1983-06-02 | Procter & Gamble Ltd | Bleach compositions |
| GB8720863D0 (en) * | 1987-09-04 | 1987-10-14 | Unilever Plc | Metalloporphyrins |
| US5196029A (en) * | 1989-04-24 | 1993-03-23 | Kao Corporation | Hair-treatment composition, bleaching composition and hair color tone modifier composition |
| JPH0669941B2 (en) * | 1989-04-24 | 1994-09-07 | 花王株式会社 | Hair treatment composition, depigmenting composition and hair color correcting composition |
| DE69637989D1 (en) | 1995-09-25 | 2009-09-17 | Discus Dental Llc | Tooth whitening compositions |
| EP1012374B1 (en) * | 1997-05-28 | 2009-07-15 | Purecolor Incorporated | Mineral stains for wood |
| US6428580B2 (en) * | 1997-08-20 | 2002-08-06 | L'oreal | Use of ascorbic acid in permanent waving and hair coloring compositions |
| AU2009321697B2 (en) | 2008-12-05 | 2013-10-17 | Unilever Plc | Colouring of keratinous fibers using a pretreatment comprising an iron salt and a colour developer comprising hydrolysable tannin |
| CN102071567B (en) * | 2010-12-21 | 2012-06-13 | 东华大学 | Method for bleaching human hair fibers at low temperature with low damage |
| CN105625021A (en) * | 2016-03-31 | 2016-06-01 | 太仓市锦达印染有限公司 | Continuous production process for blended fabric printing and dyeing pretreatment |
| WO2022169633A1 (en) | 2021-02-02 | 2022-08-11 | Federici Brands, Llc | Composition comprising a hydrolyzed keratin and a silane crosslinking agent and process for hair protection during bleaching |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2149319A (en) * | 1935-04-19 | 1939-03-07 | Soussa Edmond | Treatment of human hair |
| US2914374A (en) * | 1954-03-24 | 1959-11-24 | Harris Res Lab Inc | Bleaching of keratinous fibrous material |
| US2875018A (en) * | 1955-03-28 | 1959-02-24 | Fmc Corp | Process of bleaching specialty hair fibers with hydrogen peroxide solutions |
| US3193464A (en) * | 1961-05-31 | 1965-07-06 | Sales Affilites Inc | Hydrogen peroxide hair bleaching composition and method |
| US3378444A (en) * | 1966-06-03 | 1968-04-16 | Rayette Faberge | Hair bleaching composition |
-
1969
- 1969-04-29 US US820307A patent/US3632295A/en not_active Expired - Lifetime
-
1970
- 1970-04-28 GB GB20329/70A patent/GB1277541A/en not_active Expired
- 1970-04-28 IT IT50297/70A patent/IT1016004B/en active
- 1970-04-29 FR FR7015786A patent/FR2040414A7/fr not_active Expired
- 1970-04-29 DE DE2021099A patent/DE2021099C3/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110565357A (en) * | 2019-06-11 | 2019-12-13 | 邵阳阳光发品有限公司 | Method for bleaching human hair fibers by complexing catalysis |
| CN110424147A (en) * | 2019-06-20 | 2019-11-08 | 许昌学院 | A kind of method of the Shuan oxygen water Piao Bai treatment oil human hair of simple green high-efficient |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2021099B2 (en) | 1973-10-31 |
| DE2021099A1 (en) | 1970-11-12 |
| FR2040414A7 (en) | 1971-01-22 |
| DE2021099C3 (en) | 1974-06-12 |
| IT1016004B (en) | 1977-05-30 |
| US3632295A (en) | 1972-01-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |