GB1275771A - Liquid phase oxidation of condensed ring aromatic hydrocarbons - Google Patents
Liquid phase oxidation of condensed ring aromatic hydrocarbonsInfo
- Publication number
- GB1275771A GB1275771A GB3565969A GB3565969A GB1275771A GB 1275771 A GB1275771 A GB 1275771A GB 3565969 A GB3565969 A GB 3565969A GB 3565969 A GB3565969 A GB 3565969A GB 1275771 A GB1275771 A GB 1275771A
- Authority
- GB
- United Kingdom
- Prior art keywords
- anthracene
- liquid phase
- condensed ring
- fluorene
- ring aromatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/44—Carbon
- C09C1/48—Carbon black
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1275771 Liquid phase oxidation of condensed ring aromatic compounds ASHLAND OIL Inc 15 July 1969 [15 July 1968] 35659/69 Heading C2C A process for the preparation of condensed ring aromatic ketones comprises contacting a feed stock which is a " middle creosote oil " boiling between about 340‹ and 700‹ F. and containing anthracene, fluorene, their derivatives, mixtures of these materials with one another or with contaminants with a gas containing molecular oxygen and a catalyst comprising at least one heavy metal or heavy metal compound, the heavy metal having an atomic number of less than 84, the reaction occurring in the liquid phase in a solvent containing mineral and/or C 1-4 carboxylic acids. Preferably a bromine compound, e.g. KBr is present and manganese or cobalt acetate in acetic acid is the preferred catalyst-solvent system. The process is suitable for the oxidation of anthracene and phenanthrene and carbazole, for a coal liquid boiling between 500‹ and 700‹ F., only the anthracene and/or fluorene undergoing oxidation. In examples anthracene together with phenanthrene, carbazole or benzene is oxidized to anthraquinone in acetic acid in the presence of cobalt and manganese acetate or cerous chloride of nickelous acetate or stannous chloride and potassium bromide. Fluorene is oxidized in acetic acid in the presence of manganese and cobalt acetate and potassium bromide to fluorenone.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US74476868A | 1968-07-15 | 1968-07-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1275771A true GB1275771A (en) | 1972-05-24 |
Family
ID=24993922
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3565969A Expired GB1275771A (en) | 1968-07-15 | 1969-07-15 | Liquid phase oxidation of condensed ring aromatic hydrocarbons |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE736111A (en) |
FR (1) | FR2013015A1 (en) |
GB (1) | GB1275771A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021178285A1 (en) * | 2020-03-03 | 2021-09-10 | Momentive Performance Materials Inc. | Catalyst for use in binder compositions |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3855252A (en) * | 1968-07-15 | 1974-12-17 | Ashland Oil Inc | Liquid phase oxidation of condensed-ring aromatic hydrocarbons |
-
1969
- 1969-07-15 GB GB3565969A patent/GB1275771A/en not_active Expired
- 1969-07-15 BE BE736111D patent/BE736111A/xx unknown
- 1969-07-15 FR FR6924101A patent/FR2013015A1/fr not_active Withdrawn
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021178285A1 (en) * | 2020-03-03 | 2021-09-10 | Momentive Performance Materials Inc. | Catalyst for use in binder compositions |
Also Published As
Publication number | Publication date |
---|---|
BE736111A (en) | 1969-12-16 |
FR2013015A1 (en) | 1970-03-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |