GB1275771A - Liquid phase oxidation of condensed ring aromatic hydrocarbons - Google Patents

Liquid phase oxidation of condensed ring aromatic hydrocarbons

Info

Publication number
GB1275771A
GB1275771A GB3565969A GB3565969A GB1275771A GB 1275771 A GB1275771 A GB 1275771A GB 3565969 A GB3565969 A GB 3565969A GB 3565969 A GB3565969 A GB 3565969A GB 1275771 A GB1275771 A GB 1275771A
Authority
GB
United Kingdom
Prior art keywords
anthracene
liquid phase
condensed ring
fluorene
ring aromatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3565969A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ashland LLC
Original Assignee
Ashland Oil Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ashland Oil Inc filed Critical Ashland Oil Inc
Publication of GB1275771A publication Critical patent/GB1275771A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44Carbon
    • C09C1/48Carbon black

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1275771 Liquid phase oxidation of condensed ring aromatic compounds ASHLAND OIL Inc 15 July 1969 [15 July 1968] 35659/69 Heading C2C A process for the preparation of condensed ring aromatic ketones comprises contacting a feed stock which is a " middle creosote oil " boiling between about 340‹ and 700‹ F. and containing anthracene, fluorene, their derivatives, mixtures of these materials with one another or with contaminants with a gas containing molecular oxygen and a catalyst comprising at least one heavy metal or heavy metal compound, the heavy metal having an atomic number of less than 84, the reaction occurring in the liquid phase in a solvent containing mineral and/or C 1-4 carboxylic acids. Preferably a bromine compound, e.g. KBr is present and manganese or cobalt acetate in acetic acid is the preferred catalyst-solvent system. The process is suitable for the oxidation of anthracene and phenanthrene and carbazole, for a coal liquid boiling between 500‹ and 700‹ F., only the anthracene and/or fluorene undergoing oxidation. In examples anthracene together with phenanthrene, carbazole or benzene is oxidized to anthraquinone in acetic acid in the presence of cobalt and manganese acetate or cerous chloride of nickelous acetate or stannous chloride and potassium bromide. Fluorene is oxidized in acetic acid in the presence of manganese and cobalt acetate and potassium bromide to fluorenone.
GB3565969A 1968-07-15 1969-07-15 Liquid phase oxidation of condensed ring aromatic hydrocarbons Expired GB1275771A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US74476868A 1968-07-15 1968-07-15

Publications (1)

Publication Number Publication Date
GB1275771A true GB1275771A (en) 1972-05-24

Family

ID=24993922

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3565969A Expired GB1275771A (en) 1968-07-15 1969-07-15 Liquid phase oxidation of condensed ring aromatic hydrocarbons

Country Status (3)

Country Link
BE (1) BE736111A (en)
FR (1) FR2013015A1 (en)
GB (1) GB1275771A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021178285A1 (en) * 2020-03-03 2021-09-10 Momentive Performance Materials Inc. Catalyst for use in binder compositions

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3855252A (en) * 1968-07-15 1974-12-17 Ashland Oil Inc Liquid phase oxidation of condensed-ring aromatic hydrocarbons

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021178285A1 (en) * 2020-03-03 2021-09-10 Momentive Performance Materials Inc. Catalyst for use in binder compositions

Also Published As

Publication number Publication date
BE736111A (en) 1969-12-16
FR2013015A1 (en) 1970-03-27

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee