ES348385A1 - Process for preparing Halogenated Aromatic Compounds - Google Patents

Process for preparing Halogenated Aromatic Compounds

Info

Publication number
ES348385A1
ES348385A1 ES348385A ES348385A ES348385A1 ES 348385 A1 ES348385 A1 ES 348385A1 ES 348385 A ES348385 A ES 348385A ES 348385 A ES348385 A ES 348385A ES 348385 A1 ES348385 A1 ES 348385A1
Authority
ES
Spain
Prior art keywords
compound
nitrate
chloride
acid
iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES348385A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gulf Research and Development Co
Original Assignee
Gulf Research and Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gulf Research and Development Co filed Critical Gulf Research and Development Co
Publication of ES348385A1 publication Critical patent/ES348385A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/62—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by introduction of halogen; by substitution of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B39/00—Halogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • C07C17/12—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms in the ring of aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

An aromatic compound, which may be an aromatic hydrocarbon, a halogenated aromatic hydrocarbon, a carboxylic acid ester of a hydroxyaromatic compound or an ester of an aromatic acid, is chlorinated or brominated in the nucleus by treatment with (a) iron or a metal of the platinum group or a compound of any of these metals, (b) a source of nitrate ions and (c) a source of chloride or bromide ions, or perchloric acid. A number of iron or platinumgroup metal compounds are specified, as also are a number of sources of chloride or bromide ions. The source of nitrate ions may be nitric acid, sodium nitrate, nitric oxide, nitrous anhydride, a nitrite, nitrous acid, nitrogen di- or tetra-oxide or nitric anhydride. A single compound, e.g. palladium nitrate or ferric chloride, may provide both the iron or platinum-group metal compound and the nitrate, chloride or bromide ion. The reaction is preferably effected at about 60-150 C. in a solvent and in the presence of molecular oxygen. Examples are given of the treatment of benzene, chlorobenzene, toluene, phenyl acetate, methyl benzoate and naphthalene. Reference is made also to the treatment of ethylbenzene, cumene, anthracene, biphenyl, phenanthrene, t-butylbenzene, [alpha]-phenylnaphthalene, p-xylene, terphenyl, 3-phenylheptane, 1,4-diphenylbutane, diphenylmethane and tetralin.
ES348385A 1966-12-19 1967-12-18 Process for preparing Halogenated Aromatic Compounds Expired ES348385A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US60247166A 1966-12-19 1966-12-19
US60246966A 1966-12-19 1966-12-19

Publications (1)

Publication Number Publication Date
ES348385A1 true ES348385A1 (en) 1969-03-01

Family

ID=27084147

Family Applications (1)

Application Number Title Priority Date Filing Date
ES348385A Expired ES348385A1 (en) 1966-12-19 1967-12-18 Process for preparing Halogenated Aromatic Compounds

Country Status (6)

Country Link
BE (1) BE708192A (en)
DE (1) DE1668163A1 (en)
ES (1) ES348385A1 (en)
FR (1) FR1548020A (en)
GB (1) GB1163236A (en)
NL (1) NL6717331A (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5034544B1 (en) * 1969-06-09 1975-11-10
JPS5034548B1 (en) * 1970-02-04 1975-11-10
JPS5034546B1 (en) * 1969-11-05 1975-11-10
IT1158953B (en) * 1978-07-20 1987-02-25 Snam Progetti PROCESS FOR THE FUNCTIONALIZATION OF AROMATIC AND HETEROCYCLIC SUBSTRATES
DE3008158A1 (en) * 1980-03-04 1981-09-10 Bayer Ag, 5090 Leverkusen METHOD FOR PRODUCING 3-BROM-4-FLUORTOLUOL
CZ301809B6 (en) * 2000-04-28 2010-06-30 Nihon Nohyaku Co., Ltd. Process for preparing 2-halobenzoic acids and derivatives thereof

Also Published As

Publication number Publication date
BE708192A (en) 1968-05-02
DE1668163A1 (en) 1970-09-10
NL6717331A (en) 1968-06-20
GB1163236A (en) 1969-09-04
FR1548020A (en) 1968-11-29

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