GB1163236A - Process for preparing Halogenated Aromatic Compounds - Google Patents

Process for preparing Halogenated Aromatic Compounds

Info

Publication number
GB1163236A
GB1163236A GB5680467A GB5680467A GB1163236A GB 1163236 A GB1163236 A GB 1163236A GB 5680467 A GB5680467 A GB 5680467A GB 5680467 A GB5680467 A GB 5680467A GB 1163236 A GB1163236 A GB 1163236A
Authority
GB
United Kingdom
Prior art keywords
compound
nitrate
chloride
acid
iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5680467A
Inventor
Charles M Selwitz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gulf Research and Development Co
Original Assignee
Gulf Research and Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gulf Research and Development Co filed Critical Gulf Research and Development Co
Publication of GB1163236A publication Critical patent/GB1163236A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/62—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by introduction of halogen; by substitution of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B39/00—Halogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • C07C17/12—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms in the ring of aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,163,236. Halogenated aromatic compounds. GULF RESEARCH & DEVELOPMENT CO. 14 Dec., 1967 [19 Dec., 1966 (2)], No. 56804/66. Heading C2C. An aromatic compound, which may be an aromatic hydrocarbon, a halogenated aromatic hydrocarbon, a carboxylic acid ester of a hydroxyaromatic compound or an ester of an aromatic acid, is chlorinated or brominated in the nucleus by treatment with (a) iron or a metal of the platinum group or a compound of any of these metals, (b) a source of nitrate ions and (c) a source of chloride or bromide ions, or perchloric acid. A number of iron or platinumgroup metal compounds are specified, as also are a number of sources of chloride or bromide ions. The source of nitrate ions may be nitric acid, sodium nitrate, nitric oxide, nitrous anhydride, a nitrite, nitrous acid, nitrogen di- or tetra-oxide or nitric anhydride. A single compound, e.g. palladium nitrate or ferric chloride, may provide both the iron or platinum-group metal compound and the nitrate, chloride or bromide ion. The reaction is preferably effected at about 60-150‹ C. in a solvent and in the presence of molecular oxygen. Examples are given of the treatment of benzene, chlorobenzene, toluene, phenyl acetate, methyl benzoate and naphthalene. Reference is made also to the treatment of ethylbenzene, cumene, anthracene, biphenyl, phenanthrene, t-butylbenzene, α-phenylnaphthalene, p-xylene, terphenyl, 3-phenylheptane, 1,4-diphenylbutane, diphenylmethane and tetralin.
GB5680467A 1966-12-19 1967-12-14 Process for preparing Halogenated Aromatic Compounds Expired GB1163236A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US60246966A 1966-12-19 1966-12-19
US60247166A 1966-12-19 1966-12-19

Publications (1)

Publication Number Publication Date
GB1163236A true GB1163236A (en) 1969-09-04

Family

ID=27084147

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5680467A Expired GB1163236A (en) 1966-12-19 1967-12-14 Process for preparing Halogenated Aromatic Compounds

Country Status (6)

Country Link
BE (1) BE708192A (en)
DE (1) DE1668163A1 (en)
ES (1) ES348385A1 (en)
FR (1) FR1548020A (en)
GB (1) GB1163236A (en)
NL (1) NL6717331A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1277726A1 (en) * 2000-04-28 2003-01-22 Nihon Nohyaku Co., Ltd. Process for the preparation of 2-halobenzoic acids

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5034546B1 (en) * 1969-11-05 1975-11-10
JPS5034548B1 (en) * 1970-02-04 1975-11-10
JPS5034544B1 (en) * 1969-06-09 1975-11-10
IT1158953B (en) * 1978-07-20 1987-02-25 Snam Progetti PROCESS FOR THE FUNCTIONALIZATION OF AROMATIC AND HETEROCYCLIC SUBSTRATES
DE3008158A1 (en) * 1980-03-04 1981-09-10 Bayer Ag, 5090 Leverkusen METHOD FOR PRODUCING 3-BROM-4-FLUORTOLUOL

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1277726A1 (en) * 2000-04-28 2003-01-22 Nihon Nohyaku Co., Ltd. Process for the preparation of 2-halobenzoic acids
EP1277726A4 (en) * 2000-04-28 2005-09-14 Nihon Nohyaku Co Ltd Process for the preparation of 2-halobenzoic acids
US7057067B2 (en) 2000-04-28 2006-06-06 Nihon Nohyaku Co., Ltd. Process for the preparation of 2-halobenzoic acids
CZ301809B6 (en) * 2000-04-28 2010-06-30 Nihon Nohyaku Co., Ltd. Process for preparing 2-halobenzoic acids and derivatives thereof

Also Published As

Publication number Publication date
NL6717331A (en) 1968-06-20
FR1548020A (en) 1968-11-29
BE708192A (en) 1968-05-02
DE1668163A1 (en) 1970-09-10
ES348385A1 (en) 1969-03-01

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees