GB1274837A - A process for the production of allyl esters - Google Patents

A process for the production of allyl esters

Info

Publication number
GB1274837A
GB1274837A GB30130/70A GB3013070A GB1274837A GB 1274837 A GB1274837 A GB 1274837A GB 30130/70 A GB30130/70 A GB 30130/70A GB 3013070 A GB3013070 A GB 3013070A GB 1274837 A GB1274837 A GB 1274837A
Authority
GB
United Kingdom
Prior art keywords
ester
methyl
acid
dimethyl
allyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB30130/70A
Inventor
Wolfgang Swodenk
Gerhard Scharfe
Johann Grolig
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB1274837A publication Critical patent/GB1274837A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C68/00—Preparation of esters of carbonic or haloformic acids
    • C07C68/06—Preparation of esters of carbonic or haloformic acids from organic carbonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/02—Preparation of carboxylic acid esters by interreacting ester groups, i.e. transesterification
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F118/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F118/14—Esters of polycarboxylic acids
    • C08F118/16—Esters of polycarboxylic acids with alcohols containing three or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F18/14—Esters of polycarboxylic acids
    • C08F18/16—Esters of polycarboxylic acids with alcohols containing three or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1,274,837. Allyl esters. FARBENFABRIKEN BAYER A.G. 22 June, 1970 [2 July, 1969], No. 30130/70. Heading C2C. Allyl esters are prepared by reacting allyl acetate with a carboxylic acid methyl or ethyl ester in the presence of an alkoxide of a metal of Periodic Groups Ia, IIa, IIIa (Mendeleev) or a complex salt thereof. An excess of the allyl acetate is used and saturated and unsaturated aliphatic and cycloaliphatic, substituted aliphatic, cycloaliphatic, araliphatic mono- and polycarboxylic acids and aromatic mono- and polycarboxylic acids and carbonic acid are listed. The catalysts may be lithium, sodium, potassium, magnesium, calcium methylates or mixed methylates and others. Examples describe the reaction of allyl acetate with methyl propionate, methyl stearate, hexahydrobenzoic acid methyl ester, adipic acid dimethyl ester, chloracetic acid ethyl ester, dichloroacetic acid methyl ester, ethoxyacetic acid methyl ester, diglycolic acid dimethyl ester, phenyl acetic acid methyl ester, methyl acrylate, methyl methacrylate, ethyl cinnamate, methyl sorbate, maleic acid dimethyl ester, methyl benzoate, dimethyl phthalate, dimethyl terephthalate, and carbonic acid diethyl ester.
GB30130/70A 1969-07-02 1970-06-22 A process for the production of allyl esters Expired GB1274837A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19691933536 DE1933536B2 (en) 1969-07-02 1969-07-02 METHOD FOR PRODUCING ALLYL ESTERS

Publications (1)

Publication Number Publication Date
GB1274837A true GB1274837A (en) 1972-05-17

Family

ID=5738642

Family Applications (1)

Application Number Title Priority Date Filing Date
GB30130/70A Expired GB1274837A (en) 1969-07-02 1970-06-22 A process for the production of allyl esters

Country Status (12)

Country Link
AT (1) AT301509B (en)
BE (1) BE752882A (en)
CH (1) CH528469A (en)
DE (1) DE1933536B2 (en)
ES (1) ES381269A1 (en)
FR (1) FR2054083A5 (en)
GB (1) GB1274837A (en)
NL (1) NL7009381A (en)
PL (1) PL81332B1 (en)
RO (1) RO56781A (en)
SE (1) SE355568B (en)
ZA (1) ZA703955B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0035304A2 (en) * 1980-03-05 1981-09-09 ANIC S.p.A. Process for preparing bis or tris allyl carbonates and process for preparing polymers thereof
US6215018B1 (en) 1997-08-11 2001-04-10 Ciba Specialty Chemicals Corporation Acrylate monomer preparation using alkali metal alkoxides as ester interchange catalysts and bromide salt polymerization inhibitors

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU3710299A (en) * 1999-04-26 2000-11-10 Ciba Specialty Chemicals Holding Inc. Acrylate monomer preparation using alkali metal alkoxides as ester interchange catalysts and bromide salt polymerization inhibitors
EP1327622A1 (en) * 1999-04-26 2003-07-16 Ciba Specialty Chemicals Holding Inc. Acrylate monomer preparation using alkali metal alkoxides as ester interchange catalysts
CN114262268A (en) * 2021-12-13 2022-04-01 华东理工大学 Method for catalytically synthesizing methyl sorbate based on eutectic solvent

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0035304A2 (en) * 1980-03-05 1981-09-09 ANIC S.p.A. Process for preparing bis or tris allyl carbonates and process for preparing polymers thereof
EP0035304A3 (en) * 1980-03-05 1982-01-13 Anic S.P.A. Process for synthesising allyl carbonates of polyhydric alcohols and their derivatives
US6215018B1 (en) 1997-08-11 2001-04-10 Ciba Specialty Chemicals Corporation Acrylate monomer preparation using alkali metal alkoxides as ester interchange catalysts and bromide salt polymerization inhibitors

Also Published As

Publication number Publication date
FR2054083A5 (en) 1971-04-16
ZA703955B (en) 1971-01-27
RO56781A (en) 1974-07-01
ES381269A1 (en) 1972-11-16
CH528469A (en) 1972-09-30
BE752882A (en) 1971-01-04
SE355568B (en) 1973-04-30
DE1933536A1 (en) 1971-01-07
PL81332B1 (en) 1975-08-30
DE1933536B2 (en) 1978-01-26
NL7009381A (en) 1971-01-05
AT301509B (en) 1972-09-11

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee