GB1269986A - Porous cross-linked copolymer and ion-exchange resin - Google Patents
Porous cross-linked copolymer and ion-exchange resinInfo
- Publication number
- GB1269986A GB1269986A GB08496/69A GB1849669A GB1269986A GB 1269986 A GB1269986 A GB 1269986A GB 08496/69 A GB08496/69 A GB 08496/69A GB 1849669 A GB1849669 A GB 1849669A GB 1269986 A GB1269986 A GB 1269986A
- Authority
- GB
- United Kingdom
- Prior art keywords
- copolymer
- ion
- solvent
- linear polymer
- polyvinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003456 ion exchange resin Substances 0.000 title abstract 3
- 229920003303 ion-exchange polymer Polymers 0.000 title abstract 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 title abstract 2
- 229920006026 co-polymeric resin Polymers 0.000 title 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 6
- 229920001577 copolymer Polymers 0.000 abstract 6
- 229920000642 polymer Polymers 0.000 abstract 5
- 239000000178 monomer Substances 0.000 abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- 239000004793 Polystyrene Substances 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 238000007334 copolymerization reaction Methods 0.000 abstract 2
- 238000000605 extraction Methods 0.000 abstract 2
- 239000003999 initiator Substances 0.000 abstract 2
- 239000003960 organic solvent Substances 0.000 abstract 2
- 229920002223 polystyrene Polymers 0.000 abstract 2
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 2
- 239000011118 polyvinyl acetate Substances 0.000 abstract 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 abstract 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 abstract 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 abstract 2
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- XJUZRXYOEPSWMB-UHFFFAOYSA-N Chloromethyl methyl ether Chemical compound COCCl XJUZRXYOEPSWMB-UHFFFAOYSA-N 0.000 abstract 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 239000007900 aqueous suspension Substances 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 229940061627 chloromethyl methyl ether Drugs 0.000 abstract 1
- 238000010494 dissociation reaction Methods 0.000 abstract 1
- 230000005593 dissociations Effects 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- 229920002102 polyvinyl toluene Polymers 0.000 abstract 1
- 229920000131 polyvinylidene Polymers 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 230000008961 swelling Effects 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000011592 zinc chloride Substances 0.000 abstract 1
- 235000005074 zinc chloride Nutrition 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/16—Organic material
- B01J39/18—Macromolecular compounds
- B01J39/20—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
- C08F2/08—Organic solvent with the aid of dispersing agents for the polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/44—Preparation of metal salts or ammonium salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/26—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a solid phase from a macromolecular composition or article, e.g. leaching out
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2357/00—Characterised by the use of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL6905520A NL6905520A (enrdf_load_stackoverflow) | 1969-04-10 | 1969-04-10 | |
| GB08496/69A GB1269986A (en) | 1969-04-10 | 1969-04-10 | Porous cross-linked copolymer and ion-exchange resin |
| DE19691918399 DE1918399A1 (de) | 1969-04-10 | 1969-04-11 | Verfahren zur Herstellung eines poroesen,vernetzten Mischpolymers,insbesondere zur Verwendung als Ionenaustauscherharz |
| FR6913122A FR2044630B1 (enrdf_load_stackoverflow) | 1969-04-10 | 1969-04-25 |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL6905520A NL6905520A (enrdf_load_stackoverflow) | 1969-04-10 | 1969-04-10 | |
| GB08496/69A GB1269986A (en) | 1969-04-10 | 1969-04-10 | Porous cross-linked copolymer and ion-exchange resin |
| DE19691918399 DE1918399A1 (de) | 1969-04-10 | 1969-04-11 | Verfahren zur Herstellung eines poroesen,vernetzten Mischpolymers,insbesondere zur Verwendung als Ionenaustauscherharz |
| FR6913122A FR2044630B1 (enrdf_load_stackoverflow) | 1969-04-10 | 1969-04-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1269986A true GB1269986A (en) | 1972-04-12 |
Family
ID=27430881
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB08496/69A Expired GB1269986A (en) | 1969-04-10 | 1969-04-10 | Porous cross-linked copolymer and ion-exchange resin |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE1918399A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2044630B1 (enrdf_load_stackoverflow) |
| GB (1) | GB1269986A (enrdf_load_stackoverflow) |
| NL (1) | NL6905520A (enrdf_load_stackoverflow) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56164955A (en) * | 1980-05-23 | 1981-12-18 | Asahi Chem Ind Co Ltd | Packing for chromatography and its production |
| JPS60137908A (ja) * | 1983-12-26 | 1985-07-22 | Mitsubishi Chem Ind Ltd | クロルメチル化ポリマ−の製造法 |
| JPS60158201A (ja) * | 1984-01-30 | 1985-08-19 | Mitsubishi Chem Ind Ltd | クロルメチル化ポリマ−の製造法 |
| US4900796A (en) * | 1988-02-02 | 1990-02-13 | Rohm And Haas Company | Process for preparing chloromethylated aromatic materials |
| EP0760249A1 (en) * | 1995-08-24 | 1997-03-05 | Dainichiseika Color & Chemicals Mfg. Co. Ltd. | Process for the production of connected microgel particles and articles treated with connected microgel particles |
| EP1270609A3 (en) * | 2001-06-22 | 2003-03-26 | Rohm And Haas Company | Method for preparation of strong acid cation exchange resins |
| EP1273345A3 (en) * | 2001-07-03 | 2004-01-02 | Rohm and Haas | Method for preparation of anion exchange resins |
| CN101462083B (zh) * | 2007-12-18 | 2013-04-10 | 朗盛德国有限责任公司 | 生产阳离子交换剂的方法 |
| CN118307721A (zh) * | 2024-05-31 | 2024-07-09 | 西安蓝深新材料科技股份有限公司 | 一种大孔吸附树脂及制备方法和在甜菊糖苷提取中的应用 |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5025517B1 (enrdf_load_stackoverflow) * | 1970-12-19 | 1975-08-23 | ||
| DE2506095A1 (de) * | 1975-02-13 | 1976-08-26 | Permutit Gmbh | Verfahren zur herstellung von kationenaustauschern |
| US6323249B1 (en) * | 1988-09-26 | 2001-11-27 | Purolite International, Ltd. | Macroporous resins having large pores but with high crush strength |
| EP0565086B1 (en) * | 1992-04-10 | 1996-12-27 | Mitsubishi Chemical Corporation | Method for producing a spherical acrylonitrile crosslinked copolymer |
-
1969
- 1969-04-10 NL NL6905520A patent/NL6905520A/xx unknown
- 1969-04-10 GB GB08496/69A patent/GB1269986A/en not_active Expired
- 1969-04-11 DE DE19691918399 patent/DE1918399A1/de active Pending
- 1969-04-25 FR FR6913122A patent/FR2044630B1/fr not_active Expired
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56164955A (en) * | 1980-05-23 | 1981-12-18 | Asahi Chem Ind Co Ltd | Packing for chromatography and its production |
| JPS60137908A (ja) * | 1983-12-26 | 1985-07-22 | Mitsubishi Chem Ind Ltd | クロルメチル化ポリマ−の製造法 |
| JPS60158201A (ja) * | 1984-01-30 | 1985-08-19 | Mitsubishi Chem Ind Ltd | クロルメチル化ポリマ−の製造法 |
| US4900796A (en) * | 1988-02-02 | 1990-02-13 | Rohm And Haas Company | Process for preparing chloromethylated aromatic materials |
| EP0760249A1 (en) * | 1995-08-24 | 1997-03-05 | Dainichiseika Color & Chemicals Mfg. Co. Ltd. | Process for the production of connected microgel particles and articles treated with connected microgel particles |
| EP1270609A3 (en) * | 2001-06-22 | 2003-03-26 | Rohm And Haas Company | Method for preparation of strong acid cation exchange resins |
| EP1273345A3 (en) * | 2001-07-03 | 2004-01-02 | Rohm and Haas | Method for preparation of anion exchange resins |
| KR100877310B1 (ko) * | 2001-07-03 | 2009-01-07 | 롬 앤드 하스 캄파니 | 음이온 교환수지의 제조방법 |
| CN101462083B (zh) * | 2007-12-18 | 2013-04-10 | 朗盛德国有限责任公司 | 生产阳离子交换剂的方法 |
| CN118307721A (zh) * | 2024-05-31 | 2024-07-09 | 西安蓝深新材料科技股份有限公司 | 一种大孔吸附树脂及制备方法和在甜菊糖苷提取中的应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1918399A1 (de) | 1970-12-23 |
| FR2044630A1 (enrdf_load_stackoverflow) | 1971-02-26 |
| NL6905520A (enrdf_load_stackoverflow) | 1970-10-13 |
| FR2044630B1 (enrdf_load_stackoverflow) | 1976-04-16 |
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