GB1269297A - Method of modifying polymeric materials, wood and articles made therefrom by radiation-initiated graft copolymerization thereof - Google Patents

Method of modifying polymeric materials, wood and articles made therefrom by radiation-initiated graft copolymerization thereof

Info

Publication number
GB1269297A
GB1269297A GB3472070A GB3472070A GB1269297A GB 1269297 A GB1269297 A GB 1269297A GB 3472070 A GB3472070 A GB 3472070A GB 3472070 A GB3472070 A GB 3472070A GB 1269297 A GB1269297 A GB 1269297A
Authority
GB
United Kingdom
Prior art keywords
wood
trialkylacryloxystannane
polymer
radiation
triethylmethacryloxystannane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3472070A
Inventor
Vitaly Yakovlevich Kabanov
Nikolai Andreevich Voronkov
Dmitry Alexandrovich Kochkin
Viktor Ivanovich Spitsyn
Iraida Vasilievna Kazamanova
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
INST FIZICHESKOI KHIMKII AKADE
Original Assignee
INST FIZICHESKOI KHIMKII AKADE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by INST FIZICHESKOI KHIMKII AKADE filed Critical INST FIZICHESKOI KHIMKII AKADE
Priority to GB3472070A priority Critical patent/GB1269297A/en
Publication of GB1269297A publication Critical patent/GB1269297A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/56Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
    • C08K5/57Organo-tin compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/15Impregnating involving polymerisation including use of polymer-containing impregnating agents
    • B27K3/156Combined with grafting onto wood fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/003Treating of wood not provided for in groups B27K1/00, B27K3/00 by using electromagnetic radiation or mechanical waves
    • B27K5/004Gamma-radiation

Abstract

1,269,297. Graft polymers. INSTITUT FIZICHESKOI KHIMII AKADEMII NAUK SSSR. 17 July, 1970, No. 34720/70. Heading C3G. Synthetic polymer or wood is rendered fungu<SP>s</SP> resistant in a process which comprises contacting the synthetic polymer or wood with a trialkylacryloxystannane of the formula in which R is an alkyl group and R<SP>1</SP> is a hydrogen atom or a methyl group and graft polymerizing the trialkylacryloxystannane on to the polymer or wood by the action of ionizing radiation until at least 0À5% by weight based on the weight of polymer or wood is graft polymerized, the polymer or wood being irradiated with ionizing radiation either before or after being contacted with the trialkylacryloxystannane. The trialkylacryloxystannane is preferably triethylmethacryloxystannane. The ionizing radiation is suitably gamma radiation derived from a Co<SP>60</SP> source, the total dosage of radiation being suitably 0À1-0À5 Mrad. The polymer or wood may be contacted with the trialkylacryloxystannane in solution in a suitable solvent, e.g. acetone, benzene, methyl alcohol, or a mixture of acetone and methyl alcohol and the concentration of the trialkylacryloxystannane in the solution is suitably 6-20% by weight. Examples refer to the graft polymerizing on to polyethylene, polpropylene and polycaproamide, which may be irradiated either before or after contacting with triethylmethacryloxystannane ; polyvinyl chloride, and bars of spruce, pine, birch and oak which are irradiated after contacting with triethylmethacryloxystannane.
GB3472070A 1970-07-17 1970-07-17 Method of modifying polymeric materials, wood and articles made therefrom by radiation-initiated graft copolymerization thereof Expired GB1269297A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3472070A GB1269297A (en) 1970-07-17 1970-07-17 Method of modifying polymeric materials, wood and articles made therefrom by radiation-initiated graft copolymerization thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3472070A GB1269297A (en) 1970-07-17 1970-07-17 Method of modifying polymeric materials, wood and articles made therefrom by radiation-initiated graft copolymerization thereof

Publications (1)

Publication Number Publication Date
GB1269297A true GB1269297A (en) 1972-04-06

Family

ID=10369146

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3472070A Expired GB1269297A (en) 1970-07-17 1970-07-17 Method of modifying polymeric materials, wood and articles made therefrom by radiation-initiated graft copolymerization thereof

Country Status (1)

Country Link
GB (1) GB1269297A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0244145A1 (en) * 1986-04-18 1987-11-04 Nippon Paint Co., Ltd. Composite resin particles and preparation thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0244145A1 (en) * 1986-04-18 1987-11-04 Nippon Paint Co., Ltd. Composite resin particles and preparation thereof
AU626750B2 (en) * 1986-04-18 1992-08-06 Nippon Paint Co., Ltd. Composite resin particles and preparation thereof

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