GB1263148A - Antistatic copolymers and their use in the treatment of synthetic fibers - Google Patents

Antistatic copolymers and their use in the treatment of synthetic fibers

Info

Publication number
GB1263148A
GB1263148A GB06847/69A GB1684769A GB1263148A GB 1263148 A GB1263148 A GB 1263148A GB 06847/69 A GB06847/69 A GB 06847/69A GB 1684769 A GB1684769 A GB 1684769A GB 1263148 A GB1263148 A GB 1263148A
Authority
GB
United Kingdom
Prior art keywords
atoms
sodium
copolymers
antistatic
glycol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB06847/69A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Publication of GB1263148A publication Critical patent/GB1263148A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/267—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having amino or quaternary ammonium groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/285—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety
    • C08F220/286—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety and containing polyethylene oxide in the alcohol moiety, e.g. methoxy polyethylene glycol (meth)acrylate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S260/00—Chemistry of carbon compounds
    • Y10S260/15—Antistatic agents not otherwise provided for
    • Y10S260/17—High polymeric, resinous, antistatic agents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S260/00—Chemistry of carbon compounds
    • Y10S260/21—Polymer chemically or physically modified to impart antistatic properties and methods of antistatic agent addition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Artificial Filaments (AREA)

Abstract

1,263,148. Copolymer antistatic agents. TORAY INDUSTRIES Inc. 31 March, 1969 [3 April, 1968; 1 Oct., 1968], No. 16847/69. Heading C3P. [Also in Division D1] Antistatic copolymers are obtained by copolymerizing in water a mixture having a gelating concentration (as defined) of 14-30% by weight and comprising (1) at least one monoester of the formula wherein R 1 is H, methyl or ethyl, R 2 is OH, alkoxy (not more than 18 C atoms), halogen, alkyl sulphide (not more than 18 C atoms), mono- or di-alkylamino (having not more than 18 C atoms), or a phenoxy or naphthoxy radical, and l and m satisfy the relationships 10#l#100 and 0#m<l; and (2) at least one diacrylate or dimethacrylate of a polyol (e.g. ethylene glycol, propylene glycol, polyethylene glycol or polypropylene glycol). The copolymers may additionally be derived from (3) a component selected from acrylonitrile and acrylate or methacrylate esters of alkanols having 8 or more carbon atoms. Copolymerization of the monomers is suitably effected in the presence of a catalyst such as potassium, sodium or ammonium persulphate or hydrogen peroxide, which may optionally be used as a redox combination with a reducing agent such as sodium sulphite, sodium hydrogen sulphite, sodium thiosulphate, oxalic acid or ferrous sulphate. Polymerization can be effected with or without emulsifying agents.
GB06847/69A 1968-04-03 1969-03-31 Antistatic copolymers and their use in the treatment of synthetic fibers Expired GB1263148A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2142068 1968-04-03
JP7081768 1968-10-01

Publications (1)

Publication Number Publication Date
GB1263148A true GB1263148A (en) 1972-02-09

Family

ID=26358479

Family Applications (1)

Application Number Title Priority Date Filing Date
GB06847/69A Expired GB1263148A (en) 1968-04-03 1969-03-31 Antistatic copolymers and their use in the treatment of synthetic fibers

Country Status (4)

Country Link
US (1) US3717689A (en)
DE (1) DE1917410A1 (en)
FR (1) FR2007379A1 (en)
GB (1) GB1263148A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5506324A (en) * 1992-04-16 1996-04-09 The Dow Chemical Company Method of preparation of crosslinked hydrophilic resins

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE792145A (en) * 1971-12-02 1973-05-30 Bayer Ag ACRYLONITRILE POLYMERS HAVING REDUCED SURFACE RESISTANCE AND THEIR PREPARATION PROCESS
US3944527A (en) * 1974-07-11 1976-03-16 Minnesota Mining And Manufacturing Company Fluoroaliphatic copolymers
US4065598A (en) * 1975-03-17 1977-12-27 Toray Industries, Inc. Process for polymeric modification of a fiber
DE2758122A1 (en) * 1977-12-24 1979-07-05 Basf Ag WATER-SOLUBLE COPOLYMERISATES BASED ON HYDROPHILIC AETHYLENICALLY UNSATURATED MONOMERS
US4390401A (en) * 1981-02-23 1983-06-28 Celanese Corporation Acrylate or methacrylate esters of alkylene oxide adducts of alkyl/aryl phenols as wetting agents for ultraviolet curable coating compositions
DE3376267D1 (en) * 1982-11-11 1988-05-19 Showa Denko Kk POLYMERIZABLE COMPOSITIONS
US4893757A (en) * 1984-08-13 1990-01-16 Highland Manufacturing And Sales Company Apparatus and method for producing weighed charges of loosely aggregated filamentary material from compacted bales of the material
DE3671913D1 (en) * 1985-08-12 1990-07-19 Allied Colloids Ltd AQUEOUS ADHESIVES AND THEIR USE.
EP0213799B1 (en) * 1985-08-12 1990-04-04 Ciba Specialty Chemicals Water Treatments Limited Absorbent polymers, their manufacture and uses
AU612965B2 (en) * 1985-08-12 1991-07-25 Ciba Specialty Chemicals Water Treatments Limited Polymeric thickeners and their production
DE3635489A1 (en) * 1986-10-18 1988-04-21 Basf Ag COPOLYMERISATE MADE OF HYDROPHOBIC ACRYLIC ACID OR METHACRYLIC ACID ESTERS AND HYDROPHILIC COMONOMERS, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS A PETROLEUM EMULSION SPLITTER
JPH02225536A (en) * 1989-02-27 1990-09-07 Mitsubishi Rayon Co Ltd Synthetic resin molding of excellent antistatic property and its production
US5965206A (en) * 1996-09-16 1999-10-12 Ciba Specialty Chemicals Corporation Antistatic composition
US6258447B1 (en) * 1998-03-18 2001-07-10 Southpac Trust Int'l, Inc. Decorative shredded material
US5942120A (en) * 1997-12-04 1999-08-24 Wilkinson; Kenneth Composite microporous ultrafiltration membrane, method of making thereof, and separation methods
US20020172802A1 (en) * 1998-08-20 2002-11-21 Weder Donald E. Decorative creped shredded material
US6337313B1 (en) * 1999-11-16 2002-01-08 National Starch And Chemical Investment Company Textile manufacturing and treating processes comprising a hydrophobically modified polymer
SE0201110D0 (en) * 2002-04-12 2002-04-12 Astrazeneca Ab New film coating
CN100540760C (en) * 2006-12-12 2009-09-16 新华锦集团有限公司 A kind of modified polyacrylonitrile fiber and manufacture method thereof and purposes

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3035031A (en) * 1960-02-24 1962-05-15 American Cyanamid Co Acrylonitrile copolymers
US3341627A (en) * 1963-07-09 1967-09-12 Du Pont Polymeric anti-static composition and process
US3475366A (en) * 1966-04-28 1969-10-28 Scm Corp Hydroxyl substituted linear thermoplastic vinyl copolymers,coating compositions,and protective coatings containing same
GB1202793A (en) * 1967-01-24 1970-08-19 Toray Industries Acrylonitrile polymer compositions and fibres made therefrom

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5506324A (en) * 1992-04-16 1996-04-09 The Dow Chemical Company Method of preparation of crosslinked hydrophilic resins

Also Published As

Publication number Publication date
DE1917410A1 (en) 1970-09-10
US3717689A (en) 1973-02-20
FR2007379A1 (en) 1970-01-09

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