GB1262339A - Hydrodesulfurization of heavy petroleum distillates - Google Patents

Hydrodesulfurization of heavy petroleum distillates

Info

Publication number
GB1262339A
GB1262339A GB1971769A GB1971769A GB1262339A GB 1262339 A GB1262339 A GB 1262339A GB 1971769 A GB1971769 A GB 1971769A GB 1971769 A GB1971769 A GB 1971769A GB 1262339 A GB1262339 A GB 1262339A
Authority
GB
United Kingdom
Prior art keywords
acid
nitrate
sio
sodium
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1971769A
Inventor
Clark Edward Adams
William Thomas House
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB1262339A publication Critical patent/GB1262339A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/06—Gasoil

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

1,262,339. Hydrodesulphurisation catalysts. ESSO RESEARCH & E NG . CO. 17 April, 1969 [3 May, 1968], No. 19717/69. Heading B1E. [Also in Division C5] A hydrocarbon hydrodesulphurisation catalyst comprises Mo or W oxide or sulphide plus Co or Ni oxide or sulphide (or mixtures) on a SiO 2 -Al 2 O 3 base containing 1 to 6% SiO 2 , and has a maximum of pores in the range 30 to 70Š. It may be prepared from aluminium sulphate, chloride or nitrate and sodium silicate; or from sodium aluminate containing silica by precipitation with aluminium halides, nitrate or sulphate or with HCl, HNO 3 or H 2 SO 4 , followed by impregnating with metal salts. Preferably the support is prepared in the presence of galatonic acid, araboric acid, xylonic acid, mannonic acid or gluconic acid or a sodium, potassium, zinc, magnesium, calcium or lithium salt thereof and has an apparent bulk density of less than 0.70 g./cc.
GB1971769A 1968-05-03 1969-04-17 Hydrodesulfurization of heavy petroleum distillates Expired GB1262339A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US72645068A 1968-05-03 1968-05-03

Publications (1)

Publication Number Publication Date
GB1262339A true GB1262339A (en) 1972-02-02

Family

ID=24918654

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1971769A Expired GB1262339A (en) 1968-05-03 1969-04-17 Hydrodesulfurization of heavy petroleum distillates

Country Status (6)

Country Link
US (1) US3531398A (en)
JP (1) JPS5239044B1 (en)
DE (1) DE1922161A1 (en)
FR (1) FR2007803B1 (en)
GB (1) GB1262339A (en)
NL (1) NL163555B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112065540A (en) * 2020-09-09 2020-12-11 安徽江淮汽车集团股份有限公司 NSC desulfurization method

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3770618A (en) * 1967-06-26 1973-11-06 Exxon Research Engineering Co Hydrodesulfurization of residua
US3668116A (en) * 1970-10-16 1972-06-06 Exxon Research Engineering Co Slurry hydrodesulfurization of a heavy petroleum oil
US3770617A (en) * 1970-12-28 1973-11-06 Exxon Research Engineering Co Hydrodesulfurization with a specified pore size distribution in silica-stabilized alumina
DE2233943A1 (en) * 1971-07-14 1973-01-25 Exxon Research Engineering Co HYDRATION CATALYST, METHOD FOR MANUFACTURING IT AND ITS USE
GB1408759A (en) * 1971-12-07 1975-10-01 Shell Int Research Catalytic hydrodesulphurisation process
JPS5141641B2 (en) * 1972-01-06 1976-11-11
US3902991A (en) * 1973-04-27 1975-09-02 Chevron Res Hydrodesulfurization process for the production of low-sulfur hydrocarbon mixture
US4341625A (en) * 1973-08-09 1982-07-27 Chevron Research Company Method for preparing a catalyst carrier, a catalyst containing the carrier, and a hydrocarbon hydrodesulfurization process using the catalyst
JPS52130265A (en) * 1976-04-24 1977-11-01 Nippon Hoso Kyokai <Nhk> Elastic surface wave delay line
JPS54159931U (en) * 1978-04-28 1979-11-08
US4900711A (en) * 1988-03-23 1990-02-13 Harshaw/Filtrol Partnership Hydrotreating catalyst
US4952306A (en) * 1989-09-22 1990-08-28 Exxon Research And Engineering Company Slurry hydroprocessing process
US5037532A (en) * 1989-09-28 1991-08-06 Exxon Research & Engineering Company Slurry hydrotreating process
FR2758555B1 (en) * 1997-01-20 1999-02-19 Inst Francais Du Petrole PROCESS FOR THE PURIFICATION OF NAPHTHALENE BY SELECTIVE HYDROTREATMENT FOLLOWED BY SEPARATION
DK29598A (en) * 1998-03-04 1999-09-05 Haldor Topsoe As Process for desulphurizing FCC heavy gasoline
US7758817B2 (en) * 2006-08-09 2010-07-20 Uop Llc Device for contacting high contaminated feedstocks with catalyst in an FCC unit
CN103657671B (en) * 2012-08-30 2015-07-08 中国科学院大连化学物理研究所 Dialkenes selective hydrogenation catalyst and preparation method and application of dialkenes selective hydrogenation catalyst
US9127218B2 (en) 2013-03-26 2015-09-08 Uop Llc Hydroprocessing and apparatus relating thereto
US9771527B2 (en) 2013-12-18 2017-09-26 Saudi Arabian Oil Company Production of upgraded petroleum by supercritical water
US10604709B2 (en) 2017-02-12 2020-03-31 Magēmā Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials
US12025435B2 (en) 2017-02-12 2024-07-02 Magēmã Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil
US20180230389A1 (en) 2017-02-12 2018-08-16 Mag&#275;m&#257; Technology, LLC Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil
US11788017B2 (en) 2017-02-12 2023-10-17 Magëmã Technology LLC Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil
US12071592B2 (en) 2017-02-12 2024-08-27 Magēmā Technology LLC Multi-stage process and device utilizing structured catalyst beds and reactive distillation for the production of a low sulfur heavy marine fuel oil

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA711692A (en) * 1965-06-15 Universal Oil Products Company Process for the purification of hydrocarbons and for the manufacture of catalyst therefor
US2728710A (en) * 1954-03-15 1955-12-27 Union Oil Co Process for hydrodesulfurizing hydrocarbons
US2900332A (en) * 1955-04-06 1959-08-18 British Petroleum Co Hydrocatalytic desulfurization of gas oil
FR1331328A (en) * 1960-04-15 1963-07-05 Exxon Research Engineering Co Hydrorefining catalyst and hydrorefining process
US3162597A (en) * 1960-09-12 1964-12-22 Sun Oil Co Process for color stabilization and hydrodesulfurization or cracked gas oils
US3169918A (en) * 1962-07-02 1965-02-16 Universal Oil Prod Co Hydrorefining heavy oils using a pseudo-dry catalyst
US3205165A (en) * 1963-08-23 1965-09-07 Universal Oil Prod Co Hydrorefining process
US3306845A (en) * 1964-08-04 1967-02-28 Union Oil Co Multistage hydrofining process
FR1554168A (en) * 1967-03-08 1969-01-17

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112065540A (en) * 2020-09-09 2020-12-11 安徽江淮汽车集团股份有限公司 NSC desulfurization method
CN112065540B (en) * 2020-09-09 2021-09-21 安徽江淮汽车集团股份有限公司 NSC desulfurization method

Also Published As

Publication number Publication date
US3531398A (en) 1970-09-29
DE1922161A1 (en) 1969-11-20
NL6906669A (en) 1969-11-05
FR2007803A1 (en) 1970-01-09
NL163555B (en) 1980-04-15
FR2007803B1 (en) 1973-11-16
JPS5239044B1 (en) 1977-10-03

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