GB1246989A - The polymerisation or copolymerisation of vinyl chloride - Google Patents
The polymerisation or copolymerisation of vinyl chlorideInfo
- Publication number
- GB1246989A GB1246989A GB5998368A GB5998368A GB1246989A GB 1246989 A GB1246989 A GB 1246989A GB 5998368 A GB5998368 A GB 5998368A GB 5998368 A GB5998368 A GB 5998368A GB 1246989 A GB1246989 A GB 1246989A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl chloride
- salt
- cycloalkyl
- dec
- aryl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1,246,989. Polymerizing vinyl chloride. CHATILLON S.A. ITALIANA PER LE FIBRE TESSILI ARTIFICIALI S.p.A. 17 Dec., 1968 [19 Dec., 1967], No. 59983/68. Heading C3P. Vinyl chloride is (co-)polymerized in bulk (including the use of minor amounts of solvent or diluent) at below 0‹ C. in the presence of a hydroperoxide ROOH in which R is alkyl, cycloalkyl, aryl or arylalkyl and a salt of a monoester of sulphurous acid (R<SP>1</SP>OSOO) n M in which R<SP>1</SP> is alkyl, cycloalkyl or aryl, having up to 12 carbons and M is a metal of Group I or II or aluminium of valency n. The ester-salt is preferably added in alcoholic solution. The polymerization may be stopped by adding a hydroxylamine salt. In the examples are prepared homopolymers and copolymers with methyl methacrylate or vinyl acetate, using a continuous process in some. Syndiotactic polymers are produced.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT823425 | 1967-12-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1246989A true GB1246989A (en) | 1971-09-22 |
Family
ID=11126165
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5998368A Expired GB1246989A (en) | 1967-12-19 | 1968-12-17 | The polymerisation or copolymerisation of vinyl chloride |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1246989A (en) |
-
1968
- 1968-12-17 GB GB5998368A patent/GB1246989A/en not_active Expired
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