GB1237195A - Process for the oxidation of hydrocarbons - Google Patents

Process for the oxidation of hydrocarbons

Info

Publication number
GB1237195A
GB1237195A GB56500/67A GB5650067A GB1237195A GB 1237195 A GB1237195 A GB 1237195A GB 56500/67 A GB56500/67 A GB 56500/67A GB 5650067 A GB5650067 A GB 5650067A GB 1237195 A GB1237195 A GB 1237195A
Authority
GB
United Kingdom
Prior art keywords
acid
oxidation
dec
mixture
hydrocarbons
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB56500/67A
Inventor
Cyril Gardner
Arthur Howard Gilbert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB56500/67A priority Critical patent/GB1237195A/en
Publication of GB1237195A publication Critical patent/GB1237195A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,237,195. Oxidation of hydrocarbons. IMPERIAL CHEMICAL INDUSTRIES Ltd. 4 Dec., 1968 [12 Dec., 1967], No. 56500/67. Heading C2C. A process for the manufacture of oxygenated products, e.g. alcohols, ketones, hydroxy-acids and dicarboxylic acids comprises oxidizing a saturated hydrocarbon with a molecular oxygencontaining gas in the presence of compounds of two or more metals from Groups IIB and IVB of the Periodic System, further oxidizing, if desired, with nitric acid to convert the resultant oxygenated products to the corresponding dicarboxylic acid. Boron compounds may also be present. An example describes the oxidation of cyclohexane in the presence of zinc and lead naphthenate to yield a mixture of adipic acid, #-hydroxy caproic acid, cyclohexanol and cyclohexanone, which mixture is further oxidized to adipic acid by treatment with nitric acid. Cyclooctane and cyclododecane are other suitable starting materials.
GB56500/67A 1967-12-12 1967-12-12 Process for the oxidation of hydrocarbons Expired GB1237195A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB56500/67A GB1237195A (en) 1967-12-12 1967-12-12 Process for the oxidation of hydrocarbons

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB56500/67A GB1237195A (en) 1967-12-12 1967-12-12 Process for the oxidation of hydrocarbons

Publications (1)

Publication Number Publication Date
GB1237195A true GB1237195A (en) 1971-06-30

Family

ID=10476778

Family Applications (1)

Application Number Title Priority Date Filing Date
GB56500/67A Expired GB1237195A (en) 1967-12-12 1967-12-12 Process for the oxidation of hydrocarbons

Country Status (1)

Country Link
GB (1) GB1237195A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10233464B4 (en) * 2002-07-24 2007-03-29 Degussa Ag Process for the preparation of an initiator for the oxidation of hydrocarbons

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10233464B4 (en) * 2002-07-24 2007-03-29 Degussa Ag Process for the preparation of an initiator for the oxidation of hydrocarbons

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