GB1227144A - - Google Patents

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Publication number
GB1227144A
GB1227144A GB1227144DA GB1227144A GB 1227144 A GB1227144 A GB 1227144A GB 1227144D A GB1227144D A GB 1227144DA GB 1227144 A GB1227144 A GB 1227144A
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phases
anion
reaction
quaternary salt
organic
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
    • C07C17/208—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being MX
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/14—Preparation of carboxylic acid nitriles by reaction of cyanides with halogen-containing compounds with replacement of halogen atoms by cyano groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
    • C07C273/1809—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas with formation of the N-C(O)-N moiety
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/32—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of salts of sulfonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C331/00—Derivatives of thiocyanic acid or of isothiocyanic acid
    • C07C331/02—Thiocyanates
    • C07C331/04—Thiocyanates having sulfur atoms of thiocyanate groups bound to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/20—Unsaturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/203—Unsaturated compounds containing keto groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/285—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with peroxy-compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1,227,144. Organic compounds. CONTINENTAL OIL CO. 27 March, 1968 [5 April, 1967], No. 14639/68. Heading C2C. Heterogeneous ionic organic reactions wherein the reactants are in a plurality of immiscible liquid phases with one of the reactants being located substantially entirely in a different phase from the contiguous phase in which a second reactant is located are catalysed by adding to one or both of the contiguous phases of the heterogeneous system, an organic quaternary salt which includes at least one group having the formula (R 1 R 2 R 3 R 4 M)<SP>+</SP>X<SP>-</SP> where M is a pentavalent ion of nitrogen, phosphorus, arsenic, antimony or bismuth, R 1 , R 2 , R 3 and R 4 are hydrocarbon radicals (wherein one of the hydrocarbon radicals may be substituted by a further quaternary group) the total number of carbon atoms being from 18 to 70, and X- is an anion which will dis sociate from the Catin (R 1 R 2 R 3 R 4 M) in an aqueous environment, said organic quaternary salt being substantially more soluble in the less polar of said reactantcontaining phases than in the other of said reactant-containing phases, said quaternary salt not forming an emulsion between the immiscible phases, and wherein in the catalysed reaction the organic quaternary salt exchanges an anion with one of the reactants located in one of the phases of the system, moves to the contiguous phase and said anion there reacts with the other reactant. Processes exemplified are the alkaline hydrolysis of esters, the permanganate oxidation of olefins, the borohydride reduction of ketones to alcohols, the alkaline hydrolysis of sulphonyl chlorides to metal sulphonates, the alkylation of malononitrile with alkyi bromides to give dialkyl malononitriles, the production of dichlorocarbenes from chloroform and their subsequent reaction with olefins to give unfused or fused l,1-dichlorocyclopropanes, and ionic displacement reactions, e.g. conversion of alkyl chlorides to alkyl cyanides, and of alkyl bromides to alkyl chlorides, iodides, acetates or thiocyanates by reaction with an appropriate anion, or to dialkyl ureas by reaction with a cyanate.
GB1227144D 1967-04-05 1968-03-27 Expired GB1227144A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US62853467A 1967-04-05 1967-04-05

Publications (1)

Publication Number Publication Date
GB1227144A true GB1227144A (en) 1971-04-07

Family

ID=24519296

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1227144D Expired GB1227144A (en) 1967-04-05 1968-03-27

Country Status (8)

Country Link
JP (1) JPS506441B1 (en)
AT (1) AT296229B (en)
BE (1) BE735936A (en)
BR (1) BR6898535D0 (en)
FR (1) FR1573164A (en)
GB (1) GB1227144A (en)
NL (1) NL164837C (en)
SE (1) SE339941B (en)

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3917667A (en) * 1972-05-16 1975-11-04 Shell Oil Co Process for preparing gem-dihalocyclopropanecarboxylic acid derivatives
US3972887A (en) * 1972-12-11 1976-08-03 The Dow Chemical Company Process for preparing phosphorothioates and phenylphosponothioates
US3984475A (en) * 1972-11-17 1976-10-05 Kuraray Co., Ltd. Process for the production of substituted ketones
US4012430A (en) * 1972-05-16 1977-03-15 Shell Oil Company Process for the preparation of cyclopropane derivatives
US4013700A (en) * 1974-11-25 1977-03-22 Union Carbide Corporation Catalytic process for polyhydric alcohols and derivatives
US4014891A (en) 1975-01-17 1977-03-29 The Dow Chemical Company Process for making aryl chloromethyl sulfides
US4016190A (en) * 1975-03-01 1977-04-05 Bayer Aktiengesellschaft Process for the preparation of diarylcarbonates
US4056509A (en) 1975-07-09 1977-11-01 Shell Oil Company Preparation of benzyl cyanides
US4059603A (en) 1971-11-12 1977-11-22 Sumitomo Chemical Company, Limited Esterification of carboxylic acids by contact with a phosphonium salt
US4079075A (en) * 1975-11-06 1978-03-14 The Dow Chemical Company Primary alkyl esters as mediums for oxidations by phase-transfer catalyzed hypohalites
US4101585A (en) * 1976-08-30 1978-07-18 Ciba-Geigy Corporation Process for the production of deoxy-alpha-acids
US4218400A (en) * 1977-02-04 1980-08-19 Rutgerswerke Aktiengesellschaft Process for the production of fluorenone by catalytic oxidation of fluorene
US4321395A (en) 1978-07-13 1982-03-23 Basf Aktiengesellschaft Preparation of acetanilides
US4328170A (en) * 1978-11-02 1982-05-04 Matsumoto Seiyaku Kogyo Kabushiki Kaisha Process for preparing an α-cyanoacrylate
US4387253A (en) * 1980-09-05 1983-06-07 The Boots Company Limited Preparation of dichlorobenzyl alcohol
US4491666A (en) * 1981-03-14 1985-01-01 Basf Aktiengesellschaft Preparation of anthraquinoid disperse dyes
US4584128A (en) * 1983-08-01 1986-04-22 International Flavors & Fragrances Inc. Mixture of one or more t-mercapto terpene isomers and α-terpineol organoleptic uses thereof
US4600791A (en) * 1983-12-12 1986-07-15 Borg-Warner Chemicals, Inc. Process for preparation of phosphazene esters
US4601843A (en) * 1985-04-02 1986-07-22 Borg-Warner Chemicals, Inc. Phosphazene based functional fluid compositions
US4695659A (en) * 1984-10-22 1987-09-22 Chemical Dynamics Development Ab Method for dealkylation of alkyl-aryl ethers
US4699634A (en) * 1985-07-08 1987-10-13 The Standard Oil Company Process for the modification of aromatic polymers via phase transfer catalysis to produce polyarylene polymers and the use thereof
EP1591435A2 (en) * 2004-03-26 2005-11-02 Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo Method for preparing 2,6-Naphtalene dicarboxyclic acid
DE10196976B4 (en) * 2000-11-29 2006-10-26 China Petroleum And Chemical Corporation Reaction-Controlled Phase Transfer Catalyst-Catalyzed Oxidation Reaction Process
EP1818323A2 (en) 2006-02-08 2007-08-15 Cognis IP Management GmbH Process for the preparation of unsymmetric alkoxylated mixed ethers
EP1918358A1 (en) 2006-10-11 2008-05-07 Cognis IP Management GmbH Process for the partial hydrogenation of fatty acid esters

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1539183A (en) * 1975-07-31 1979-01-31 Ici Ltd Process for the manufacture of aromatic ethers
DE2545644A1 (en) * 1975-10-11 1977-04-14 Bayer Ag PROCESS FOR THE PRODUCTION OF SULPHONIC ACIDS
DE2648965C2 (en) * 1976-10-28 1978-09-21 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt Process for the production of chloromethyl thiocyanate
FR2413348A1 (en) * 1977-12-31 1979-07-27 Dynamit Nobel Ag PROCESS FOR OBTAINING BENZYL ALCOHOLS
FR2434134A1 (en) * 1978-06-26 1980-03-21 Rhone Poulenc Agrochimie PROCESS FOR THE PREPARATION OF O-METHALLYLOXYPHENOL BY SELECTIVE MONOETHERIFICATION OF PYROCATECHIN
FR2442822A1 (en) * 1978-11-30 1980-06-27 Rhone Poulenc Agrochimie PROCESS FOR THE PREPARATION OF UNSATURATED ETHERS
IT1120780B (en) * 1979-06-06 1986-03-26 Montedison Spa PROCEDURE FOR THE PREPARATION OF 3,3-DIMETYL-ALLYL ALCOHOL
FR2467186A1 (en) * 1979-10-15 1981-04-17 Elf France ALKYL ETHERS OF POLYOLS, THEIR PREPARATION AND THEIR JOBS
DE3512518A1 (en) * 1985-04-06 1986-10-09 Deutsche Texaco Ag, 2000 Hamburg METHOD FOR THE CONTINUOUS PRODUCTION OF LOW ALCOHOLS
US4754089A (en) * 1986-12-05 1988-06-28 Sepracor Inc. Phase transfer catalysis

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4059603A (en) 1971-11-12 1977-11-22 Sumitomo Chemical Company, Limited Esterification of carboxylic acids by contact with a phosphonium salt
US4012430A (en) * 1972-05-16 1977-03-15 Shell Oil Company Process for the preparation of cyclopropane derivatives
US3917667A (en) * 1972-05-16 1975-11-04 Shell Oil Co Process for preparing gem-dihalocyclopropanecarboxylic acid derivatives
US3984475A (en) * 1972-11-17 1976-10-05 Kuraray Co., Ltd. Process for the production of substituted ketones
US3972887A (en) * 1972-12-11 1976-08-03 The Dow Chemical Company Process for preparing phosphorothioates and phenylphosponothioates
US4013700A (en) * 1974-11-25 1977-03-22 Union Carbide Corporation Catalytic process for polyhydric alcohols and derivatives
US4014891A (en) 1975-01-17 1977-03-29 The Dow Chemical Company Process for making aryl chloromethyl sulfides
US4016190A (en) * 1975-03-01 1977-04-05 Bayer Aktiengesellschaft Process for the preparation of diarylcarbonates
US4056509A (en) 1975-07-09 1977-11-01 Shell Oil Company Preparation of benzyl cyanides
US4079075A (en) * 1975-11-06 1978-03-14 The Dow Chemical Company Primary alkyl esters as mediums for oxidations by phase-transfer catalyzed hypohalites
US4101585A (en) * 1976-08-30 1978-07-18 Ciba-Geigy Corporation Process for the production of deoxy-alpha-acids
US4218400A (en) * 1977-02-04 1980-08-19 Rutgerswerke Aktiengesellschaft Process for the production of fluorenone by catalytic oxidation of fluorene
US4321395A (en) 1978-07-13 1982-03-23 Basf Aktiengesellschaft Preparation of acetanilides
US4328170A (en) * 1978-11-02 1982-05-04 Matsumoto Seiyaku Kogyo Kabushiki Kaisha Process for preparing an α-cyanoacrylate
US4387253A (en) * 1980-09-05 1983-06-07 The Boots Company Limited Preparation of dichlorobenzyl alcohol
US4491666A (en) * 1981-03-14 1985-01-01 Basf Aktiengesellschaft Preparation of anthraquinoid disperse dyes
US4584128A (en) * 1983-08-01 1986-04-22 International Flavors & Fragrances Inc. Mixture of one or more t-mercapto terpene isomers and α-terpineol organoleptic uses thereof
US4600791A (en) * 1983-12-12 1986-07-15 Borg-Warner Chemicals, Inc. Process for preparation of phosphazene esters
US4695659A (en) * 1984-10-22 1987-09-22 Chemical Dynamics Development Ab Method for dealkylation of alkyl-aryl ethers
US4601843A (en) * 1985-04-02 1986-07-22 Borg-Warner Chemicals, Inc. Phosphazene based functional fluid compositions
US4699634A (en) * 1985-07-08 1987-10-13 The Standard Oil Company Process for the modification of aromatic polymers via phase transfer catalysis to produce polyarylene polymers and the use thereof
DE10196976B4 (en) * 2000-11-29 2006-10-26 China Petroleum And Chemical Corporation Reaction-Controlled Phase Transfer Catalyst-Catalyzed Oxidation Reaction Process
EP1591435A2 (en) * 2004-03-26 2005-11-02 Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo Method for preparing 2,6-Naphtalene dicarboxyclic acid
EP1591435A3 (en) * 2004-03-26 2007-11-28 Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo Method for preparing 2,6-Naphtalene dicarboxyclic acid
US7355071B2 (en) 2004-03-26 2008-04-08 Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo Method for preparing 2,6-naphthalene dicarboxylic acid
EP1818323A2 (en) 2006-02-08 2007-08-15 Cognis IP Management GmbH Process for the preparation of unsymmetric alkoxylated mixed ethers
EP1918358A1 (en) 2006-10-11 2008-05-07 Cognis IP Management GmbH Process for the partial hydrogenation of fatty acid esters
US8263794B2 (en) 2006-10-11 2012-09-11 Cognis Ip Management Gmbh Process for the partial hydrogenation of fatty acid esters

Also Published As

Publication number Publication date
NL6804687A (en) 1968-10-07
AT296229B (en) 1972-02-10
SE339941B (en) 1971-11-01
NL164837C (en) 1981-02-16
BE735936A (en) 1969-12-16
BR6898535D0 (en) 1973-01-04
NL164837B (en) 1980-09-15
JPS506441B1 (en) 1975-03-14
FR1573164A (en) 1969-07-04

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Legal Events

Date Code Title Description
PS Patent sealed
746 Register noted 'licences of right' (sect. 46/1977)
PE20 Patent expired after termination of 20 years