FR2127063A6 - Catalysed oxidation of olefins in a hetero-generous system - Google Patents

Catalysed oxidation of olefins in a hetero-generous system

Info

Publication number
FR2127063A6
FR2127063A6 FR7105925A FR7105925A FR2127063A6 FR 2127063 A6 FR2127063 A6 FR 2127063A6 FR 7105925 A FR7105925 A FR 7105925A FR 7105925 A FR7105925 A FR 7105925A FR 2127063 A6 FR2127063 A6 FR 2127063A6
Authority
FR
France
Prior art keywords
olefins
aqs
organic
quaternary
oxidising agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR7105925A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ConocoPhillips Co
Original Assignee
Continental Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Continental Oil Co filed Critical Continental Oil Co
Priority to FR7105925A priority Critical patent/FR2127063A6/en
Priority to BE763326A priority patent/BE763326R/en
Application granted granted Critical
Publication of FR2127063A6 publication Critical patent/FR2127063A6/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Heterogeneous ionic organic reactions, particularly the oxidation of olefins, is greatly facilitated (c.f. parent patent) by placing the olefin in an oily phase together with an oxidising agent in an aqs. phase to form a heterogeneous system, and adding thereto an organic quaternary salt contg. at least one gp. of formula (AM)+X- (wherein M is a pentavalent ion of an element selected from N, P, As, Sb and Bi; A is an organic fragment of the salt molecule linked to M by four covalent links; X- is an anion dissociating from the cation (AM)+ in aqs. medium. A metallic oxide is also present as catalyst, suitably OsO4 or RuO4. The oxidising agent may be H2O2 or periodic acid, and suitable quaternary salts are quaternary ammonium salts such as methyl-tricaprylyl-ammonium chloride, tridecyl methylammonium chloride.
FR7105925A 1968-11-22 1971-02-22 Catalysed oxidation of olefins in a hetero-generous system Expired FR2127063A6 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR7105925A FR2127063A6 (en) 1971-02-22 1971-02-22 Catalysed oxidation of olefins in a hetero-generous system
BE763326A BE763326R (en) 1968-11-22 1971-02-23 Catalysed oxidation of olefins in a hetero-generous system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7105925A FR2127063A6 (en) 1971-02-22 1971-02-22 Catalysed oxidation of olefins in a hetero-generous system

Publications (1)

Publication Number Publication Date
FR2127063A6 true FR2127063A6 (en) 1972-10-13

Family

ID=9072266

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7105925A Expired FR2127063A6 (en) 1968-11-22 1971-02-22 Catalysed oxidation of olefins in a hetero-generous system

Country Status (1)

Country Link
FR (1) FR2127063A6 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2300765A1 (en) * 1975-02-11 1976-09-10 Ugine Kuhlmann EPOXIDATION PROCESS
EP0000143A1 (en) * 1977-06-29 1979-01-10 Phillips Petroleum Company Olefin oxidation process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2300765A1 (en) * 1975-02-11 1976-09-10 Ugine Kuhlmann EPOXIDATION PROCESS
EP0000143A1 (en) * 1977-06-29 1979-01-10 Phillips Petroleum Company Olefin oxidation process

Similar Documents

Publication Publication Date Title
Chang et al. Kinetics of aquation of aquopentachloroiridate (III) and chloride anation of diaquotetrachloroiridate (III) anions
GB1418704A (en) Halogenation of aromatic and heteroaromatic compounds
ES445564A1 (en) Production of olefin oxides
AT339870B (en) LOOP REACTOR FOR CHEMICAL REACTIONS, ETC.
FR2127063A6 (en) Catalysed oxidation of olefins in a hetero-generous system
NL7100563A (en) Catalysed oxidation of olefins in a hetero-generous system
BE763326R (en) Catalysed oxidation of olefins in a hetero-generous system
ES417099A1 (en) Oxidising agent method and apparatus for cutting metal
GB1147997A (en) Process for the catalytic oxidation of toluene with oxygen, in the gaseous phase, to benzaldehyde
GB1515190A (en) Process for preparing a hydroxylammonium salt solution
ES435827A1 (en) Process for reactivating platinum catalysts used in production of hydroxylammonium salts
Beck Effect of Fluoride Ion on the Activation of Molecular Hydrogen by Silver (I)
GB1155281A (en) Process for Preparing Allyl Chloride and its Monomethyl Substitution Products.
GB1030945A (en) Improvements in or relating to the production of fluorocarbons
GB1006593A (en) Improvements in or relating to amidino hydrazones and the manufacture thereof
US3104263A (en) Process for the manufacture of acetaldehyde
ES2031259T3 (en) PROCEDURE FOR THE PREPARATION OF BENZOIC ACID DERIVATIVES.
Epstein et al. Silver ion assisted dimethyl sulphoxide oxidations of organic halides
GB1042365A (en) The production of adiponitrile
GB1341575A (en)
IE34875L (en) Bipyridylium compounds.
GB1101591A (en) Process for the preparation of chloro-organo-polysulphides
GB1111833A (en) Process for the production of 4-hydroxy-2-sulpholene
GB1075218A (en) Preparation of alkyl chlorides
ES351613A3 (en) Procedure for the manufacture of tetrae-tiltiuram disulfide. (Machine-translation by Google Translate, not legally binding)