NL7100563A - Catalysed oxidation of olefins in a hetero-generous system - Google Patents

Catalysed oxidation of olefins in a hetero-generous system

Info

Publication number
NL7100563A
NL7100563A NL7100563A NL7100563A NL7100563A NL 7100563 A NL7100563 A NL 7100563A NL 7100563 A NL7100563 A NL 7100563A NL 7100563 A NL7100563 A NL 7100563A NL 7100563 A NL7100563 A NL 7100563A
Authority
NL
Netherlands
Prior art keywords
olefins
aqs
organic
quaternary
oxidising agent
Prior art date
Application number
NL7100563A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Priority to NL7100563A priority Critical patent/NL7100563A/en
Publication of NL7100563A publication Critical patent/NL7100563A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Heterogeneous ionic organic reactions, particularly the oxidation of olefins, is greatly facilitated (c.f. parent patent) by placing the olefin in an oily phase together with an oxidising agent in an aqs. phase to form a heterogeneous system, and adding thereto an organic quaternary salt contg. at least one gp. of formula (AM)+X- (wherein M is a pentavalent ion of an element selected from N, P, As, Sb and Bi; A is an organic fragment of the salt molecule linked to M by four covalent links; X- is an anion dissociating from the cation (AM)+ in aqs. medium. A metallic oxide is also present as catalyst, suitably OsO4 or RuO4. The oxidising agent may be H2O2 or periodic acid, and suitable quaternary salts are quaternary ammonium salts such as methyl-tricaprylyl-ammonium chloride, tridecyl methylammonium chloride.
NL7100563A 1971-01-15 1971-01-15 Catalysed oxidation of olefins in a hetero-generous system NL7100563A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
NL7100563A NL7100563A (en) 1971-01-15 1971-01-15 Catalysed oxidation of olefins in a hetero-generous system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7100563A NL7100563A (en) 1971-01-15 1971-01-15 Catalysed oxidation of olefins in a hetero-generous system

Publications (1)

Publication Number Publication Date
NL7100563A true NL7100563A (en) 1972-07-18

Family

ID=19812266

Family Applications (1)

Application Number Title Priority Date Filing Date
NL7100563A NL7100563A (en) 1971-01-15 1971-01-15 Catalysed oxidation of olefins in a hetero-generous system

Country Status (1)

Country Link
NL (1) NL7100563A (en)

Similar Documents

Publication Publication Date Title
ES479787A1 (en) Technique for forming multi-component oxide complex catalysts.
GB1418704A (en) Halogenation of aromatic and heteroaromatic compounds
ES445564A1 (en) Production of olefin oxides
AT339870B (en) LOOP REACTOR FOR CHEMICAL REACTIONS, ETC.
FR2127063A6 (en) Catalysed oxidation of olefins in a hetero-generous system
NL7100563A (en) Catalysed oxidation of olefins in a hetero-generous system
BE763326R (en) Catalysed oxidation of olefins in a hetero-generous system
ES417099A1 (en) Oxidising agent method and apparatus for cutting metal
GB1147997A (en) Process for the catalytic oxidation of toluene with oxygen, in the gaseous phase, to benzaldehyde
ES288701A1 (en) Procedure for the preparation of hydroxylamine (Machine-translation by Google Translate, not legally binding)
GB902368A (en) Oxidation of alcohols
AR205757A1 (en) PROCEDURE TO PREPARE A HYDROXYLAMONIC SALT SOLUTION BY CATALYTIC REDUCTION OF NITRATE IONS IN AN ACID MEDIUM IN THE PRESENCE OF A CATALYST CONSTITUTED BY PALADIUM OR CONTAINING PALADIUM
MX3304E (en) PROCEDURE FOR PREPARING AN ALPHA-AMINO ACID
ES435827A1 (en) Process for reactivating platinum catalysts used in production of hydroxylammonium salts
Beck Effect of Fluoride Ion on the Activation of Molecular Hydrogen by Silver (I)
GB1155281A (en) Process for Preparing Allyl Chloride and its Monomethyl Substitution Products.
GB1006593A (en) Improvements in or relating to amidino hydrazones and the manufacture thereof
ES2031259T3 (en) PROCEDURE FOR THE PREPARATION OF BENZOIC ACID DERIVATIVES.
Epstein et al. Silver ion assisted dimethyl sulphoxide oxidations of organic halides
GB1042365A (en) The production of adiponitrile
IE34875L (en) Bipyridylium compounds.
GB1075218A (en) Preparation of alkyl chlorides
ES351613A3 (en) Procedure for the manufacture of tetrae-tiltiuram disulfide. (Machine-translation by Google Translate, not legally binding)
Savin et al. Mechanism of the secondary azo-combination of monoazo-derivatives of chromotropic acid, taken in the form of cyclic salts
Oraevskii Controlled stimulation of chemical reactions by laser radiation

Legal Events

Date Code Title Description
BV The patent application has lapsed