BE763326R - Catalysed oxidation of olefins in a hetero-generous system - Google Patents

Catalysed oxidation of olefins in a hetero-generous system

Info

Publication number
BE763326R
BE763326R BE763326A BE763326A BE763326R BE 763326 R BE763326 R BE 763326R BE 763326 A BE763326 A BE 763326A BE 763326 A BE763326 A BE 763326A BE 763326 R BE763326 R BE 763326R
Authority
BE
Belgium
Prior art keywords
olefins
aqs
organic
quaternary
oxidising agent
Prior art date
Application number
BE763326A
Other languages
French (fr)
Original Assignee
Continental Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR7105925A external-priority patent/FR2127063A6/en
Application filed by Continental Oil Co filed Critical Continental Oil Co
Application granted granted Critical
Publication of BE763326R publication Critical patent/BE763326R/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/285—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with peroxy-compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Heterogeneous ionic organic reactions, particularly the oxidation of olefins, is greatly facilitated (c.f. parent patent) by placing the olefin in an oily phase together with an oxidising agent in an aqs. phase to form a heterogeneous system, and adding thereto an organic quaternary salt contg. at least one gp. of formula (AM)+X- (wherein M is a pentavalent ion of an element selected from N, P, As, Sb and Bi; A is an organic fragment of the salt molecule linked to M by four covalent links; X- is an anion dissociating from the cation (AM)+ in aqs. medium. A metallic oxide is also present as catalyst, suitably OsO4 or RuO4. The oxidising agent may be H2O2 or periodic acid, and suitable quaternary salts are quaternary ammonium salts such as methyl-tricaprylyl-ammonium chloride, tridecyl methylammonium chloride.
BE763326A 1968-11-22 1971-02-23 Catalysed oxidation of olefins in a hetero-generous system BE763326R (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US77832468A 1968-11-22 1968-11-22
FR7105925A FR2127063A6 (en) 1971-02-22 1971-02-22 Catalysed oxidation of olefins in a hetero-generous system

Publications (1)

Publication Number Publication Date
BE763326R true BE763326R (en) 1971-08-23

Family

ID=26216218

Family Applications (1)

Application Number Title Priority Date Filing Date
BE763326A BE763326R (en) 1968-11-22 1971-02-23 Catalysed oxidation of olefins in a hetero-generous system

Country Status (1)

Country Link
BE (1) BE763326R (en)

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