GB1222686A - Detergent compositions with textile softening properties - Google Patents

Detergent compositions with textile softening properties

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Publication number
GB1222686A
GB1222686A GB26712/68A GB2671268A GB1222686A GB 1222686 A GB1222686 A GB 1222686A GB 26712/68 A GB26712/68 A GB 26712/68A GB 2671268 A GB2671268 A GB 2671268A GB 1222686 A GB1222686 A GB 1222686A
Authority
GB
United Kingdom
Prior art keywords
carbon atoms
alkyl
sodium
radical
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB26712/68A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of GB1222686A publication Critical patent/GB1222686A/en
Expired legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/02—Sulfonic acids having sulfo groups bound to acyclic carbon atoms
    • C07C309/03—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C309/07—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing oxygen atoms bound to the carbon skeleton
    • C07C309/12—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing oxygen atoms bound to the carbon skeleton containing esterified hydroxy groups bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/02—Sulfonic acids having sulfo groups bound to acyclic carbon atoms
    • C07C309/03—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C309/13—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing nitrogen atoms, not being part of nitro or nitroso groups, bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • C07F9/5304—Acyclic saturated phosphine oxides or thioxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • C08G65/2606—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
    • C08G65/2609—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups containing aliphatic hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/321—Polymers modified by chemical after-treatment with inorganic compounds
    • C08G65/326—Polymers modified by chemical after-treatment with inorganic compounds containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3472—Organic compounds containing sulfur additionally containing -COOH groups or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/60—Optical bleaching or brightening
    • D06L4/657—Optical bleaching or brightening combined with other treatments, e.g. finishing, bleaching, softening, dyeing or pigment printing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/60—Optical bleaching or brightening
    • D06L4/664—Preparations of optical brighteners; Optical brighteners in aerosol form; Physical treatment of optical brighteners
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/262—Sulfated compounds thiosulfates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/285—Phosphines; Phosphine oxides; Phosphine sulfides; Phosphinic or phosphinous acids or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/388—Amine oxides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)
  • Powder Metallurgy (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)

Abstract

1,222,686. Softening textiles. PROCTER & GAMBLE CO. 5 June, 1968 ,[5 June, 1967 (2)], No. 26712/68. Heading DIP. [Also in Division C5] A detergent composition with textile softening properties comprises by weight of the total composition:-(a) from 1% to 20% of a water soluble anionic, nonionic, ampholytic or zwilterionic synthetic detergent having in its molecular structure one hydrophobic radical from 8-18 carbon atoms (b) from 0-90% of a water soluble alkaline builder salt, (c) from 1-25% of a textile softening agent which is (i) a zwilterionic compound of general formula: in which R<SP>1</SP> and R<SP>2</SP> which may be the same or different are each methyl, ethyl, n-propyl, isopropyl, 2-hydroxy-ethyl or 2-hydroxypropyl, R<SP>3</SP> is straight or branched C 20-30 alkyl or C 20-30 alkenyl chain which may be substituted with 1 or 2 hydroxyl groups and which may be interrupted by 1 to 5 ether linkages and 1 amide linkage and R is an alkylene radical or monohydroxy-alkylene radical of from 1-4 carbon atoms; or (ii) a tertiary amine oxide of formula:- in which R<SP>4</SP> is straight or branched chain C 20-30 alkyl or alkenyl which may be interrupted by 1-5 ether linkages or 1 amide linkage and which may carry 1 or 2 hydroxyl substituents and 1 or 2 chloro substituents, R<SP>6</SP> is methyl, ethyl, n-propyl, isopropyl, 2-hydroxyethyl or 2-hydroxy propyl, R<SP>5</SP> is an alkyl radical of from 1 to 20 carbon atoms which may be interrupted by from 1 to 5 ether linkages and 1 amide linkage and which may carry from 1 to 2 hydroxyl substituents and from 1 to 2 chloro substituents or R<SP>5</SP> and R<SP>6</SP> together with the nitrogen atom may form a heterocyclic radical of from 4 to 6 carbon atoms which may contain oxygen as a second hetero atom (III) a tertiary phosphine oxide of the general formula:- in which R<SP>7</SP> is an alkyl, alkenyl or monohydroxyalkyl radical of from 20 to 30 carbon atoms and R<SP>8</SP> and R<SP>9</SP> which may be the same or different are each alkyl or monohydroxy alkyl groups of from 1 to 4 carbon atoms (IV) sulphated ethoxylated alcohol compounds of the general formula: in which R<SP>10</SP> is a C 21-30 alkyl radical M is an alkali metal ammonium or substituted ammonium and y is an integer of from 1 to 20, (V) anionic sulphonate compounds of the general formula: in which R 11 is a C 20-30 alkyl radical and M has the same meaning as above (VI) a mixture of two or more of (I) to (V) and (d) water. Anionic synthetic detergents mentioned are sodium alkyl sulphates; sodium or potassium alkylbenzenesulphonates, the alkyl group containing 9 to 15 carbon atoms; sodium alkylglyceryl ether sulphonates; sodium coconut oil fatty acid monoglyceride sulphates and sulphonates; sodium or potassium salts of sulphuric acid esters of the reaction product of one mole of a higher fatty alcohol and from 1 to 6 moles of ethylene oxide, sodium or potassium salts of alkylphenol ethylene. oxide ether sulphates with 1 to 10 units of ethylene oxide per molecule and in which the alkyl radicals contain 9 to 12 carbon atoms; the reaction product of fatty acids esterified with isothionic acid and neutralised with sodium hydroxide, or sodium or potassuim salts of fatty acid amines of a methyltauride. Nonionic synthetic detergent mentioned are condensation products of ethylene oxide and a hydrophobic base formed by the condensation of propylene oxide with propylene glycol; polyethylene oxide condensates of alkylphenols; condensation products of ethylene oxide and the product resulting from the reaction of propylene oxide and ethylenediamine, condensation product of aliphatic alcohols having from 8 to 18 carbon atoms with ethylene oxide; long chain tertiary amine oxides of formula RR'R"N->0 in which R is an alkyl radical of from 8 to 18 carbon atoms, and R' and R" are each methyl or ethyl radicals; long chain tertiary phosphine oxides of formula RR'R"P->0 in which R is an alkyl, alkenyl or monohydroxyalkyl radical from 10 to 18 carbon atoms and R' and R" are each alkyl or monohydroxyalkyl groups containing 1 to 3 carbon atoms. Ampholytic synthetic detergents mentioned are derivatives of aliphatic amines which contain long chains of from 8 to 18 carbon atoms and an anionic water solubilizing group zwelterionic synthetic detergents include derivatives of aliphatic quaternary ammonium compounds, in which the aliphatic radical may be straight chain or branched and wherein one of the aliphatic substituents contains from 8 to 18 carbon atoms and one contains an anionic watersolubilizing group. Water-soluble inorganic alkaline builder salts may be alkali metal or ammonium or substituted ammonium carbonates borates, phosphates, polyphosphates, bicarbonates and silicates. Organic alkaline sequestrant builder salts which may be used are alkali metal, ammonium or substituted ammonium aminopolycarboxylates. Water soluble salts of ethane-1-hydroxy-11-diphosphonate, water soluble salts of methylene diphosphonic acid, substituted or not, water soluble salts of polycarboxylite polymers and copolymers. Optionally the compositions may contain brightening agent from 0.01% to 1.0% by weight of the total composition. these include cotton brighteners of the bis-triazinyl stilbene type, the bis-N-acylstilbene type; the stilbenetriazole type and the dibenzothiophenedioxide type. Other brighteners mentioned are the bisazoles, monozoles; pyrazolines; and coumarins. The detergent softener compositions may also contain other compatible softening agents such as ester-, ether-, or amide like condensation products containing polyalcohol, polyglycol, polyglycerol radicals and other suitable higher molecular, preferably long chain aliphatic, radicals with 12 to 18 carbon atoms or sulphated or sulphonated long chain aliphatic alcohols. Condensation products of long chain fatty acids with hydroxy- or amino sulphonic acid; as well as additives such as diluents, e.g. sodium sulphate; tarnish inhibitors, bactericides, anti-redeposition agents e.g. sodium carboxymethyl cellulose, sud boosters, colours and perfumes. The compositions of the invention may be in granular, flake, liquid and tablet forms. Reference has been directed by the Comptroller to Specification 1,222,687.
GB26712/68A 1967-06-05 1968-06-05 Detergent compositions with textile softening properties Expired GB1222686A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US64852767A 1967-06-05 1967-06-05
US64334367A 1967-06-05 1967-06-05

Publications (1)

Publication Number Publication Date
GB1222686A true GB1222686A (en) 1971-02-17

Family

ID=27094241

Family Applications (2)

Application Number Title Priority Date Filing Date
GB26713/68A Expired GB1222687A (en) 1967-06-05 1968-06-05 Textile softening compositions
GB26712/68A Expired GB1222686A (en) 1967-06-05 1968-06-05 Detergent compositions with textile softening properties

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB26713/68A Expired GB1222687A (en) 1967-06-05 1968-06-05 Textile softening compositions

Country Status (12)

Country Link
US (1) US3554784A (en)
AT (2) AT305196B (en)
AU (1) AU429843B2 (en)
BE (1) BE716077A (en)
CH (2) CH502473A (en)
DE (2) DE1769504A1 (en)
FI (2) FI46530C (en)
FR (1) FR1568522A (en)
GB (2) GB1222687A (en)
NL (1) NL6807890A (en)
NO (2) NO126804B (en)
SE (2) SE350066B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3956302A (en) 1974-05-24 1976-05-11 The Upjohn Company Substituted pyrimidines

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4053992A (en) * 1970-10-20 1977-10-18 Colgate-Palmolive Company Apparatus and method for conditioning fibrous materials, utilizing and abradable conditioning agent fastened to the interior of an automatic laundry dryer door
US4000077A (en) * 1972-05-04 1976-12-28 Colgate-Palmolive Company Enhancement of cationic softener
ES426477A1 (en) * 1973-05-26 1976-07-01 Hoechst Ag Fiber-lubricating compositions
US4057673A (en) * 1974-10-09 1977-11-08 Colgate Palmolive Company Fabric conditioning with improved composition containing a plasticizer
DE3028016A1 (en) 1980-07-24 1982-02-25 Hoechst Ag, 6000 Frankfurt PREPARATION AGENTS FOR SYNTHESIS FIBERS AND THE USE THEREOF
NZ201857A (en) * 1982-09-09 1985-09-13 Wool Res Organisation An antistatic composition containing a water insoluble quaternary ammonium salt and a nonionic surfactant
US4795032A (en) * 1987-12-04 1989-01-03 S. C. Johnson & Son, Inc. Wash-added, rinse-activated fabric conditioner and package
DE68919236T2 (en) * 1988-01-28 1995-04-06 Unilever Nv Textile treatment preparation and its manufacture.
US4970008A (en) * 1988-12-20 1990-11-13 Kandathil Thomas V Fabric conditioner comprising a mixture of quaternary ammonium compounds and select tertiary amines
DE19829787A1 (en) * 1998-07-03 2000-01-05 Henkel Kgaa Finishing agent
US20080229513A1 (en) * 2007-03-23 2008-09-25 John Michael Ogden Method of obtaining effective transfer of liquid fabric treatment compositions containing limited amounts of cationic compounds to clothing in washing machines

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3956302A (en) 1974-05-24 1976-05-11 The Upjohn Company Substituted pyrimidines

Also Published As

Publication number Publication date
SE350066B (en) 1972-10-16
AU429843B2 (en) 1972-11-07
FI49059B (en) 1974-12-02
GB1222687A (en) 1971-02-17
FI49059C (en) 1975-03-10
CH822768A4 (en) 1971-03-15
NO126803B (en) 1973-03-26
US3554784A (en) 1971-01-12
FR1568522A (en) 1969-05-23
AT305196B (en) 1973-02-12
DE1767682A1 (en) 1971-09-23
NL6807890A (en) 1968-12-06
CH509400A (en) 1971-08-13
CH502473A (en) 1971-03-15
CH825568A4 (en) 1971-08-13
BE716077A (en) 1968-12-04
FI46530B (en) 1973-01-02
DE1769504A1 (en) 1971-07-22
AU4480368A (en) 1970-04-23
FI46530C (en) 1973-04-10
SE359129B (en) 1973-08-20
NO126804B (en) 1973-03-26
AT317392B (en) 1974-08-26

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PS Patent sealed [section 19, patents act 1949]
PLNP Patent lapsed through nonpayment of renewal fees