GB1054755A - Polyelectrolyte builders and detergent compositions - Google Patents

Polyelectrolyte builders and detergent compositions

Info

Publication number
GB1054755A
GB1054755A GB1285864A GB1285864A GB1054755A GB 1054755 A GB1054755 A GB 1054755A GB 1285864 A GB1285864 A GB 1285864A GB 1285864 A GB1285864 A GB 1285864A GB 1054755 A GB1054755 A GB 1054755A
Authority
GB
United Kingdom
Prior art keywords
acid
carboxyl
carboxymethyl
methyl
aliphatic polycarboxylic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1285864A
Inventor
Francis Louvaine Diehl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of GB1054755A publication Critical patent/GB1054755A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C55/00—Saturated compounds having more than one carboxyl group bound to acyclic carbon atoms
    • C07C55/24—Saturated compounds having more than one carboxyl group bound to acyclic carbon atoms containing more than three carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/235—Saturated compounds containing more than one carboxyl group
    • C07C59/305—Saturated compounds containing more than one carboxyl group containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Detergent Compositions (AREA)

Abstract

1,054,755. Detergent composition. PROCTER & GAMBLE CO. March 26, 1964 [April 1. 1963], No. 12858/64. Heading C5D. [Also in Division C3] A cleansing and laundering composition comprises an organic water-soluble anionic, non- ionic, zwitterionic or ampholytic detergent surfactant or a mixture thereof and a polyelectrolyte builder material comprising a watersoluble salt of a polymeric aliphatic polycarboxylic acid having the following properties: (a) a minimum molecular weight of 350 calculated as the acid form: (b) an equivalent weight of from 50 to 80 calculated as the acid form; and (c) at least 45 mole per cent of the monomeric species making up the polymer being aliphatic polycarboxylic species having at least two carboxyl radicals on the same carbon atom or on adjacent carbon atoms, not more than 27.5 mole per cent of the monomeric species making up the polymer having the form wherein one or more of the groups R is a non- carboxyl containing radical or molecular weight exceeding 16. Preferably, the polyelectrolyte builder material is a water-soluble salt of a homopolymer of an aliphatic polycarboxylic acid, the homopolymer having the following general formula wherein X, Y, and Z are each independently hydrogen, methyl, carboxyl or carboxymethyl; at least one of X. Y and Z being carboxyl or carboxymethyl and not more than one of X, Y and Z being methyl, provided that X and Y either individually or together, can be carboxymethyl only when Z is carboxyl or earboxymethyl; and wherein n is an integer of from three to an upper limiting value such that the polyelectrolyte builder has a solubility in water of at least 0.01% by weight. Suitable acids include maleic, itaconic, mesaconic, fumaric, aconitic, methylenemalonic and citraconic; these may be homo- or copolymerized with each other, or copolymerized with ethylene, propylene, acrylic acid, methacrylic acid, crotonic acid, 3-butenoic acid. 3-methyl-3- butenoic acid or 4-pentenoic acid.
GB1285864A 1963-04-01 1964-03-26 Polyelectrolyte builders and detergent compositions Expired GB1054755A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US269359A US3308067A (en) 1963-04-01 1963-04-01 Polyelectrolyte builders and detergent compositions
NL6501871A NL132878C (en) 1963-04-01 1965-02-15 Method for preparing a detergent or cleaning agent
BE685413 1966-08-11

Publications (1)

Publication Number Publication Date
GB1054755A true GB1054755A (en) 1967-01-11

Family

ID=27159179

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1285864A Expired GB1054755A (en) 1963-04-01 1964-03-26 Polyelectrolyte builders and detergent compositions

Country Status (12)

Country Link
US (1) US3308067A (en)
AT (1) AT278215B (en)
AU (1) AU293474B2 (en)
BE (1) BE685413A (en)
CH (1) CH490491A (en)
DE (1) DE1467656B2 (en)
DK (1) DK119268B (en)
FI (1) FI42739B (en)
FR (1) FR1476512A (en)
GB (1) GB1054755A (en)
NL (1) NL132878C (en)
SE (1) SE328362B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5159041A (en) * 1989-12-14 1992-10-27 Lever Brothers Company Polymers and detergent compositions containing them
US5431846A (en) * 1993-05-20 1995-07-11 Lever Brothers Company, Division Of Conopco, Inc. Copolymers and detergent compositions containing them
WO2015147623A1 (en) * 2014-03-25 2015-10-01 Instituto Mexicano Del Petroléo Method for obtaining random terpolymers derived from itaconic acid and aconitic acid, and/or the isomers thereof, and/or sodium alkenyl sulphonates, and use of the resulting product

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AU4194664A (en) 1966-09-08
FR1476512A (en) 1967-04-14
AU293474B2 (en) 1969-08-19
US3308067A (en) 1967-03-07
CH490491A (en) 1970-05-15
FI42739B (en) 1970-06-30
DE1467656B2 (en) 1973-02-22
SE328362B (en) 1970-09-14
BE685413A (en) 1967-01-16
AT278215B (en) 1970-01-26
NL6501871A (en) 1966-08-16
NL132878C (en) 1971-07-15
DE1467656A1 (en) 1969-10-23
DK119268B (en) 1970-12-07

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