GB1209384A - Method of producing polybutadiene - Google Patents
Method of producing polybutadieneInfo
- Publication number
- GB1209384A GB1209384A GB25507/68A GB2550768A GB1209384A GB 1209384 A GB1209384 A GB 1209384A GB 25507/68 A GB25507/68 A GB 25507/68A GB 2550768 A GB2550768 A GB 2550768A GB 1209384 A GB1209384 A GB 1209384A
- Authority
- GB
- United Kingdom
- Prior art keywords
- butadiene
- catalyst
- cooh
- nickel
- complex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000005062 Polybutadiene Substances 0.000 title 1
- 229920002857 polybutadiene Polymers 0.000 title 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 abstract 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 abstract 1
- 229940093475 2-ethoxyethanol Drugs 0.000 abstract 1
- 229910015900 BF3 Inorganic materials 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 abstract 1
- ORTFAQDWJHRMNX-UHFFFAOYSA-N hydroxidooxidocarbon(.) Chemical compound O[C]=O ORTFAQDWJHRMNX-UHFFFAOYSA-N 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- DVTHIMLUHWEZOM-UHFFFAOYSA-L nickel(2+);octanoate Chemical compound [Ni+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O DVTHIMLUHWEZOM-UHFFFAOYSA-L 0.000 abstract 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F36/06—Butadiene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US65199167A | 1967-07-10 | 1967-07-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1209384A true GB1209384A (en) | 1970-10-21 |
Family
ID=24615073
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB25507/68A Expired GB1209384A (en) | 1967-07-10 | 1968-05-28 | Method of producing polybutadiene |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3528957A (https=) |
| BE (1) | BE717604A (https=) |
| DE (1) | DE1770587A1 (https=) |
| FR (1) | FR1573466A (https=) |
| GB (1) | GB1209384A (https=) |
| NL (1) | NL6809757A (https=) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4096322A (en) * | 1974-12-23 | 1978-06-20 | The Goodyear Tire & Rubber Company | Polymerization of butadiene |
| US4020255A (en) * | 1975-05-07 | 1977-04-26 | The Goodyear Tire & Rubber Company | Continuous insitu catalyst addition for polybutadiene polymerization |
| US4383097A (en) * | 1981-08-21 | 1983-05-10 | The Goodyear Tire & Rubber Company | Molecular weight regulation of cis-1,4-polybutadiene |
| US4522989A (en) * | 1984-06-04 | 1985-06-11 | The Firestone Tire & Rubber Company | Method of preparing high cis-1,4 diene polymers having good green strength and tack using a catalyst composition containing a carboxylated metal oxy aluminate component |
| US4522988A (en) * | 1984-06-04 | 1985-06-11 | The Firestone Tire & Rubber Company | Method of preparing high cis-1,4 diene polymers having good green strength and tack |
| US4562172A (en) * | 1984-06-04 | 1985-12-31 | The Firestone Tire & Rubber Company | Method of preparing high cis-1,4 diene polymers having good green strength and tack |
| US4562171A (en) * | 1984-06-04 | 1985-12-31 | The Firestone Tire & Rubber Company | Method of preparing high cis-1,4 diene polymers having good green strength and tack using a catalyst composition containing a carboxylated metal oxy aluminate component |
| US4501866A (en) * | 1984-07-23 | 1985-02-26 | The Firestone Tire & Rubber Company | Continuous method for preparing high cis-1,4 polybutadiene |
| US5733835A (en) * | 1996-08-05 | 1998-03-31 | The Goodyear Tire & Rubber Company | Cobalt containing catalyst system |
| US5955553A (en) * | 1998-08-19 | 1999-09-21 | Bridgestone Corporation | Molecular weight regulation of cis-1,4-polybutadiene using carboxylates |
| KR100348763B1 (ko) | 2000-07-06 | 2002-08-13 | 금호석유화학 주식회사 | 높은 1,4-시스 함량을 갖는 폴리부타디엔의 분지도 조절방법 |
| US6596825B1 (en) | 2002-07-30 | 2003-07-22 | Firestone Polymers, Llc | Low gel high cis polydiene |
| US6727330B1 (en) | 2003-02-07 | 2004-04-27 | Firestone Polymers, Llc | Termination and reduced gel in high cis polybutadiene |
| US7585805B2 (en) * | 2005-11-22 | 2009-09-08 | Bridgestone Corporation | Nickel-based catalyst composition |
| US8372925B2 (en) | 2007-04-10 | 2013-02-12 | Bridgestone Corporation | Nickel-based catalyst composition |
| CN108129590A (zh) | 2010-12-31 | 2018-06-08 | 株式会社普利司通 | 使用基于镍的催化剂系统的共轭二烯本体聚合 |
| WO2012092547A1 (en) | 2010-12-31 | 2012-07-05 | Bridgestone Corporation | Bulk polymerization of conjugated dienes using a nickel-based catalyst system |
| SG194811A1 (en) | 2011-05-09 | 2013-12-30 | Bridgestone Corp | Processes for the preparation of high-cis polydienes |
| US10066035B2 (en) | 2015-12-07 | 2018-09-04 | Bridgestone Corporation | Catalyst systems and methods for preparation of 1,4-polybutadiene rubber |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA662850A (en) * | 1963-05-07 | Polymer Corporation Limited | 1,3-butadiene polymerization with a titanium-aluminum catalyst | |
| US2977349A (en) * | 1956-11-07 | 1961-03-28 | Goodrich Gulf Chem Inc | Process for polymerizing dienes |
| US3219650A (en) * | 1958-09-17 | 1965-11-23 | Gulf Oil Corp | Process for the polymerization of diolefins |
| GB906334A (en) * | 1959-12-31 | 1962-09-19 | Bridgestone Tire Co Ltd | Method of manufacturing cis-1,4-polybutadiene |
| US3170907A (en) * | 1959-12-31 | 1965-02-23 | Bridgestone Tire Co Ltd | Production of cis-1, 4 polybutadiene with a nickel carboxylic acid salt-boron trifluoride etherate-aluminum trialkyl catalyst |
| GB1035796A (en) * | 1964-10-22 | 1966-07-13 | Japan Synthetic Rubber Co Ltd | Method for producing polybutadiene |
| NL132157C (https=) * | 1965-10-27 |
-
1967
- 1967-07-10 US US651991A patent/US3528957A/en not_active Expired - Lifetime
-
1968
- 1968-05-28 GB GB25507/68A patent/GB1209384A/en not_active Expired
- 1968-06-07 DE DE19681770587 patent/DE1770587A1/de active Pending
- 1968-07-04 FR FR1573466D patent/FR1573466A/fr not_active Expired
- 1968-07-04 BE BE717604D patent/BE717604A/xx unknown
- 1968-07-10 NL NL6809757A patent/NL6809757A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE1770587A1 (de) | 1971-11-11 |
| FR1573466A (https=) | 1969-07-04 |
| BE717604A (https=) | 1968-12-16 |
| US3528957A (en) | 1970-09-15 |
| NL6809757A (https=) | 1969-01-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB1209384A (en) | Method of producing polybutadiene | |
| GB1218232A (en) | Process for the preparation of polybutadiene | |
| GB1200537A (en) | Polymerization process | |
| GB1485873A (en) | Process for producing butadiene polymers | |
| GB837251A (en) | Improvements in or relating to olefine polymerisation processes | |
| GB890139A (en) | Process for the polymerisation of conjugated dienes and catalysts therefor | |
| GB1499638A (en) | Continuous insitu catalyst addition for polybutadiene polymerization | |
| GB1202118A (en) | Improvements in polymerization process | |
| GB1245797A (en) | Process for producing hydrogenated hydrocarbon polymers | |
| GB1506834A (en) | Process for producing a solution of essentially linear polydihalophosphazenes | |
| ES8603518A1 (es) | Procedimiento para preparar polibutadieno de alto contenido en cis-1,4 | |
| US3328376A (en) | Process for the production of polybutadiene | |
| GB1446062A (en) | Hydrocarbon polymer | |
| GB1274347A (en) | Process for polymerisation of tetrahydrofuran | |
| GB1231657A (https=) | ||
| GB1146336A (en) | Polymerization process | |
| GB1174614A (en) | Metal Plated Plastics and Process Therefor | |
| GB1270362A (en) | Polymerization of conjugated dienes by means of a binary catalyst system | |
| GB1298150A (en) | Cobalt (iii) complexes and processes for producing the same | |
| GB1254519A (en) | A novel binary catalyst system for the polymerization of diolefins | |
| ES367718A2 (es) | Procedimiento para la polimerizacion y la copolimerizacion de las olefinas. | |
| GB714659A (en) | Improvements in the production of carboxylic acid esters | |
| GB1292867A (en) | Production of cis-1,4-polydienes by means of a ternary catalyst system | |
| GB1343530A (en) | Process for producing polymers | |
| GB1298316A (en) | A method for reducing zearalenone to zearalanol |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |