GB1207759A - Process for the production of a methanol synthesis gas - Google Patents

Process for the production of a methanol synthesis gas

Info

Publication number
GB1207759A
GB1207759A GB60480/68A GB6048068A GB1207759A GB 1207759 A GB1207759 A GB 1207759A GB 60480/68 A GB60480/68 A GB 60480/68A GB 6048068 A GB6048068 A GB 6048068A GB 1207759 A GB1207759 A GB 1207759A
Authority
GB
United Kingdom
Prior art keywords
stage
gas
methanol synthesis
synthesis gas
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB60480/68A
Inventor
Heinz Jockel
Emil Supp
Hagen Krumm
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GEA Group AG
Original Assignee
Metallgesellschaft AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Metallgesellschaft AG filed Critical Metallgesellschaft AG
Publication of GB1207759A publication Critical patent/GB1207759A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

1,207,759. Methanol synthesis gas. METALLGESELLSCHAFT A.G. 19 Dec., 1968 [15 Jan., 1968], No. 60480/68. Heading C5E. Methanol synthesis gas in which the molar proportion (H 2 -CO 2 ) to (CO + CO 2 ) is at least 2À05 to 1, is made in a two-stage catalytic process from a sulphur-free hydrocarbon feed having an average of 2 to 20 carbon atoms in the molecule. The feed is evaporated at between 2 to 20 atmospheres pressure and steam reformed over a Ni-rich catalyst at between 250‹ and 500‹ C. to produce a CH 4 -rich gas containing CO 2 . This gas is cracked at the same pressure in an indirectly heated tube furnace at at least 820‹ C. over a Ni catalyst. The ratio of steam to hydrocarbon in the first stage is in the range 2:1 to 3:1 by weight, and the catalyst in this stage should contain at least 30 wt. per cent Ni, preferably up to 60 wt. per cent, and have a surface area exceeding 80 sq. m. per gram. Feeds may be desulphurized by catalytic hydrogenation by recycling the synthesis gas or decompression gas from the methanol synthesis stage. Feeds mentioned include petrol, light fuel, diesel oil and propane/butane mixtures.
GB60480/68A 1968-01-15 1968-12-19 Process for the production of a methanol synthesis gas Expired GB1207759A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1667631 1968-01-15

Publications (1)

Publication Number Publication Date
GB1207759A true GB1207759A (en) 1970-10-07

Family

ID=5685988

Family Applications (1)

Application Number Title Priority Date Filing Date
GB60480/68A Expired GB1207759A (en) 1968-01-15 1968-12-19 Process for the production of a methanol synthesis gas

Country Status (6)

Country Link
JP (1) JPS4948839B1 (en)
BE (1) BE726873A (en)
FR (1) FR1598573A (en)
GB (1) GB1207759A (en)
NO (1) NO126231B (en)
SE (1) SE345647B (en)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1423823A (en) * 1964-11-20 1966-01-07 Azote Office Nat Ind Catalytic reforming process under high pressure of petroleum hydrocarbons by steam
CH443242A (en) * 1965-03-11 1967-09-15 Basf Ag Process for obtaining a methane-rich cracking gas by catalytic cracking of hydrocarbons with a C number of C2 to C30

Also Published As

Publication number Publication date
FR1598573A (en) 1970-07-06
NO126231B (en) 1973-01-08
JPS4948839B1 (en) 1974-12-24
BE726873A (en) 1969-06-16
SE345647B (en) 1972-06-05

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees