GB1204860A - Manufacture of synthetic fibres - Google Patents
Manufacture of synthetic fibresInfo
- Publication number
- GB1204860A GB1204860A GB3951267A GB3951267A GB1204860A GB 1204860 A GB1204860 A GB 1204860A GB 3951267 A GB3951267 A GB 3951267A GB 3951267 A GB3951267 A GB 3951267A GB 1204860 A GB1204860 A GB 1204860A
- Authority
- GB
- United Kingdom
- Prior art keywords
- filaments
- acrylonitrile
- stream
- weight
- dmf
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/38—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising unsaturated nitriles as the major constituent
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
Abstract
1,204,860. Acrylonitrile copolymer. HUMPHREYS & GLASGOW Ltd. 29 Aug., 1968 [29 Aug., 1967], No. 39512/67. Heading B5B. Soil-resistant filaments of acrylonitrile copolymers are produced by extruding a solution of the polymer in dimethyl formamide (DMF) into a stream of essentially aliphatic hydrocarbons of initial boiling point above 140‹ C., preferably kerosene, and containing not more than 2% by weight of aromatic hydrocarbons, to precipitate the polymer and to form the filaments, the stream being maintained between 100‹ to 150‹ C. Residual DMF is removed from the filaments by washing in hot water until the filaments contain less than 2% by weight of DMF, which are then dried above 100‹ C., tension being applied to the filaments during the washing and drying steps. A final stretching and orientation of the filaments is then carried out above 175‹ C. The filaments can then be relaxed in a chamber with wet steam and allowed to shrink before crimping, followed by steam setting and cutting into fibres. Preferably, the extruded filaments are fed countercurrent to the stream of kerosene and are preferably dried by passage over heated rollers. The acrylonitrile copolymers used are those described in patent Specification 824,225 and include copolymers of acrylonitrile with acrylic and methaorylic acid, esters and amides thereof and comprise at least 85 mol. per cent of acrylonitrile and up to 15% of copolymerizable comonomer. The filaments have a very smooth outer surface, but have numerous internal closed cavities, and preferably contain not more than 6% by weight of hydrocarbons.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3951267A GB1204860A (en) | 1967-08-29 | 1967-08-29 | Manufacture of synthetic fibres |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3951267A GB1204860A (en) | 1967-08-29 | 1967-08-29 | Manufacture of synthetic fibres |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1204860A true GB1204860A (en) | 1970-09-09 |
Family
ID=10409969
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3951267A Expired GB1204860A (en) | 1967-08-29 | 1967-08-29 | Manufacture of synthetic fibres |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1204860A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0375650A2 (en) * | 1988-12-23 | 1990-06-27 | Monsanto Company | An improvement in wet-spinning processes for producing acrylic filaments |
-
1967
- 1967-08-29 GB GB3951267A patent/GB1204860A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0375650A2 (en) * | 1988-12-23 | 1990-06-27 | Monsanto Company | An improvement in wet-spinning processes for producing acrylic filaments |
EP0375650A3 (en) * | 1988-12-23 | 1991-04-17 | Monsanto Company | An improvement in wet-spinning processes for producing acrylic filaments |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PLNP | Patent lapsed through nonpayment of renewal fees |