GB1192252A - Improvements in or relating to Hydrogen Diffusion Apparatus. - Google Patents

Improvements in or relating to Hydrogen Diffusion Apparatus.

Info

Publication number
GB1192252A
GB1192252A GB4837/68A GB483768A GB1192252A GB 1192252 A GB1192252 A GB 1192252A GB 4837/68 A GB4837/68 A GB 4837/68A GB 483768 A GB483768 A GB 483768A GB 1192252 A GB1192252 A GB 1192252A
Authority
GB
United Kingdom
Prior art keywords
palladium
ferrule
tube
alloy
silver
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4837/68A
Inventor
Leonard Roy Rubin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Engelhard Minerals and Chemicals Corp
Original Assignee
Engelhard Minerals and Chemicals Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Engelhard Minerals and Chemicals Corp filed Critical Engelhard Minerals and Chemicals Corp
Publication of GB1192252A publication Critical patent/GB1192252A/en
Expired legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L19/00Joints in which sealing surfaces are pressed together by means of a member, e.g. a swivel nut, screwed on or into one of the joint parts
    • F16L19/06Joints in which sealing surfaces are pressed together by means of a member, e.g. a swivel nut, screwed on or into one of the joint parts in which radial clamping is obtained by wedging action on non-deformed pipe ends
    • F16L19/065Joints in which sealing surfaces are pressed together by means of a member, e.g. a swivel nut, screwed on or into one of the joint parts in which radial clamping is obtained by wedging action on non-deformed pipe ends the wedging action being effected by means of a ring
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L19/00Joints in which sealing surfaces are pressed together by means of a member, e.g. a swivel nut, screwed on or into one of the joint parts
    • F16L19/08Joints in which sealing surfaces are pressed together by means of a member, e.g. a swivel nut, screwed on or into one of the joint parts with metal rings which bite into the wall of the pipe
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
    • C01B3/505Membranes containing palladium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L19/00Joints in which sealing surfaces are pressed together by means of a member, e.g. a swivel nut, screwed on or into one of the joint parts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L19/00Joints in which sealing surfaces are pressed together by means of a member, e.g. a swivel nut, screwed on or into one of the joint parts
    • F16L19/06Joints in which sealing surfaces are pressed together by means of a member, e.g. a swivel nut, screwed on or into one of the joint parts in which radial clamping is obtained by wedging action on non-deformed pipe ends
    • F16L19/061Joints in which sealing surfaces are pressed together by means of a member, e.g. a swivel nut, screwed on or into one of the joint parts in which radial clamping is obtained by wedging action on non-deformed pipe ends a pressure ring being arranged between the clamping ring and the threaded member or the connecting member
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L41/00Branching pipes; Joining pipes to walls
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L41/00Branching pipes; Joining pipes to walls
    • F16L41/02Branch units, e.g. made in one piece, welded, riveted
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L41/00Branching pipes; Joining pipes to walls
    • F16L41/08Joining pipes to walls or pipes, the joined pipe axis being perpendicular to the plane of the wall or to the axis of another pipe

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Gasket Seals (AREA)

Abstract

1,192,252. Separating hydrogen by diffusion. ENGELHARD MINERALS & CHEMICALS CORP. 30 Jan., 1968 [1 Feb., 1967]. No. 4837/ 68. Heading B1L. [Also in Division F2] A palladium or palladium alloy tube 7 extending through a header tube sheet wall 4 of hydrogen diffusion apparatus, is sealingly secured to the wall by a body 1 which has a tube-receiving bore 2 and which is welded to the wall at one end and provided with a frusto-conical end face 6 at the other, a first ferrule 9 having frusto-conical end faces 11 and 12, a second ferrule 13 of harder material than that of the first ferrule and having frusto conical and planar end faces 14 and 18 respectively, a tubular bush 8 within the tube and of harder material than that of the first ferrule, and a nut 15 screwed onto the body 1 causing bearing between the cooperating end faces of the ferrules and the body, between the bore of the first ferrule and the tube, and between the bore of the tube and the bush. In the diffusion apparatus of Fig. 3, a plurality of coiled tubes are each connected to end walls in the manner described above, said endwalls defining an inlet chamber 26 for feed gas, a collecting chamber 22 for diffused hydrogen, and an outlet chamber 28 for the throughput gas. In alternative arrangement (not shown, a single end wall supporting one or more diffusion tubes closed at one end inside chamber 22 may be used. The palladium, alloy used for tube 7 may be a palladium-silver, palladium boron, or a palladium-gold alloy. A suitable palladium-silver alloy comprises 75% Palladium: 25% silver by weight. The first ferrule preferably surface-roughened by oxidation, may be of copper, annealed copper-nickel alloy, silver, and aluminium, the second harder ferrule may be made from stainless steel, coldworked copper-nickel alloy, or carbon steel, and the bush may be of stainless or carbon steel.
GB4837/68A 1967-02-01 1968-01-30 Improvements in or relating to Hydrogen Diffusion Apparatus. Expired GB1192252A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US61314967A 1967-02-01 1967-02-01

Publications (1)

Publication Number Publication Date
GB1192252A true GB1192252A (en) 1970-05-20

Family

ID=24456070

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4837/68A Expired GB1192252A (en) 1967-02-01 1968-01-30 Improvements in or relating to Hydrogen Diffusion Apparatus.

Country Status (10)

Country Link
US (1) US3437357A (en)
AT (1) AT299637B (en)
BE (1) BE710229A (en)
CH (1) CH470624A (en)
DE (1) DE1675287A1 (en)
ES (1) ES349888A1 (en)
FR (1) FR1554128A (en)
GB (1) GB1192252A (en)
NL (1) NL6801432A (en)
SE (1) SE336256B (en)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3791106A (en) * 1970-09-24 1974-02-12 California Inst Of Techn Gas analysis systems and palladium tube separator therefor
US3665680A (en) * 1970-12-18 1972-05-30 Engelhard Min & Chem Hydrogen diffusion apparatus
US3751880A (en) * 1972-02-22 1973-08-14 Universal Monitor Corp Carrier gas separating unit
US3928204A (en) * 1974-06-27 1975-12-23 Frank A Thomas Interconnectors for spiral-wound filtration modules
FR2459534A1 (en) * 1979-06-14 1981-01-09 Commissariat Energie Atomique METHOD AND DEVICE FOR FIXING A GUIDE PIPE OF A NUCLEAR COMBUSTIBLE ASSEMBLY TO THE END PLATES OF SAID ASSEMBLY
US4346923A (en) * 1979-08-23 1982-08-31 Vaponics Inc. Apparatus for joining tubing
US4458927A (en) * 1981-06-19 1984-07-10 The United States Of America As Represented By The United States Department Of Energy Ferrules seals
FR2524955B1 (en) * 1982-04-08 1986-05-30 Legris SEAL BETWEEN AN APPARATUS AND A SCREW CONNECTION FOR HIGH PRESSURE FLUID PIPING
JPS59119304U (en) * 1983-01-29 1984-08-11 株式会社エルマ Dissolved gas deaerator in liquid
US4541537A (en) * 1983-11-21 1985-09-17 City Of Hope National Medical Center Fluid tight seal for container
US4808201A (en) * 1986-09-19 1989-02-28 Perma Pure Products, Inc. Connector construction for fluid drying tube
US4722127A (en) * 1986-12-03 1988-02-02 Pujol Marlon P Method of servicing condensate line of an air conditioner
JPS63185987U (en) * 1987-05-23 1988-11-29
US4776618A (en) * 1987-08-14 1988-10-11 Marathon Oil Company High pressure coupling
JP2898384B2 (en) * 1989-09-27 1999-05-31 臼井国際産業株式会社 Connection structure of branch connector in high-pressure fuel rail
US5172939A (en) * 1989-10-14 1992-12-22 Usui Kokusai Sangyo Kaisha Ltd. Connection structure for branch pipe in high-pressure fuel rail
DE4006839A1 (en) * 1990-03-05 1991-09-12 Rheydt Kabelwerk Ag Sealing equipment for heated cylinder - esp. glass fibre preform tube in furnace to prevent reactive gas entry
JP2529032Y2 (en) * 1990-05-22 1997-03-12 臼井国際産業株式会社 Connection structure of branch pipe in high pressure fuel manifold
JP2915099B2 (en) * 1990-06-30 1999-07-05 臼井国際産業株式会社 Connection structure of branch connector in high pressure fuel manifold
US5253520A (en) * 1990-12-07 1993-10-19 Dxl International, Inc. Flow sensor connector
FR2685218B1 (en) * 1991-12-19 1994-02-11 Institut Francais Petrole HYDROGEN PURIFIER COMPRISING AN ALLOY BASE OF THE SAME COMPOSITION AS THAT OF THE TUBES.
US5340384A (en) * 1993-03-05 1994-08-23 Systec, Inc. Vacuum degassing
JP3402515B2 (en) * 1994-05-23 2003-05-06 日本碍子株式会社 Hydrogen separator, hydrogen separator using the same, and method for producing hydrogen separator
US5934269A (en) * 1998-03-27 1999-08-10 Tru-Flex Metal Hose Corporation Flexible fuel tube assembly for gas-fired appliance and installation method
US6554015B1 (en) 2001-08-07 2003-04-29 The United States Of America As Represented By The United States Department Of Energy Single piece silver/palladium cell for adjusting or measuring a level of hydrogen and methods therefor
JP3933907B2 (en) * 2001-10-23 2007-06-20 日本碍子株式会社 Gas separator fixing structure and gas separator using the same
US20040061333A1 (en) * 2002-09-30 2004-04-01 Chu Henry C. Conduit coupling
US7080859B1 (en) * 2004-08-06 2006-07-25 Arlington Industries, Inc. Rain tight fitting for metal tubing
US7900974B1 (en) * 2007-03-16 2011-03-08 Plattner Wesley M Method and apparatus for connecting air conditioning coolant lines
CN108302263A (en) * 2018-04-04 2018-07-20 南京知行管业有限公司 A kind of New type kitchen range stainless steel connecting tube
WO2022050837A1 (en) * 2020-09-01 2022-03-10 Technische Universiteit Eindhoven Coupling device and combination and assembly thereof with a tube.
WO2024007057A1 (en) * 2022-07-07 2024-01-11 Commonwealth Scientific And Industrial Research Organisation Arrangement for joining and sealing a metallic hydrogen separation membrane to a metallic connector

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2761704A (en) * 1952-01-14 1956-09-04 Watts Electric & Mfg Co Tube coupling adapted to upset pipe end
US2961062A (en) * 1958-10-06 1960-11-22 Atlantic Refining Co Large surface area hydrogen permeation cell
US3103373A (en) * 1961-06-29 1963-09-10 Crawford Fitting Co Controlled phase sequential gripping device
US3215457A (en) * 1962-04-17 1965-11-02 Hoke Mfg Company Inc Pipe coupling
US3251173A (en) * 1962-11-26 1966-05-17 Heraeus Gmbh W C Device for the purification of hydrogen
US3274754A (en) * 1964-01-17 1966-09-27 Engelhard Ind Inc Gas purification apparatus
US3375025A (en) * 1964-07-15 1968-03-26 Yara Engineering Corp Fittings and combinations of conduits therewith making or adapted to make fluid-tight seals therewith

Also Published As

Publication number Publication date
US3437357A (en) 1969-04-08
BE710229A (en) 1968-08-01
DE1675287A1 (en) 1970-12-23
SE336256B (en) 1971-06-28
ES349888A1 (en) 1969-11-01
CH470624A (en) 1969-03-31
FR1554128A (en) 1969-01-17
AT299637B (en) 1972-06-26
NL6801432A (en) 1968-08-02

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PLNP Patent lapsed through nonpayment of renewal fees