GB1163264A - Polyurethane Sealants and their preparation - Google Patents

Polyurethane Sealants and their preparation

Info

Publication number
GB1163264A
GB1163264A GB2411466A GB2411466A GB1163264A GB 1163264 A GB1163264 A GB 1163264A GB 2411466 A GB2411466 A GB 2411466A GB 2411466 A GB2411466 A GB 2411466A GB 1163264 A GB1163264 A GB 1163264A
Authority
GB
United Kingdom
Prior art keywords
prepolymer
polyol
diphenylmethane diisocyanate
polyether
glycerol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2411466A
Inventor
Gordon Lloyd
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Priority to GB2411466A priority Critical patent/GB1163264A/en
Publication of GB1163264A publication Critical patent/GB1163264A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2190/00Compositions for sealing or packing joints

Abstract

1,163,264. Polyurethane prepolymers. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 11 May, 1967 [31 May, 1966], No. 24114/66. Heading C3R. Polyurethane prepolymers are prepared by reacting, at ambient temperature, (suitably a temperature of 0‹ to 35‹ C.), a diphenylmethane diisooyanate with a polyether diol or triol with a M.W. greater than 1000 such that the NCO: OH ratio is not less than 4:1. The prepolymers may be reacted with a polyol to form a sealant. Preferred diisooyanates are 3,3<SP>1</SP> - diphenylmethane diisocyanate; 3,4<SP>1</SP> - diphenylmethane diisocyanate and 4,4<SP>1</SP>- diphenylmethane diisocyanate (which may be the technical grade). Polypropylene glycols or polyether triols based on glycerol are preferred diols and triols. The polyol used to cure the prepolymer may be dipropylene glycol, glycerol, a polyether triol or mixtures thereof. Conventional catalysts may be used in the formation of the prepolymer and/or in the curing reaction. A filler such as china clay or a silica and/or a pigment such as titanium dioxide may be incorporated in the prepolymer or polyol or in both.
GB2411466A 1966-05-31 1966-05-31 Polyurethane Sealants and their preparation Expired GB1163264A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2411466A GB1163264A (en) 1966-05-31 1966-05-31 Polyurethane Sealants and their preparation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2411466A GB1163264A (en) 1966-05-31 1966-05-31 Polyurethane Sealants and their preparation

Publications (1)

Publication Number Publication Date
GB1163264A true GB1163264A (en) 1969-09-04

Family

ID=10206599

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2411466A Expired GB1163264A (en) 1966-05-31 1966-05-31 Polyurethane Sealants and their preparation

Country Status (1)

Country Link
GB (1) GB1163264A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4232608A (en) 1978-12-04 1980-11-11 Aerojet-General Corporation Dimer isocyanate liner compositions
EP0046556A1 (en) * 1980-08-26 1982-03-03 Bayer Ag Diisocyanates or mixtures of diisocyanates of the diphenylmethane class, processes for their preparation, as well as their use as synthesis components in the manufacture of polyurethanes by the isocyanate-polyaddition process
US4328281A (en) 1972-09-25 1982-05-04 Aerojet-General Corporation Dimer isocyanate liner compositions
FR2850973A1 (en) * 2003-02-12 2004-08-13 Weber A Two-part polyurethane product based on a methylene diphenyl diisocyanate prepolymer and a polyol component, useful for earth consolidation and gas sealing in mining operations and public works, has defined properties

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4328281A (en) 1972-09-25 1982-05-04 Aerojet-General Corporation Dimer isocyanate liner compositions
US4232608A (en) 1978-12-04 1980-11-11 Aerojet-General Corporation Dimer isocyanate liner compositions
EP0046556A1 (en) * 1980-08-26 1982-03-03 Bayer Ag Diisocyanates or mixtures of diisocyanates of the diphenylmethane class, processes for their preparation, as well as their use as synthesis components in the manufacture of polyurethanes by the isocyanate-polyaddition process
US4587058A (en) * 1980-08-26 1986-05-06 Bayer Aktiengesellschaft Diisocyanates of the diphenyl methane series and processes for the production thereof
FR2850973A1 (en) * 2003-02-12 2004-08-13 Weber A Two-part polyurethane product based on a methylene diphenyl diisocyanate prepolymer and a polyol component, useful for earth consolidation and gas sealing in mining operations and public works, has defined properties
EP1447418A1 (en) * 2003-02-12 2004-08-18 A. Weber, S.A. Two component product

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Legal Events

Date Code Title Description
CSNS Application of which complete specification have been accepted and published, but patent is not sealed