GB1161906A - Improvements in or relating to Silica-Magnesia Cracking Catalysts Containing Fluorine. - Google Patents

Improvements in or relating to Silica-Magnesia Cracking Catalysts Containing Fluorine.

Info

Publication number
GB1161906A
GB1161906A GB3668566A GB3668566A GB1161906A GB 1161906 A GB1161906 A GB 1161906A GB 3668566 A GB3668566 A GB 3668566A GB 3668566 A GB3668566 A GB 3668566A GB 1161906 A GB1161906 A GB 1161906A
Authority
GB
United Kingdom
Prior art keywords
magnesia
silica
slurry
fluorine
relating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3668566A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WR Grace and Co
Original Assignee
WR Grace and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US479710A external-priority patent/US3404097A/en
Priority claimed from US499046A external-priority patent/US3395103A/en
Application filed by WR Grace and Co filed Critical WR Grace and Co
Publication of GB1161906A publication Critical patent/GB1161906A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/14Silica and magnesia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06Halogens; Compounds thereof
    • B01J27/08Halides
    • B01J27/12Fluorides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

1,161,906. Coating catalyst. W. R. GRACE & CO. 16 Aug., 1966 [16 Aug., 1965; 20 Oct., 1965], No. 36685/66. Heading B1E. (Also in Division CS] A silica-magnesia-fluorine cracking catalyst is prepared by a process comprising gelling a sodium silicate solution to give a silica gel, adding an aqueous slurry of magnesia to the gel, adding a water-soluble fluorine-containing compound to the silica-magnesia slurry, ageing the resulting composite for at least one hour at a temperature in the range 160 to 180‹F., and washing and drying the aged composite. The final product may contain from 17% to 48% magnesia and 0.5% to 5% fluorine. The silica gel may be adjusted to pH 2.0 to 8.0 and aged before adding the magnesia slurry. Strong mineral acid may be added to the magnesia slurry or to the silica magnesia slurry. The silica magnesia slurry may be aged before addition of the fluorine compound. The ageing of the silica magnesia fluoride slurry is .preferably carried out on the unwashed spray dried product.
GB3668566A 1965-08-16 1966-08-16 Improvements in or relating to Silica-Magnesia Cracking Catalysts Containing Fluorine. Expired GB1161906A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US479710A US3404097A (en) 1965-08-16 1965-08-16 Method for preparing silica-magnesiafluoride catalyst
US499046A US3395103A (en) 1965-10-20 1965-10-20 Process for making silica-magnesia-magnesium fluoride cracking catalysts

Publications (1)

Publication Number Publication Date
GB1161906A true GB1161906A (en) 1969-08-20

Family

ID=27046331

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3668566A Expired GB1161906A (en) 1965-08-16 1966-08-16 Improvements in or relating to Silica-Magnesia Cracking Catalysts Containing Fluorine.

Country Status (3)

Country Link
FR (1) FR1514979A (en)
GB (1) GB1161906A (en)
NL (1) NL6611491A (en)

Also Published As

Publication number Publication date
NL6611491A (en) 1967-02-17
FR1514979A (en) 1968-03-01
DE1542184B2 (en) 1976-04-01
DE1542184A1 (en) 1970-10-01

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Legal Events

Date Code Title Description
PS Patent sealed
PE Patent expired