GB1160446A - Improvements relating to Cellulosic Textiles - Google Patents

Improvements relating to Cellulosic Textiles

Info

Publication number
GB1160446A
GB1160446A GB3903366A GB3903366A GB1160446A GB 1160446 A GB1160446 A GB 1160446A GB 3903366 A GB3903366 A GB 3903366A GB 3903366 A GB3903366 A GB 3903366A GB 1160446 A GB1160446 A GB 1160446A
Authority
GB
United Kingdom
Prior art keywords
cellulose
compound
impregnated
linkage
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3903366A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Deering Milliken Research Corp
Milliken Research Corp
Original Assignee
Deering Milliken Research Corp
Milliken Research Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Deering Milliken Research Corp, Milliken Research Corp filed Critical Deering Milliken Research Corp
Publication of GB1160446A publication Critical patent/GB1160446A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12—Aldehydes; Ketones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/08—Organic compounds
    • D06M10/10—Macromolecular compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/41—Amides derived from unsaturated carboxylic acids, e.g. acrylamide
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
    • D06M14/20—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
    • D06M14/20—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin
    • D06M14/22—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
    • D06M14/20—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin
    • D06M14/24—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin of animal origin, e.g. wool or silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Zoology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1,160,446. Grafting cellulosic material. DEERING MILLIKEN RESEARCH CORP. 1 Sept., 1966 [17 Sept., 1965], No. 39033/66. Heading C3G. Cellulosic material having a permanent configuration is produced by a process comprising subjecting to the influence of irradiation a cellulosic material impregnated with a compound containing at least one primary group capable of polymerizing under the influence of irradiation and at least one secondary group capable of reacting to join the compound to cellulose through a linkage other than a carboncarbon linkage, and thereby polymerizing the compound and linking it to cellulose through a carbon-carbon linkage, arranging the cellulosic material in a desired configuration and causing the secondary group or groups to react to link the compound to cellulose through a linkage other than a carbon-carbon linkage while the material is in the desired configuration. The secondary group may be a group which reacts with a hydroxyl group of cellulose or one which is reacted with an aldehyde to form a methylol group, which reacts with a hydroxyl group of cellulose. A second compound, e.g. hydroxyalkyl cellulose or carboxylated alkyl cellulose may be incorporated during or after treatment with the first compound, for reaction with other secondary groups present in said first compound. The cellulosic material, which may be fibres, yarns, threads or fabric of any form of cellulose, including regenerated cellulose, alone or together with synthetic material such as polyester, polyamide, acrylic fibres, polyethylene or polypropylene or with keratin fibres, is subjected to irradiation prior to or after impregnation with the compound. A catalyst for reaction of the secondary groups, e.g. MgCl 2 or Zn(NO 3 ) 2 may be applied together with the compound, as may be a conventional textile cross-linking agent, e.g. an amino resin, an acrolein-urea-formaldehyde resin, a cyclic ethylene urea-formaldehyde resin or triazone resin. In the examples, fabric selected from dyed and undyed polyethylene terephthalatecotton poplin, cotton twill and cotton broadcloth is impregnated with an aqueous solution of N - methylolacrylamide, N,N - dimethylolacrylamide, N - methylol allyl carbamate or the reaction product of acrylamide, formaldehyde and ethyl triazone (2: 4: 1 molar ratio) prior to being irradiated and pressed. In Example VIII, polyethylene terephthalatecotton poplin fabric is impregnated with an aqueous solution of acrylamide, irradiated, immersed in aqueous formaldehyde, treated with MgCl 2 solution and pressed. Cotton broadcloth is impregnated in Example XIV with an aqueous solution of N-methylolacrylamide, irradiated, impregnated with an aqueous solution of sodium carboxymethyl cellulose and Zn(NO 3 ) 2 , dried and cured; alternatively the said cellulose derivative is applied together with the N-methylolacrylamide. In Example VI, polyethylene terephthalate-cotton poplin fabric is irradiated, impregnated with an aqueous N - methylolacrylamide solution containing MgCl 2 , and heated prior to pressing. The material treated in Example I is formed into stacks before being pressed.
GB3903366A 1965-09-17 1966-09-01 Improvements relating to Cellulosic Textiles Expired GB1160446A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US48826265A 1965-09-17 1965-09-17

Publications (1)

Publication Number Publication Date
GB1160446A true GB1160446A (en) 1969-08-06

Family

ID=23939004

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3903366A Expired GB1160446A (en) 1965-09-17 1966-09-01 Improvements relating to Cellulosic Textiles

Country Status (10)

Country Link
AT (1) AT284780B (en)
BE (1) BE686982A (en)
CH (1) CH475409A (en)
DE (1) DE1594997A1 (en)
DK (1) DK118282B (en)
ES (1) ES331290A1 (en)
GB (1) GB1160446A (en)
IL (1) IL26427A (en)
LU (1) LU51981A1 (en)
NL (1) NL6613125A (en)

Also Published As

Publication number Publication date
BE686982A (en) 1967-03-16
DE1594997A1 (en) 1970-09-03
NL6613125A (en) 1967-03-20
CH1330866A4 (en) 1969-02-28
AT284780B (en) 1970-09-25
IL26427A (en) 1971-01-28
CH475409A (en) 1969-08-29
DK118282B (en) 1970-08-03
LU51981A1 (en) 1966-11-16
ES331290A1 (en) 1967-11-01

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees