GB1153115A - Process for the Hydrodimerisation of Acrylic Acid Derivatives - Google Patents
Process for the Hydrodimerisation of Acrylic Acid DerivativesInfo
- Publication number
- GB1153115A GB1153115A GB5659/68A GB565968A GB1153115A GB 1153115 A GB1153115 A GB 1153115A GB 5659/68 A GB5659/68 A GB 5659/68A GB 565968 A GB565968 A GB 565968A GB 1153115 A GB1153115 A GB 1153115A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acrylic acid
- acid derivatives
- reaction
- alkyl
- hydrodimerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/02—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms of an acyclic and saturated carbon skeleton
- C07C255/03—Mononitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/02—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms of an acyclic and saturated carbon skeleton
- C07C255/04—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms of an acyclic and saturated carbon skeleton containing two cyano groups bound to the carbon skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,153,115. Hydrodimerization of acrylic acid derivatives. UCB (UNION CHIMIQUECHEMISCHE BEDRIJVEN) S.A. 5 Feb., 1968 [8 Feb., 1967], No. 5659/68. Heading C2C. A process for the hydrodimerization of acrylic acid derivatives selected from acrylonitrile, C 1 to C 4 alkyl acrylonitriles and C 1 to C 4 alkyl esters and amides of acrylic acid by reaction with an alkali metal amalgam, which comprises carrying out the reaction in a non-polar, at least partly water-miscible solvent medium containing a free quaternary ammonium base preferably of the formula in which R 1 , R 2 , R 3 and R 4 , which may be the same or different, are alkyl, cycloalkyl, aryl or aralkyl radicals; and water, the process being performed, without pH control at the degree of alkalinity generated by the reaction, preferably at a temperature between -10 and +30 C. Suitable solvents mentioned are ethers, e.g. tetrahydrofuran, dioxan, dimethoxyethane and diglyme (diethyleneglycol dimethyl ether).
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IL27411A IL27411A (en) | 1967-02-08 | 1967-02-08 | Process for the hydrodimerization of acrylic acid derivatives |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1153115A true GB1153115A (en) | 1969-05-21 |
Family
ID=11044113
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5659/68A Expired GB1153115A (en) | 1967-02-08 | 1968-02-05 | Process for the Hydrodimerisation of Acrylic Acid Derivatives |
Country Status (14)
Country | Link |
---|---|
US (1) | US3686269A (en) |
AT (1) | AT274772B (en) |
BE (1) | BE710363A (en) |
CH (1) | CH484027A (en) |
CS (1) | CS149415B2 (en) |
DE (1) | DE1668807A1 (en) |
ES (1) | ES350125A1 (en) |
FR (1) | FR1553196A (en) |
GB (1) | GB1153115A (en) |
IL (1) | IL27411A (en) |
LU (1) | LU55420A1 (en) |
NL (1) | NL6801473A (en) |
NO (1) | NO126132B (en) |
SE (1) | SE351843B (en) |
-
1967
- 1967-02-08 IL IL27411A patent/IL27411A/en unknown
-
1968
- 1968-01-08 FR FR1553196D patent/FR1553196A/fr not_active Expired
- 1968-02-01 NL NL6801473A patent/NL6801473A/xx unknown
- 1968-02-03 ES ES350125A patent/ES350125A1/en not_active Expired
- 1968-02-05 GB GB5659/68A patent/GB1153115A/en not_active Expired
- 1968-02-05 SE SE01496/68A patent/SE351843B/xx unknown
- 1968-02-06 BE BE710363D patent/BE710363A/xx unknown
- 1968-02-06 DE DE19681668807 patent/DE1668807A1/en active Pending
- 1968-02-06 LU LU55420D patent/LU55420A1/xx unknown
- 1968-02-06 CH CH181368A patent/CH484027A/en not_active IP Right Cessation
- 1968-02-07 AT AT115568A patent/AT274772B/en active
- 1968-02-07 NO NO0471/68A patent/NO126132B/no unknown
- 1968-02-07 CS CS938A patent/CS149415B2/cs unknown
-
1970
- 1970-08-27 US US67605A patent/US3686269A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
SE351843B (en) | 1972-12-11 |
US3686269A (en) | 1972-08-22 |
DE1668807A1 (en) | 1971-01-28 |
LU55420A1 (en) | 1968-10-09 |
NO126132B (en) | 1972-12-27 |
NL6801473A (en) | 1968-08-09 |
AT274772B (en) | 1969-09-25 |
IL27411A (en) | 1970-06-17 |
FR1553196A (en) | 1969-01-10 |
CS149415B2 (en) | 1973-07-05 |
ES350125A1 (en) | 1969-05-01 |
BE710363A (en) | 1968-08-06 |
CH484027A (en) | 1970-01-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PLNP | Patent lapsed through nonpayment of renewal fees |