GB1141777A - Separation of cobalt and nickel by liquid-liquid extraction from acid solutions - Google Patents
Separation of cobalt and nickel by liquid-liquid extraction from acid solutionsInfo
- Publication number
- GB1141777A GB1141777A GB27243/66A GB2724366A GB1141777A GB 1141777 A GB1141777 A GB 1141777A GB 27243/66 A GB27243/66 A GB 27243/66A GB 2724366 A GB2724366 A GB 2724366A GB 1141777 A GB1141777 A GB 1141777A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- cobalt
- phosphoric acid
- nickel
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title abstract 10
- 239000002253 acid Substances 0.000 title abstract 5
- 229910052759 nickel Inorganic materials 0.000 title abstract 5
- 229910017052 cobalt Inorganic materials 0.000 title abstract 3
- 239000010941 cobalt Substances 0.000 title abstract 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title abstract 3
- 238000000926 separation method Methods 0.000 title abstract 2
- 238000000622 liquid--liquid extraction Methods 0.000 title 1
- 238000000638 solvent extraction Methods 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 abstract 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 abstract 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 abstract 2
- PLLBRTOLHQQAQQ-UHFFFAOYSA-N 8-methylnonan-1-ol Chemical compound CC(C)CCCCCCCO PLLBRTOLHQQAQQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 239000008346 aqueous phase Substances 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- KIFWZXNWWYGPMG-UHFFFAOYSA-N bis(2-ethyl-4-methylpentyl) hydrogen phosphate Chemical compound CC(C)CC(CC)COP(O)(=O)OCC(CC)CC(C)C KIFWZXNWWYGPMG-UHFFFAOYSA-N 0.000 abstract 1
- OFTUVGHKQMUAJA-UHFFFAOYSA-N bis(4-methyl-2-propylpentyl) hydrogen phosphate Chemical compound CCCC(CC(C)C)COP(O)(=O)OCC(CCC)CC(C)C OFTUVGHKQMUAJA-UHFFFAOYSA-N 0.000 abstract 1
- 150000001868 cobalt Chemical class 0.000 abstract 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000002425 crystallisation Methods 0.000 abstract 1
- 230000008025 crystallization Effects 0.000 abstract 1
- SEGLCEQVOFDUPX-UHFFFAOYSA-N di-(2-ethylhexyl)phosphoric acid Chemical compound CCCCC(CC)COP(O)(=O)OCC(CC)CCCC SEGLCEQVOFDUPX-UHFFFAOYSA-N 0.000 abstract 1
- DXQYKFGICLVQFD-UHFFFAOYSA-N dioctan-2-yl hydrogen phosphate Chemical compound CCCCCCC(C)OP(O)(=O)OC(C)CCCCCC DXQYKFGICLVQFD-UHFFFAOYSA-N 0.000 abstract 1
- TVACALAUIQMRDF-UHFFFAOYSA-N dodecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCOP(O)(O)=O TVACALAUIQMRDF-UHFFFAOYSA-N 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- CYZASAMUYFRGTI-UHFFFAOYSA-N heptadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCCOP(O)(O)=O CYZASAMUYFRGTI-UHFFFAOYSA-N 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- -1 isooctyl Chemical group 0.000 abstract 1
- 239000003350 kerosene Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000005065 mining Methods 0.000 abstract 1
- 229910017604 nitric acid Inorganic materials 0.000 abstract 1
- 239000012074 organic phase Substances 0.000 abstract 1
- 238000010979 pH adjustment Methods 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
- 238000007670 refining Methods 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G51/00—Compounds of cobalt
- C01G51/10—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3846—Phosphoric acid, e.g. (O)P(OH)3
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/387—Cyclic or polycyclic compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US465789A US3399055A (en) | 1965-06-21 | 1965-06-21 | Separation of cobalt by liquid extraction from acid solutions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1141777A true GB1141777A (en) | 1969-01-29 |
Family
ID=23849155
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB27243/66A Expired GB1141777A (en) | 1965-06-21 | 1966-06-17 | Separation of cobalt and nickel by liquid-liquid extraction from acid solutions |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3399055A (enExample) |
| BE (1) | BE682884A (enExample) |
| DE (1) | DE1592264B2 (enExample) |
| GB (1) | GB1141777A (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10577255B2 (en) * | 2016-09-05 | 2020-03-03 | Sumitomo Metal Mining Co., Ltd. | Method for producing solutions containing nickel or cobalt |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA902932A (en) * | 1970-02-03 | 1972-06-20 | Her Majesty The Queen, In Right Of Canada As Represented By The Minister Of Natural Resources Canada | Liquid-liquid separation of cobalt from ammoniacal solutions |
| US3794719A (en) * | 1972-02-25 | 1974-02-26 | Sec Corp | Reduction of nickel contamination by zinc in {60 -hydroxy oxime extract |
| FR2208983B2 (enExample) * | 1972-12-01 | 1978-06-02 | Nickel Le | |
| FR2208984B2 (enExample) * | 1972-12-01 | 1981-04-10 | Nickel Le | |
| FI51110C (fi) * | 1973-05-22 | 1976-10-11 | Outokumpu Oy | Tapa erottaa kobolttia(II) ja nikkeliä(II) neste-nesteuuttauksella |
| GB1499406A (en) * | 1975-04-24 | 1978-02-01 | Inco Europ Ltd | Separation of cobalt and nickel |
| US4088733A (en) * | 1976-02-23 | 1978-05-09 | Metallurgie Hoboken-Overpelt | Process for liquid-liquid extraction of cobalt from nickel |
| FR2342346A1 (fr) * | 1976-02-27 | 1977-09-23 | Metallurgie Hoboken | Procede d'extraction liquide-liquide du cobalt |
| US4042665A (en) * | 1976-09-27 | 1977-08-16 | Falconbridge Nickel Mines Limited | Cobalt ion exchange process |
| US4193969A (en) * | 1976-11-12 | 1980-03-18 | Amax Inc. | Selective nickel and cobalt extraction from aqueous acidic solutions |
| GB1598561A (en) * | 1977-01-11 | 1981-09-23 | Matthey Rustenberg Refiners Pt | Solvent extraction |
| US4246240A (en) * | 1978-07-24 | 1981-01-20 | Nippon Mining Co., Ltd. | Process for separating cobalt and nickel from a solution containing cobalt and nickel |
| AU516800B2 (en) * | 1978-11-09 | 1981-06-25 | Nippon Mining Company Limited | Separation and recovery of cobalt by stripping |
| FR2462481A1 (fr) * | 1979-07-30 | 1981-02-13 | British Petroleum Co | Procede d'extraction liquide-liquide de metaux en solution aqueuse au moyen de derives organophosphores |
| US4423012A (en) * | 1981-12-31 | 1983-12-27 | Hazen Research Incorporated | Manganese and zinc solvent extraction process |
| US4600435A (en) * | 1984-08-24 | 1986-07-15 | Amax Inc. | Solvent extraction of cobalt (II) from sulfate solutions with cobalt extractants |
| US4861565A (en) * | 1987-01-27 | 1989-08-29 | The Hall Chemical Company | Method of separately recovering metal values of petroleum refining catalyst |
| US5399322A (en) * | 1992-10-15 | 1995-03-21 | Hazen Research, Inc. | Selective recovery of dissolved metals and preparation of metal salt products |
| CN112650176B (zh) * | 2020-12-22 | 2022-08-30 | 天能化工有限公司 | 一种盐酸解析开停车工序的dcs控制方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA718834A (en) * | 1965-09-28 | E. Williams Robert | Separation of cobalt from nickel | |
| CA710712A (en) * | 1961-06-29 | 1965-06-01 | H. B. George James | Removal of metal contaminants from nickel-containing process solutions |
| NL124965C (enExample) * | 1962-03-19 | 1900-01-01 |
-
1965
- 1965-06-21 US US465789A patent/US3399055A/en not_active Expired - Lifetime
-
1966
- 1966-06-16 DE DE1966E0031888 patent/DE1592264B2/de active Granted
- 1966-06-17 GB GB27243/66A patent/GB1141777A/en not_active Expired
- 1966-06-21 BE BE682884D patent/BE682884A/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10577255B2 (en) * | 2016-09-05 | 2020-03-03 | Sumitomo Metal Mining Co., Ltd. | Method for producing solutions containing nickel or cobalt |
Also Published As
| Publication number | Publication date |
|---|---|
| US3399055A (en) | 1968-08-27 |
| DE1592264A1 (de) | 1970-12-03 |
| BE682884A (enExample) | 1966-12-01 |
| DE1592264B2 (de) | 1976-09-23 |
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