US3794719A - Reduction of nickel contamination by zinc in {60 -hydroxy oxime extract - Google Patents
Reduction of nickel contamination by zinc in {60 -hydroxy oxime extract Download PDFInfo
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- US3794719A US3794719A US00229328A US3794719DA US3794719A US 3794719 A US3794719 A US 3794719A US 00229328 A US00229328 A US 00229328A US 3794719D A US3794719D A US 3794719DA US 3794719 A US3794719 A US 3794719A
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- nickel
- zinc
- extractant
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- hydroxy oxime
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/30—Oximes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0446—Juxtaposition of mixers-settlers
- B01D11/0457—Juxtaposition of mixers-settlers comprising rotating mechanisms, e.g. mixers, mixing pumps
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- nickel values can be extracted from aqueous solutions utilizing as extractants certain a-hydroxy .oximes.
- US. Pat. No. 3,276,863 which issued Oct. 4, 1966 to Drobnick et al. relates to a process for the separation of nickel values from aqueous solutions using a water-immiscible organic phase containing certain oz-hydroxy oximes.
- This patent also discloses that the nickel values can be stripped from the loaded organic phase by employing an aqueous solution of a strong acid, with the nickel values then being recoverable from the aqueous stripping solution by electrowinning (electrolysis).
- feed solutions contain, in addition to nickel, zinc which is also extracted by the a-hydroxy oximes. Zinc is difficult to separate from nickel by chemical means and when present in appreciable amounts seriously interferes with electrowinning of nickel. The electrolytic separation of zinc from nickel is also extremely hard to achieve.
- lt is the principal object of this invention to effec-' tively reduce contamination of nickel by zinc when nickel is extracted with a-hydroxy oxime extractants.
- an a-hydroxy oxime containing both nickel and zinc values is contacted with a source of nickel ions to saturate substantially or overload the oxime with nickel and to displace zinc therefrom.
- the a-hydroxy oxime material after being saturated or overloaded with nickel ions, is washed with a weakly acidic solution to remove additional amounts of zinc.
- R, R and R may be an organic hydrocarbon radical, such as aliphatic and alkaryl radicals.
- R" may also be hydrogen.
- the preferred extractants are those wherein R and R are the same and are unsaturated hydrocarbon or branched chain alkyl groups of from six to carbon atoms, and R is hydrogen or is similar to R or R.
- the feed solution can be a solution obtained from leaching an ore which contains both nickel and zinc.
- Nickel is preferably extracted from aqueous solutions by the a-hydroxy. oximes under alkaline conditions.
- the nickel-containing feed solution is either basic or made alkaline by addition of a base, such as ammonia, prior to extraction with the a-hydroxy oximes. Since nickel will precipitate as nickel hydroxide at pHs above about 6.5, and inasmuch as the preferred pHs for extraction are 8 or above, a complexing agent is utilized to hold the nickel in solution.
- the preferred complexing agent is ammonia which acts both as a base for pH adjustment and as a complexing agent for nickel.
- the a-hydroxy oxime extractants are employed preferably in the form of a solution in an organic solvent of aliphatic or aromatic hydrocarbons such as kerosene, benzene, toluene, Napoleum 470 and the like.
- the amount of the a-hydroxy oxime extractant dissolved in the organic solvent can vary widely and is generally about 2 to 30 percent by volume.
- the extraction is carried out at normal ambient temperatures and at an alkaline pH, preferably above 8.
- the quantity of a-hydroxy oxime extractant to employ for the extraction depends upon the concentration of nickel in the feed solution and sufficient of the extractant is employed to achieve desired extraction of nickel.
- the a-hydroxy oxime extractant which is loaded or partially loaded with nickel and zinc is then contacted with a source of nickel ions to displace the zinc from the extractant.
- This source of nickel ions contains nickel in excess of the remaining extracting capacity of the extractant, or an overload in the terminology of this description. It is an important feature of this invention that the excess can be recycled and need not be lost to the raffinate.
- the so contacted a-hydroxy oxime extractant can then be stripped using suitable stripping agents such as aqueous solutions of inorganic acids, e. g.
- the whydroxy oxime extractant prior to the stripping opera tion, can be washed with a slightly acidic solution so as to remove the zinc contaminant in addition to that removed previously by the overloading" treatment.
- the stripping solution can then be subjected to known procedures, such as crystallization or electrowinning procedures, to recover substantially pure nickel.
- an aqueous solution containing nickel and zinc which, for example, can be an aqueous solution resulting from the leaching of an ore, flows through line 1 into the primary extractor 3 which may comprise any suitable tank equipped with agitating and mixing means so as to obtain intimate contact between the feed solution and the a-hydroxy oxime extractant.
- the extractor 3 can suitably be conventional mixer-settler equipment provided with an appropriate weir arrangement to accomplish separation of an aqueous phase and an organic phase.
- the feed solution Prior to introduction into extractor 3 the feed solution can be made basic, preferably with ammonia, if it is not already so.
- the a-hydroxy oxime extractant preferably in an organic solvent, is introduced into extractor 3 via line 2.
- the feed solution (line 1) and the a-hydroxy oxime extractant (line 2) are delivered'to extractor 3 at such rates to provide sufficient extracting capacity for the amount of nickel and zinc metal values present in feed solution 1.
- the amount of extractant to be supplied through line 2 can be readily and routinely determined.
- the mixed aqueous and organic phases are permitted to separate by virtue of their immiscibility in the settler area 38 and are withdrawn on opposite sides of weir 4.
- the aqueous phase or raffinate., relatively barren of nickel value, is withdrawn through line 5 and can be processed for recovery of ammonia or recycled to the ore leaching operation, for example.
- the metalscontaining organic phase is sent via line 6 to overloading tank 7 which-conveniently can be a mixer-settler tank where it is contacted with a nickel-bearing liquid stream which is introduced through line 8.
- the nickelbearing stream which is introduced through line 8 may, if desired, be from the same source as the original feed solution.
- Stream 8 is fed to mixer-settler 7 at a rate to provide nickel ions in excess of the remaining extraction capacity of the a-hydroxy oxime in tank 7.
- the aqueous phase is withdrawn through line 9 and sent to storage tank 10.
- the minimum excess of nickel ions leaving overload stage 7 is preferably in the range of 2-3 grams/liter but can vary widely above and below this range depending on the system and degree of effectiveness desired in the overloading process.
- the organic extractant phase now substantially saturated or overloaded with nickel, leaves mixer-settler 7 via line 11 and can be sent directly to stripper 14.
- this organic phase can be directed through line 11a into washer 13.
- a slightly acidic aqueous wash solution containing, for example, sufficient electrolytes (ammonium sulfate, sodium chloride, etc.) to cause adequate phase separation, is introduced into washer 13 via line 12 and is removed'therefrom via line 16, and optionally may be directed back to extraction stage 3.
- the pH of the wash solution can vary widely, but preferably is in the range of pH 3.5 to 5.5. Washed organic is sent via line to stripper 14.
- the organic extractant phase is con tacted with an aqueous nickel stripping solution.
- stripping agents can be used, although it is preferred to use aqueous solutions of inorganic acids and salts such as the electrolyte employed in a subsequent electro-winning operation.
- the stripping agent is introduced into stripper 14 via line 17.
- the stripping agent comprises a spent electrolyte from an electrowinning operation or a mother liquor from a subsequent crystallization recovery procedure it can, if necessary, be fortified with acid prior to introduction into stripper 14.
- the volume phase ratio of the aqueous stripping solution to the organic phase can be varied over wide limits which are well known to those skilled in the art.
- ous stripping solution loaded with nickel is sent via line 18 to nickel recovery at 19.
- Nickel can be recovered at 19 by conventional procedures such as crystallization or electrowinning.
- the stripped organic phase from stripper 14 is recycled via line 2 to the primary extractorstage 3 for reuse as extractant.
- the a-hydroxy oxime extractant becomes partially loaded with nickel and some zinc for which it has lesser affinity'in extractor stage 3.
- stage 7 it is exposed to nickel ions which displace zinc ions from the extractant.
- the nickel ion concentration in storage tank 10 becomes depleted or reduced to a low level through continuous recycling through overload" stage 7 it can be fed to the extraction stage 3 as feed for removal of nickel values therefrom while tank 10 is replenished with a source of nickel.
- the overload mkeribn' source from tank 10 may, if desired, be the same as feed stream 1 and can contain the same impurities.
- the process of this invention is not limited by the particular type of equipment employed.
- mixer-settler units have been referred to in the above description, pulsed columns, centrifugal contactors and similar equipment known to those skilled in the art can be used.
- the number of contacting stages for the steps of extraction, overloading, washing and stripping of nickel ions can be varied to accomplish the desired operations, and one or more stages may be necessary, depending upon the zinc content of the feed solution.
- Extract-ant (line 15) 0.00013 3.15 Raffinate (line 5) 0.033 0010 00K) Feed (line l) & Overload Sol'n (line 8) 0.033 5.0 5.0 Wt. /r Zn in Ni 0.00l7 0.0285
- a process which comprises contacting an aqueous stream containing nickel and zinc with' an a-hydroxy oxime to extract nickel and zinc from said stream, then contacting said extractant containing both nickel and zinc with an aqueous solution containing an excess of nickel ions to displace zinc therefrom, and then stripping nickel from said extractant.
Abstract
The amount of zinc coextracted with nickel by Alpha -hydroxy oxime extractants is reduced by contacting said extractants with an excess of nickel ions to selectively displace zinc.
Description
United States Patent Lowenhaupt, III et al.
[ Feb. 26, I974 REDUCTION OF NICKEL CONTAMINATION BY ZINC IN a-HYDROXY OXIME EXTRACT Inventors:
Assignee:
Filed:
App]. No]:
Edward Harris Lowenhaupt, III; Edward Edmunds, Jr.; Richard Dean Eliasen, all of El Paso, Tex.
S.E.C. Corporation, El Paso, Tex. Feb. 25, 1972 References Cited UNITED STATES PATENTS Drobnick 75/119 3,399,055 8/1968 Ritcey 423/139 3,088,799 5/1963 Fetscher 23/312 R 3,682,589 8/1972 Moore 23/312 R 3,479,378 11/1969 Orlandine 75/119 Primary ExaminerNorman Yudkoff Assistant ExaminerS. J. Emery Attorney, Agent, or Firm-Neuman, Williams, Anderson & Olson 5 7 ABSTRACT The amount of zinc coextracted with nickel by a-hydroxy oxime extractants is reduced by contacting said extractants with an excess of nickel ions to selectively displace zinc.
3 Claims, 1 Drawing Figure 1 REDUCTION OF NICKEL CONTAMINATION BY ZINC IN a-HYDROXY OXIME EXTRACT The present invention relates to a process for the separation of nickel values from aqueous solutions containing both nickel and zinc values.
It is known that nickel values can be extracted from aqueous solutions utilizing as extractants certain a-hydroxy .oximes. Thus, for example, US. Pat. No. 3,276,863 which issued Oct. 4, 1966 to Drobnick et al. relates to a process for the separation of nickel values from aqueous solutions using a water-immiscible organic phase containing certain oz-hydroxy oximes. This patent also discloses that the nickel values can be stripped from the loaded organic phase by employing an aqueous solution of a strong acid, with the nickel values then being recoverable from the aqueous stripping solution by electrowinning (electrolysis). In practice, quite often feed solutions contain, in addition to nickel, zinc which is also extracted by the a-hydroxy oximes. Zinc is difficult to separate from nickel by chemical means and when present in appreciable amounts seriously interferes with electrowinning of nickel. The electrolytic separation of zinc from nickel is also extremely hard to achieve.
lt is the principal object of this invention to effec-' tively reduce contamination of nickel by zinc when nickel is extracted with a-hydroxy oxime extractants.
In accordance with a basic embodiment of this invention, an a-hydroxy oxime containing both nickel and zinc values is contacted with a source of nickel ions to saturate substantially or overload the oxime with nickel and to displace zinc therefrom.
According to a further optional embodiment of the invention, the a-hydroxy oxime material, after being saturated or overloaded with nickel ions, is washed with a weakly acidic solution to remove additional amounts of zinc.
The a-hydroxy oximes with which this invention is concerned and their preparation are described in US. Pat. No. 3,224,873 to Ronald R. Swanson which issued Dec. 21, 1965. As described therein, the a-hydroxy oxime extractants have the following general formula:
where R, R and R may be an organic hydrocarbon radical, such as aliphatic and alkaryl radicals. R" may also be hydrogen. The preferred extractants are those wherein R and R are the same and are unsaturated hydrocarbon or branched chain alkyl groups of from six to carbon atoms, and R is hydrogen or is similar to R or R.
The present invention finds application in reducing zinc contamination, of a-hydr'oxy oximes which are used to extract nickel from aqueous solutions containing both metal values. Thus, the feed solution can be a solution obtained from leaching an ore which contains both nickel and zinc. Nickel is preferably extracted from aqueous solutions by the a-hydroxy. oximes under alkaline conditions. Accordingly, the nickel-containing feed solution is either basic or made alkaline by addition of a base, such as ammonia, prior to extraction with the a-hydroxy oximes. Since nickel will precipitate as nickel hydroxide at pHs above about 6.5, and inasmuch as the preferred pHs for extraction are 8 or above, a complexing agent is utilized to hold the nickel in solution. The preferred complexing agent is ammonia which acts both as a base for pH adjustment and as a complexing agent for nickel. The a-hydroxy oxime extractants are employed preferably in the form of a solution in an organic solvent of aliphatic or aromatic hydrocarbons such as kerosene, benzene, toluene, Napoleum 470 and the like. The amount of the a-hydroxy oxime extractant dissolved in the organic solvent can vary widely and is generally about 2 to 30 percent by volume. The extraction is carried out at normal ambient temperatures and at an alkaline pH, preferably above 8. The quantity of a-hydroxy oxime extractant to employ for the extraction depends upon the concentration of nickel in the feed solution and sufficient of the extractant is employed to achieve desired extraction of nickel.
The a-hydroxy oxime extractant which is loaded or partially loaded with nickel and zinc is then contacted with a source of nickel ions to displace the zinc from the extractant. This source of nickel ions contains nickel in excess of the remaining extracting capacity of the extractant, or an overload in the terminology of this description. It is an important feature of this invention that the excess can be recycled and need not be lost to the raffinate. The so contacted a-hydroxy oxime extractant can then be stripped using suitable stripping agents such as aqueous solutions of inorganic acids, e. g.
sulfuric, nitric or hydrochloric. If desired, the whydroxy oxime extractant, prior to the stripping opera tion, can be washed with a slightly acidic solution so as to remove the zinc contaminant in addition to that removed previously by the overloading" treatment. The stripping solution can then be subjected to known procedures, such as crystallization or electrowinning procedures, to recover substantially pure nickel.
The present invention will now be described in further detail in conjunction with the drawing which is a schematic flow diagram. Thus, an aqueous solution containing nickel and zinc which, for example, can be an aqueous solution resulting from the leaching of an ore, flows through line 1 into the primary extractor 3 which may comprise any suitable tank equipped with agitating and mixing means so as to obtain intimate contact between the feed solution and the a-hydroxy oxime extractant. The extractor 3 can suitably be conventional mixer-settler equipment provided with an appropriate weir arrangement to accomplish separation of an aqueous phase and an organic phase. Prior to introduction into extractor 3 the feed solution can be made basic, preferably with ammonia, if it is not already so.
The a-hydroxy oxime extractant, preferably in an organic solvent, is introduced into extractor 3 via line 2. The feed solution (line 1) and the a-hydroxy oxime extractant (line 2) are delivered'to extractor 3 at such rates to provide sufficient extracting capacity for the amount of nickel and zinc metal values present in feed solution 1. The amount of extractant to be supplied through line 2 can be readily and routinely determined. Afterintimate contact in the mixing area 3A of the extractor, the mixed aqueous and organic phases are permitted to separate by virtue of their immiscibility in the settler area 38 and are withdrawn on opposite sides of weir 4. The aqueous phase or raffinate., relatively barren of nickel value, is withdrawn through line 5 and can be processed for recovery of ammonia or recycled to the ore leaching operation, for example. The metalscontaining organic phase is sent via line 6 to overloading tank 7 which-conveniently can be a mixer-settler tank where it is contacted with a nickel-bearing liquid stream which is introduced through line 8. The nickelbearing stream which is introduced through line 8 may, if desired, be from the same source as the original feed solution. Stream 8 is fed to mixer-settler 7 at a rate to provide nickel ions in excess of the remaining extraction capacity of the a-hydroxy oxime in tank 7. Since all of the nickel ions present in stream 8 cannot be extracted (an excess of nickel ions being desired) the aqueous phase, after phase separation, is withdrawn through line 9 and sent to storage tank 10. The minimum excess of nickel ions leaving overload stage 7 is preferably in the range of 2-3 grams/liter but can vary widely above and below this range depending on the system and degree of effectiveness desired in the overloading process.
The organic extractant phase, now substantially saturated or overloaded with nickel, leaves mixer-settler 7 via line 11 and can be sent directly to stripper 14. Optionally, if desired, this organic phase can be directed through line 11a into washer 13. A slightly acidic aqueous wash solution containing, for example, sufficient electrolytes (ammonium sulfate, sodium chloride, etc.) to cause adequate phase separation, is introduced into washer 13 via line 12 and is removed'therefrom via line 16, and optionally may be directed back to extraction stage 3. The pH of the wash solution can vary widely, but preferably is in the range of pH 3.5 to 5.5. Washed organic is sent via line to stripper 14.
lfi s tri p r 14 the organic extractant phase is con tacted with an aqueous nickel stripping solution. A variety of stripping agents can be used, although it is preferred to use aqueous solutions of inorganic acids and salts such as the electrolyte employed in a subsequent electro-winning operation. The stripping agent is introduced into stripper 14 via line 17. When the stripping agent comprises a spent electrolyte from an electrowinning operation or a mother liquor from a subsequent crystallization recovery procedure it can, if necessary, be fortified with acid prior to introduction into stripper 14. The volume phase ratio of the aqueous stripping solution to the organic phase can be varied over wide limits which are well known to those skilled in the art. The
ous stripping solution loaded with nickel is sent via line 18 to nickel recovery at 19. Nickel can be recovered at 19 by conventional procedures such as crystallization or electrowinning. The stripped organic phase from stripper 14 is recycled via line 2 to the primary extractorstage 3 for reuse as extractant.
As is seen from the described process, the a-hydroxy oxime extractant becomes partially loaded with nickel and some zinc for which it has lesser affinity'in extractor stage 3. In stage 7 it is exposed to nickel ions which displace zinc ions from the extractant. When the nickel ion concentration in storage tank 10 becomes depleted or reduced to a low level through continuous recycling through overload" stage 7 it can be fed to the extraction stage 3 as feed for removal of nickel values therefrom while tank 10 is replenished with a source of nickel. It is to be appreciated that the overload mkeribn' source from tank 10 may, if desired, be the same as feed stream 1 and can contain the same impurities.
The process of this invention is not limited by the particular type of equipment employed. Thus, while mixer-settler units have been referred to in the above description, pulsed columns, centrifugal contactors and similar equipment known to those skilled in the art can be used. Moreover, the number of contacting stages for the steps of extraction, overloading, washing and stripping of nickel ions can be varied to accomplish the desired operations, and one or more stages may be necessary, depending upon the zinc content of the feed solution.
A summary of a typical operation of the process of the invention is as follows:
To extract nickel from a stream containing zinc as a primary impurity a solution of approximately 15 percent of a-hydroxy oxime organic extractant (LIX64N developed by General Mills, Inc.) in a hydrocarbon solvent was employed. The system consisted of conventional mixer-settler stages utilizing two primary extraction stages (3), one overload stage (7), one acidic wash stage (13) and two strip stages (14). The organic extractant was stripped with an aqueous nickel sulfate electrolyte which was continuously recycled from nickel electrowinning cells. Ammonia was entrained in the organic liquid extractant and the wash stage was used to prevent crystallization of relatively insoluble nickel ammonium sulfate in the strip stages and electrowinning operation. The acidic wash also removed aqueous stripping solution and the organic phase are much of the zinc left on the extractant after the overseparated by virtue of their immiscibility and the aqueload stage.
With Overload and Without Overload Selective Strip and Selective Strip FLOW Zn, g/l Ni, g/l Zn, g/l Nil l Stripped Organic Extractant (line 2) 0.00008 0.28 0.00008 0.28 Loaded Organic Extractant (line 6) 0.00088 2.90 0.00088 2,90 Overloaded Organic Extractant (line I l) 0.00036 3.35 Washed Organic.
Extract-ant (line 15) 0.00013 3.15 Raffinate (line 5) 0.033 0010 00K) Feed (line l) & Overload Sol'n (line 8) 0.033 5.0 5.0 Wt. /r Zn in Ni 0.00l7 0.0285
From the above data the advantages of the present process are readily seen. As can be seen, without the employment of the overload'and wash stages a relatively large amount of zinc was transferred to the electrolyte. However, by employing the present invention the zinc transfer was reduced to less than current ASTM specifications for electrolytic nickel which is 0.002 weight percent zinc in nickel or less.
Those modifications and equivalents which fall within the spirit of the invention are to be considered a part thereof.
What is claimed is:
1. A process which comprises contacting an aqueous stream containing nickel and zinc with' an a-hydroxy oxime to extract nickel and zinc from said stream, then contacting said extractant containing both nickel and zinc with an aqueous solution containing an excess of nickel ions to displace zinc therefrom, and then stripping nickel from said extractant.
2. The process of claim 1 wherein after contacting the said extractant with an excess of nickel ions the extractant prior to the stripping operation is washed with an acidic wash solution.
3. A process according to claim 1 wherein the excess of nickel ions is recycled in a closed circuit to prevent loss of the excess of nickel ions.
Claims (2)
- 2. The process of claim 1 wherein after contacting the said extractant with an excess of nickel ions the extractant prior to the stripping operation is washed with an acidic wash solution.
- 3. A process according to claim 1 wherein the excess of nickel ions is recycled in a closed circuit to prevent loss of the excess of nickel ions.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US22932872A | 1972-02-25 | 1972-02-25 |
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US3794719A true US3794719A (en) | 1974-02-26 |
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US00229328A Expired - Lifetime US3794719A (en) | 1972-02-25 | 1972-02-25 | Reduction of nickel contamination by zinc in {60 -hydroxy oxime extract |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3981969A (en) * | 1975-10-15 | 1976-09-21 | Uop Inc. | Pressurized column solvent extraction of nickel from ammoniacal solutions |
US3981966A (en) * | 1974-07-26 | 1976-09-21 | E. I. Du Pont De Nemours And Company | Zinc recovery from acidic aqueous streams |
US3988151A (en) * | 1973-07-19 | 1976-10-26 | Kennecott Copper Corporation | Liquid ion exchange process for the recovery of copper and nickel |
FR2319578A1 (en) * | 1975-07-21 | 1977-02-25 | Kennecott Copper Corp | CLEANING OF AMMONIA IN LIQUID ION EXCHANGER REAGENTS |
US4032660A (en) * | 1974-06-25 | 1977-06-28 | Labaz | Acetoxime derivatives and process for preparing the same |
US4314976A (en) * | 1980-07-18 | 1982-02-09 | Southwire Company | Purification of nickel sulfate |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3088799A (en) * | 1959-05-25 | 1963-05-07 | Nopco Chem Co | Metal extraction process |
US3276863A (en) * | 1964-01-21 | 1966-10-04 | Gen Mills Inc | Separation of nickel and cobalt values using alpha-hydroxy oximes |
US3399055A (en) * | 1965-06-21 | 1968-08-27 | Eldorado Mining & Refining Ltd | Separation of cobalt by liquid extraction from acid solutions |
US3479378A (en) * | 1967-11-06 | 1969-11-18 | Bunker Hill Co | Liquid ion exchange process for metal recovery |
US3682589A (en) * | 1969-11-10 | 1972-08-08 | Bunker Hill Co | Sorbate extraction of metallic values from aqueous leach solutions |
-
1972
- 1972-02-25 US US00229328A patent/US3794719A/en not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3088799A (en) * | 1959-05-25 | 1963-05-07 | Nopco Chem Co | Metal extraction process |
US3276863A (en) * | 1964-01-21 | 1966-10-04 | Gen Mills Inc | Separation of nickel and cobalt values using alpha-hydroxy oximes |
US3399055A (en) * | 1965-06-21 | 1968-08-27 | Eldorado Mining & Refining Ltd | Separation of cobalt by liquid extraction from acid solutions |
US3479378A (en) * | 1967-11-06 | 1969-11-18 | Bunker Hill Co | Liquid ion exchange process for metal recovery |
US3682589A (en) * | 1969-11-10 | 1972-08-08 | Bunker Hill Co | Sorbate extraction of metallic values from aqueous leach solutions |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3988151A (en) * | 1973-07-19 | 1976-10-26 | Kennecott Copper Corporation | Liquid ion exchange process for the recovery of copper and nickel |
US4032660A (en) * | 1974-06-25 | 1977-06-28 | Labaz | Acetoxime derivatives and process for preparing the same |
US3981966A (en) * | 1974-07-26 | 1976-09-21 | E. I. Du Pont De Nemours And Company | Zinc recovery from acidic aqueous streams |
FR2319578A1 (en) * | 1975-07-21 | 1977-02-25 | Kennecott Copper Corp | CLEANING OF AMMONIA IN LIQUID ION EXCHANGER REAGENTS |
US4012482A (en) * | 1975-07-21 | 1977-03-15 | Kennecott Copper Corporation | Scrubbing of ammonia from oxime liquid ion exchange reagents |
US3981969A (en) * | 1975-10-15 | 1976-09-21 | Uop Inc. | Pressurized column solvent extraction of nickel from ammoniacal solutions |
US4314976A (en) * | 1980-07-18 | 1982-02-09 | Southwire Company | Purification of nickel sulfate |
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