GB1139446A - Polymers containing n,n-disubstituted vinyloxymethylamine units - Google Patents
Polymers containing n,n-disubstituted vinyloxymethylamine unitsInfo
- Publication number
- GB1139446A GB1139446A GB16510/66A GB1651066A GB1139446A GB 1139446 A GB1139446 A GB 1139446A GB 16510/66 A GB16510/66 A GB 16510/66A GB 1651066 A GB1651066 A GB 1651066A GB 1139446 A GB1139446 A GB 1139446A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polyvinyl alcohol
- alcohol
- alkyl
- april
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000642 polymer Polymers 0.000 title abstract 4
- CASAJNRMGIBYSQ-UHFFFAOYSA-N ethenoxymethanamine Chemical group NCOC=C CASAJNRMGIBYSQ-UHFFFAOYSA-N 0.000 title 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 4
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 abstract 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 abstract 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 abstract 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 abstract 2
- 150000003839 salts Chemical group 0.000 abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 1
- AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methyl-N-phenylamine Natural products CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 abstract 1
- XTUVJUMINZSXGF-UHFFFAOYSA-N N-methylcyclohexylamine Chemical compound CNC1CCCCC1 XTUVJUMINZSXGF-UHFFFAOYSA-N 0.000 abstract 1
- PAMIQIKDUOTOBW-UHFFFAOYSA-N N-methylcyclohexylamine Natural products CN1CCCCC1 PAMIQIKDUOTOBW-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001350 alkyl halides Chemical class 0.000 abstract 1
- -1 alkyl p-toluenesulphonates Chemical class 0.000 abstract 1
- 239000002216 antistatic agent Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 abstract 1
- 239000012971 dimethylpiperazine Substances 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- MHYFEEDKONKGEB-UHFFFAOYSA-N oxathiane 2,2-dioxide Chemical compound O=S1(=O)CCCCO1 MHYFEEDKONKGEB-UHFFFAOYSA-N 0.000 abstract 1
- 239000001294 propane Substances 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/02—Photosensitive materials characterised by the image-forming section
- G03C8/04—Photosensitive materials characterised by the image-forming section the substances transferred by diffusion consisting of inorganic or organo-metallic compounds derived from photosensitive noble metals
- G03C8/06—Silver salt diffusion transfer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/44—Preparation of metal salts or ammonium salts
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/04—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with macromolecular additives; with layer-forming substances
- G03C1/053—Polymers obtained by reactions involving only carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/24—Photosensitive materials characterised by the image-receiving section
- G03C8/26—Image-receiving layers
- G03C8/28—Image-receiving layers containing development nuclei or compounds forming such nuclei
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/923—Ethylenic monomers containing at least one salt group
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Physics & Mathematics (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
1,139,446. After-treated polyvinyl alcohol. EASTMAN KODAK CO. 15 April, 1966 [15 April, 1965],No. 16510/66. Heading C3P. Polymers having repeating units of the formula in which R<SP>1</SP> and R<SP>2</SP> represent any two substituents or together with the nitrogen form a heterocyclic ring, or a quaternary salt thereof, are formed by reacting a polyvinyl alcohol with a compound of the formula ROCH 2 NR<SP>1</SP>R<SP>2</SP> in which R is alkyl and quaternizing if desired. The polyvinyl alcohol may contain comonomers, particularly vinyl acetate and the acetate groups may be removed after the reaction. Exemplified reactants are the N-ethoxymethyl derivatives of N-methyl aniline, morpholine, piperidine, diethylamine, dibutylamine, 4,4-dimethylpiperazine, and N-methyl cyclohexylamine, and quaternizing agents are alkyl p-toluenesulphonates, dialkyl sulphates, alkyl halides, and propane or butane sultone. Reaction with an alcohol reconverts the polymer to polyvinyl alcohol and a solution of the polymer containing an alcohol can be spun into fibres or cast as a film. The quaternary salts can be used as mordants, peptizers, sensitizers or anti-static agents.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US44826665A | 1965-04-15 | 1965-04-15 | |
US448264A US3345346A (en) | 1965-04-15 | 1965-04-15 | Aminopolymer compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1139446A true GB1139446A (en) | 1969-01-08 |
Family
ID=27035291
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB16509/66A Expired GB1148482A (en) | 1965-04-15 | 1966-04-15 | Silver halide dispersions |
GB35567/68A Expired GB1148483A (en) | 1965-04-15 | 1966-04-15 | Dispersions of physical development nuclei |
GB16510/66A Expired GB1139446A (en) | 1965-04-15 | 1966-04-15 | Polymers containing n,n-disubstituted vinyloxymethylamine units |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB16509/66A Expired GB1148482A (en) | 1965-04-15 | 1966-04-15 | Silver halide dispersions |
GB35567/68A Expired GB1148483A (en) | 1965-04-15 | 1966-04-15 | Dispersions of physical development nuclei |
Country Status (4)
Country | Link |
---|---|
US (1) | US3425836A (en) |
BE (1) | BE678582A (en) |
DE (2) | DE1595569B2 (en) |
GB (3) | GB1148482A (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3637394A (en) * | 1968-04-22 | 1972-01-25 | Eastman Kodak Co | Photographic elements containing synthetic polymeric vehicles |
US3816129A (en) * | 1973-01-02 | 1974-06-11 | Polaroid Corp | Synthetic silver halide emulsion binder |
US3962527A (en) * | 1973-03-09 | 1976-06-08 | Eastman Kodak Company | Novel polymers and photographic elements containing same |
US4299898A (en) * | 1979-05-03 | 1981-11-10 | Xerox Corporation | Positively charged toners containing quaternary ammonium salts attached to acrylate polymers |
US5804363A (en) * | 1997-04-28 | 1998-09-08 | Eastman Kodak Company | High bromide (111) tabular grain emulsions containing a cationic peptizer having diallylammonium derived repeating units |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2358836A (en) * | 1942-05-26 | 1944-09-26 | Eastman Kodak Co | Water-soluble polyvinyl acetals |
US2725381A (en) * | 1953-02-02 | 1955-11-29 | Eastman Kodak Co | Process of preparing methyl 4-vinylpyridinium p-toluenesulfonate |
BE542633A (en) * | 1954-11-08 |
-
1965
- 1965-04-15 US US448266A patent/US3425836A/en not_active Expired - Lifetime
-
1966
- 1966-03-10 DE DE19661595569 patent/DE1595569B2/en active Pending
- 1966-03-28 BE BE678582D patent/BE678582A/xx unknown
- 1966-04-13 DE DE19661547678 patent/DE1547678A1/en active Pending
- 1966-04-15 GB GB16509/66A patent/GB1148482A/en not_active Expired
- 1966-04-15 GB GB35567/68A patent/GB1148483A/en not_active Expired
- 1966-04-15 GB GB16510/66A patent/GB1139446A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
GB1148483A (en) | 1969-04-10 |
DE1595569B2 (en) | 1971-04-08 |
BE678582A (en) | 1966-09-01 |
US3425836A (en) | 1969-02-04 |
GB1148482A (en) | 1969-04-10 |
DE1595569A1 (en) | 1970-03-19 |
DE1547678A1 (en) | 1971-11-25 |
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