GB1123837A - Catalytic hydrogenation of unsaturated aldehydes - Google Patents
Catalytic hydrogenation of unsaturated aldehydesInfo
- Publication number
- GB1123837A GB1123837A GB3473165A GB3473165A GB1123837A GB 1123837 A GB1123837 A GB 1123837A GB 3473165 A GB3473165 A GB 3473165A GB 3473165 A GB3473165 A GB 3473165A GB 1123837 A GB1123837 A GB 1123837A
- Authority
- GB
- United Kingdom
- Prior art keywords
- platinum
- charcoal
- selective hydrogenation
- metal catalyst
- hydroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001299 aldehydes Chemical class 0.000 title abstract 3
- 238000009903 catalytic hydrogenation reaction Methods 0.000 title 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 abstract 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000005984 hydrogenation reaction Methods 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 abstract 1
- VAJVDSVGBWFCLW-UHFFFAOYSA-N 3-Phenyl-1-propanol Chemical compound OCCCC1=CC=CC=C1 VAJVDSVGBWFCLW-UHFFFAOYSA-N 0.000 abstract 1
- YGCZTXZTJXYWCO-UHFFFAOYSA-N 3-phenylpropanal Chemical compound O=CCCC1=CC=CC=C1 YGCZTXZTJXYWCO-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 230000001476 alcoholic effect Effects 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- 150000004703 alkoxides Chemical class 0.000 abstract 1
- OOCCDEMITAIZTP-UHFFFAOYSA-N allylic benzylic alcohol Natural products OCC=CC1=CC=CC=C1 OOCCDEMITAIZTP-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000003610 charcoal Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229940117916 cinnamic aldehyde Drugs 0.000 abstract 1
- KJPRLNWUNMBNBZ-UHFFFAOYSA-N cinnamic aldehyde Natural products O=CC=CC1=CC=CC=C1 KJPRLNWUNMBNBZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229960004592 isopropanol Drugs 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- CFQCIHVMOFOCGH-UHFFFAOYSA-N platinum ruthenium Chemical compound [Ru].[Pt] CFQCIHVMOFOCGH-UHFFFAOYSA-N 0.000 abstract 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/42—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/09—Geometrical isomers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3473165A GB1123837A (en) | 1965-08-13 | 1965-08-13 | Catalytic hydrogenation of unsaturated aldehydes |
| DE19661568861 DE1568861A1 (de) | 1965-08-13 | 1966-08-06 | Verfahren zur Hydrierung ungesaettigter Aldehyde |
| BE685368D BE685368A (enrdf_load_stackoverflow) | 1965-08-13 | 1966-08-10 | |
| FR73033A FR1489504A (fr) | 1965-08-13 | 1966-08-12 | Procédé d'hydrogénation des aldéhydes insaturés |
| NL6611392A NL6611392A (enrdf_load_stackoverflow) | 1965-08-13 | 1966-08-12 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3473165A GB1123837A (en) | 1965-08-13 | 1965-08-13 | Catalytic hydrogenation of unsaturated aldehydes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1123837A true GB1123837A (en) | 1968-08-14 |
Family
ID=10369277
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3473165A Expired GB1123837A (en) | 1965-08-13 | 1965-08-13 | Catalytic hydrogenation of unsaturated aldehydes |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE685368A (enrdf_load_stackoverflow) |
| DE (1) | DE1568861A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1123837A (enrdf_load_stackoverflow) |
| NL (1) | NL6611392A (enrdf_load_stackoverflow) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3953524A (en) * | 1973-03-21 | 1976-04-27 | Hoffmann-La Roche Inc. | Catalytic hydrogenation of alpha,beta-unsaturated aldehydes to alpha,beta-unsaturated alcohols |
| US4455442A (en) * | 1979-08-24 | 1984-06-19 | Basf Aktiengesellschaft | Preparation of unsaturated alcohols |
| CN107285994A (zh) * | 2016-04-13 | 2017-10-24 | 中国科学院大连化学物理研究所 | 一种肉桂醛选择性加氢合成肉桂醇的方法 |
| US9993812B2 (en) | 2012-04-17 | 2018-06-12 | Momentive Pereformance Materials Inc. | High activity catalyst for hydrosilylation reactions and methods of making the same |
| WO2022252580A1 (zh) * | 2021-06-02 | 2022-12-08 | 中国华能集团清洁能源技术研究院有限公司 | 一种金属铂催化剂及其制备方法和应用 |
| CN119346105A (zh) * | 2024-11-18 | 2025-01-24 | 南京工业大学 | 一种利用Au@Pt/C催化剂用于苯甲醛加氢制备苯甲醇的方法 |
-
1965
- 1965-08-13 GB GB3473165A patent/GB1123837A/en not_active Expired
-
1966
- 1966-08-06 DE DE19661568861 patent/DE1568861A1/de active Pending
- 1966-08-10 BE BE685368D patent/BE685368A/xx unknown
- 1966-08-12 NL NL6611392A patent/NL6611392A/xx unknown
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3953524A (en) * | 1973-03-21 | 1976-04-27 | Hoffmann-La Roche Inc. | Catalytic hydrogenation of alpha,beta-unsaturated aldehydes to alpha,beta-unsaturated alcohols |
| US4455442A (en) * | 1979-08-24 | 1984-06-19 | Basf Aktiengesellschaft | Preparation of unsaturated alcohols |
| US9993812B2 (en) | 2012-04-17 | 2018-06-12 | Momentive Pereformance Materials Inc. | High activity catalyst for hydrosilylation reactions and methods of making the same |
| CN107285994A (zh) * | 2016-04-13 | 2017-10-24 | 中国科学院大连化学物理研究所 | 一种肉桂醛选择性加氢合成肉桂醇的方法 |
| CN107285994B (zh) * | 2016-04-13 | 2020-08-14 | 中国科学院大连化学物理研究所 | 一种肉桂醛选择性加氢合成肉桂醇的方法 |
| WO2022252580A1 (zh) * | 2021-06-02 | 2022-12-08 | 中国华能集团清洁能源技术研究院有限公司 | 一种金属铂催化剂及其制备方法和应用 |
| CN119346105A (zh) * | 2024-11-18 | 2025-01-24 | 南京工业大学 | 一种利用Au@Pt/C催化剂用于苯甲醛加氢制备苯甲醇的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| BE685368A (enrdf_load_stackoverflow) | 1967-01-16 |
| DE1568861A1 (de) | 1970-06-25 |
| NL6611392A (enrdf_load_stackoverflow) | 1967-02-14 |
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