GB1122525A - Process for catalytically hydrodesulfurizing a sulfur-containing petroleum oil - Google Patents
Process for catalytically hydrodesulfurizing a sulfur-containing petroleum oilInfo
- Publication number
- GB1122525A GB1122525A GB1416/67A GB141667A GB1122525A GB 1122525 A GB1122525 A GB 1122525A GB 1416/67 A GB1416/67 A GB 1416/67A GB 141667 A GB141667 A GB 141667A GB 1122525 A GB1122525 A GB 1122525A
- Authority
- GB
- United Kingdom
- Prior art keywords
- radius
- pores
- less
- catalyst
- pore
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003208 petroleum Substances 0.000 title abstract 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 229910052717 sulfur Inorganic materials 0.000 title 1
- 239000011593 sulfur Substances 0.000 title 1
- 239000011148 porous material Substances 0.000 abstract 13
- 239000003054 catalyst Substances 0.000 abstract 5
- 239000003921 oil Substances 0.000 abstract 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- 230000032683 aging Effects 0.000 abstract 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 abstract 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 abstract 1
- 229910000329 aluminium sulfate Inorganic materials 0.000 abstract 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 abstract 1
- 235000011128 aluminium sulphate Nutrition 0.000 abstract 1
- 235000011114 ammonium hydroxide Nutrition 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 229910001680 bayerite Inorganic materials 0.000 abstract 1
- 229910001593 boehmite Inorganic materials 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 239000000356 contaminant Substances 0.000 abstract 1
- 230000018044 dehydration Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 229910001679 gibbsite Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 239000002574 poison Substances 0.000 abstract 1
- 231100000614 poison Toxicity 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- -1 sulphate ions Chemical class 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US521816A US3383301A (en) | 1966-01-20 | 1966-01-20 | Residue desulfurization with catalyst whose pore volume is distributed over wide range of pore sizes |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1122525A true GB1122525A (en) | 1968-08-07 |
Family
ID=24078287
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1416/67A Expired GB1122525A (en) | 1966-01-20 | 1967-01-11 | Process for catalytically hydrodesulfurizing a sulfur-containing petroleum oil |
Country Status (9)
Country | Link |
---|---|
US (1) | US3383301A (da) |
BE (1) | BE692879A (da) |
CH (1) | CH487235A (da) |
DE (1) | DE1645750B2 (da) |
DK (1) | DK115194B (da) |
ES (1) | ES335782A1 (da) |
FR (1) | FR1509369A (da) |
GB (1) | GB1122525A (da) |
NL (1) | NL152295B (da) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4918763B1 (da) * | 1970-01-12 | 1974-05-13 |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3471399A (en) * | 1967-06-09 | 1969-10-07 | Universal Oil Prod Co | Hydrodesulfurization catalyst and process for treating residual fuel oils |
NL167464C (nl) * | 1970-07-14 | 1981-12-16 | Shell Int Research | Werkwijze voor het katalytisch hydrogerend ontzwa- velen van residuale koolwaterstofolien. |
US4012340A (en) * | 1971-02-01 | 1977-03-15 | Chiyoda Kako Kensetsu Kabushiki Kaisha | Process for preparing catalysts for hydrodesulfurization |
JPS526711B1 (da) * | 1971-02-01 | 1977-02-24 | ||
CA1020478A (en) * | 1972-07-14 | 1977-11-08 | Gulf Research And Development Company | Hydrodesulfurization of petroleum distillates |
US4341625A (en) * | 1973-08-09 | 1982-07-27 | Chevron Research Company | Method for preparing a catalyst carrier, a catalyst containing the carrier, and a hydrocarbon hydrodesulfurization process using the catalyst |
GB1452802A (en) * | 1974-03-25 | 1976-10-20 | British Petroleum Co | Desulphurisation process |
US4082695A (en) * | 1975-01-20 | 1978-04-04 | Mobil Oil Corporation | Catalyst for residua demetalation and desulfurization |
US4134856A (en) * | 1975-04-18 | 1979-01-16 | Toa Nenryo Kogyo Kabushiki Kaisha | Catalyst for hydro-refining hydrocarbon oils |
NZ184201A (en) * | 1976-08-12 | 1979-10-25 | Mobil Oil Corp | Residium hydroprocessing catalyst of group vi-b and viii metal sulfides and/or oxides on alumina |
US4267071A (en) * | 1977-08-08 | 1981-05-12 | Mobil Oil Corporation | Catalyst for hydrotreating residual petroleum oil |
US4351717A (en) * | 1977-08-08 | 1982-09-28 | Mobil Oil Corporation | Catalyst for hydrotreating residual petroleum oil |
US4224144A (en) * | 1979-03-19 | 1980-09-23 | Standard Oil Company (Indiana) | Hydrotreating a hydrocarbon stream to remove nitrogen and sulfur |
US4301037A (en) * | 1980-04-01 | 1981-11-17 | W. R. Grace & Co. | Extruded alumina catalyst support having controlled distribution of pore sizes |
AU547464B2 (en) * | 1981-06-17 | 1985-10-24 | Amoco Corporation | Catalyst for hydrotreating hydrocarbon feed |
JPS6065093A (ja) * | 1983-09-21 | 1985-04-13 | Res Assoc Petroleum Alternat Dev<Rapad> | オイルサンド油および残渣油の処理方法 |
US4652545A (en) * | 1985-05-06 | 1987-03-24 | American Cyanamid Company | Catalyst for hydroconversion of heavy oils and method of making the catalyst |
JP2631712B2 (ja) * | 1988-08-18 | 1997-07-16 | コスモ石油株式会社 | 重質炭化水素油の水素化処理触媒組成物ならびにそれを用いる水素化処理方法 |
US5041404A (en) * | 1988-09-13 | 1991-08-20 | Cri Ventures, Inc. | Method of presulfiding a hydrotreating, hydrocracking or tail gas treating catalyst |
US4943547A (en) * | 1988-09-13 | 1990-07-24 | Seamans James D | Method of presulfiding a hydrotreating catalyst |
US5215954A (en) * | 1991-07-30 | 1993-06-01 | Cri International, Inc. | Method of presulfurizing a hydrotreating, hydrocracking or tail gas treating catalyst |
US5192734A (en) * | 1991-10-25 | 1993-03-09 | W. R. Grace & Co.- Conn. | Hydroprocessing catalyst composition |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL302376A (da) * | 1962-12-21 | |||
US3322666A (en) * | 1964-08-25 | 1967-05-30 | Gulf Research Development Co | Chemical process for hydrocracking and hydrorefining of hydrocarbon oils |
US3340180A (en) * | 1964-08-25 | 1967-09-05 | Gulf Research Development Co | Hydrofining-hydrocracking process employing special alumina base catalysts |
US3297588A (en) * | 1964-10-01 | 1967-01-10 | Gulf Research Development Co | Catalyst comprising a metallic composnent supported on an alumina base |
-
1966
- 1966-01-20 US US521816A patent/US3383301A/en not_active Expired - Lifetime
-
1967
- 1967-01-11 GB GB1416/67A patent/GB1122525A/en not_active Expired
- 1967-01-16 DE DE1967G0049000 patent/DE1645750B2/de active Granted
- 1967-01-18 CH CH71767A patent/CH487235A/fr not_active IP Right Cessation
- 1967-01-18 ES ES0335782A patent/ES335782A1/es not_active Expired
- 1967-01-19 DK DK33567AA patent/DK115194B/da not_active IP Right Cessation
- 1967-01-19 FR FR91702A patent/FR1509369A/fr not_active Expired
- 1967-01-19 BE BE692879D patent/BE692879A/xx not_active IP Right Cessation
- 1967-01-20 NL NL676700961A patent/NL152295B/xx not_active IP Right Cessation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4918763B1 (da) * | 1970-01-12 | 1974-05-13 |
Also Published As
Publication number | Publication date |
---|---|
BE692879A (da) | 1967-07-03 |
FR1509369A (fr) | 1968-01-12 |
DE1645750B2 (de) | 1977-01-13 |
CH487235A (fr) | 1970-03-15 |
NL152295B (nl) | 1977-02-15 |
NL6700961A (da) | 1967-07-21 |
DK115194B (da) | 1969-09-15 |
DE1645750A1 (de) | 1970-05-14 |
US3383301A (en) | 1968-05-14 |
ES335782A1 (es) | 1967-12-16 |
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