GB1121859A - Improvements relating to drafting films - Google Patents
Improvements relating to drafting filmsInfo
- Publication number
- GB1121859A GB1121859A GB2785/65A GB278565A GB1121859A GB 1121859 A GB1121859 A GB 1121859A GB 2785/65 A GB2785/65 A GB 2785/65A GB 278565 A GB278565 A GB 278565A GB 1121859 A GB1121859 A GB 1121859A
- Authority
- GB
- United Kingdom
- Prior art keywords
- copolymer
- vinylidene chloride
- matting agent
- film
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/795—Photosensitive materials characterised by the base or auxiliary layers the base being of macromolecular substances
- G03C1/7954—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/91—Photosensitive materials characterised by the base or auxiliary layers characterised by subbing layers or subbing means
- G03C1/93—Macromolecular substances therefor
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/95—Photosensitive materials characterised by the base or auxiliary layers rendered opaque or writable, e.g. with inert particulate additives
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
- G03F1/68—Preparation processes not covered by groups G03F1/20 - G03F1/50
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2483/02—Polysilicates
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Laminated Bodies (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
Abstract
A drafting film comprises a flexible, biaxially oriented, highly polymeric polyester film composed of the polyesterification product of at least one dicarboxylic acid and at least one dihydric alcohol, having on at least one surface a layer of essentially hydrophobic vinylidene chloride copolymer containing at least 35% of vinylidene chloride, or of a hydrophobic terpolymer comprising 48 to 70% C2-C10 alkyl acrylate, 30 to 48% styrene, acrylonitrile or methyl methacrylate, and 4 to 12% acrylic or methacrylic acid, followed by a hydrophobic, continuous layer of methyl methacrylate -C1 to C2 alkyl acrylate copolymer having a Tukon film hardness above 10 KHN and containing up to 1 part uniformly dispersed, finely-divided, discrete particles of a water-insoluble, translucence-producing solid matting agent. Suitable polyester supports are films of polyethylene terephthalate, polyethylene terephthalate/isophthalates, and the condensates of terephthalic acid or dimethyl terephthalate with propylene glycol, diethylene glycol, tetramethylene glycol or cyclo-hexane-1, 4-dimethanol, and polycarbonates. The Tukon hardness can be adjusted by mixing the methyl methacrylate copolymer with another acrylic polymer of different hardness. The vinylidene chloride copolymer layer may be a vinylidene chloride/acrylic ester/itaconic acid copolymer. A suitable copolymer may be vinylidene chloride/methyl acrylate/itaconic acid copolymer. The matting agent may be silicon dioxide, rice starch particles and materials additionally acting as opacifying pigment or colouring agent e.g. silica, ground glass, chalk, talc, diatomaceous earth, magnesium carbonate, barytes, clay, Monastral Fast Blue, and other pigments and dyes. Methods of applying the vinylidene chloride copolymer layer are those disclosed in Specifications 718,422, and 786,176, the said layer being usually applied to the polyester base prior to orienting it. The methyl methacrylate copolymer layer is applied as an aqueous dispersion, or latex, containing heat-removable coalescent material and the particles of matting agent which is then dried at 60 to 125 DEG C. and cured at 100 to 150 DEG C to remove the coalescent material, or heated for a longer time at a temperature above 60 DEG C. Suitable coalescent materials are glycols, glycol-ethers, glycol-ether esters. The dispersion may contain a hydrosol of silica, dispersants, a thickener such as a copolymer of methyl vinyl ether and maleic anhydride, and surfactants e.g. isooctyl phenoxy polyethoxy ethanol, to act as wetting agents. The dispersion may be treated mechanically say by passing it through a sand mill to disperse the pigments before or after adding the polymer latex. The dispersions can be applied by dip-coating, bead coating or applicator rolls, or supplied from a gravity- or pressure-fed hopper, and the thickness of the coating can be controlled by doctor blades or air streams. The support film may be coated on both sides with the same drafting film composition or with different drafting film compositions e.g. one side with a drafting film containing a hard matting agent such as silicon dioxide, and the other with either no matting agent or a soft matting agent such as rice starch. The drafting film may be overcoated with a substratum comprised of a reaction product prepared by polymerising, in the presence of gelatin, at least one vinyl monomer such as vinylidene chloride, methyl acrylate or ethyl acrylate. At least one surfactant e.g. an amphoteric material such as sodium N-coco-b -aminopropionate, N-tallow-b -imino-dipropionate, N-lauryl-b -aminopionic acid or cetyl or other long chain betaine, compounds of formula RHNn[(CH2)nCOOM]m where R is an unsubstituted alkyl group of 12 to 18 carbon atoms, m and n are 1 or 2, p is 2-m, and M is a cation such as sodium, potassium, lithium, ammonium, hydrogen, may be present in the substratum.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US339849A US3353958A (en) | 1964-01-24 | 1964-01-24 | Photographic compositions and process |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1121859A true GB1121859A (en) | 1968-07-31 |
Family
ID=23330891
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2785/65A Expired GB1121859A (en) | 1964-01-24 | 1967-09-25 | Improvements relating to drafting films |
Country Status (4)
Country | Link |
---|---|
US (1) | US3353958A (en) |
BE (1) | BE658724A (en) |
FR (1) | FR1422579A (en) |
GB (1) | GB1121859A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0019178A2 (en) * | 1979-05-16 | 1980-11-26 | Agfa-Gevaert AG | Process for the preparation of matting layers |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3547644A (en) * | 1966-01-03 | 1970-12-15 | Du Pont | Photographic drafting film with a polyethylene terephthalate base containing silica |
USRE29255E (en) * | 1968-10-16 | 1977-06-07 | E. I. Du Pont De Nemours And Company | Photographic layers containing perfluoro compounds and coating thereof |
US3988157A (en) * | 1972-07-17 | 1976-10-26 | Agfa-Gevaert N.V. | Process for adhering hydrophilic layers to dimensionally stable polyester films |
US4124395A (en) * | 1973-08-10 | 1978-11-07 | Fuji Photo Film Co., Ltd. | Subbing layer on polyester film for light-sensitive material |
IT1159920B (en) * | 1977-10-03 | 1987-03-04 | Ici Ltd | IMPROVEMENTS RELATED TO COATED BASIC FILMS |
JPS5947987B2 (en) * | 1979-10-08 | 1984-11-22 | 富士写真フイルム株式会社 | Matsuto film that can be added/edited |
JPS5952647A (en) * | 1982-06-30 | 1984-03-27 | 富士写真フイルム株式会社 | Mat film which can be corrected |
JP2006527674A (en) * | 2003-06-18 | 2006-12-07 | フジ フォト フィルム ビー.ブイ. | Inkjet recording medium |
EP1677989B1 (en) * | 2003-10-03 | 2008-01-30 | FUJIFILM Manufacturing Europe B.V. | Recording medium |
DE602004007677T2 (en) * | 2003-10-03 | 2008-04-17 | Fujifilm Manufacturing Europe B.V. | INK JET RECORDING MEDIUM |
US7147909B2 (en) * | 2004-11-30 | 2006-12-12 | Eastman Kodak Company | Electrophotographic media with carboxylic acid polymer |
US7687136B2 (en) * | 2004-11-30 | 2010-03-30 | Eastman Kodak Company | Fuser-oil sorbent electrophotographic toner receiver layer |
US7754315B2 (en) * | 2004-11-30 | 2010-07-13 | Eastman Kodak Company | Marking enhancement layer for toner receiver element |
JP5734569B2 (en) * | 2010-01-18 | 2015-06-17 | 富士フイルム株式会社 | SOLAR CELL BACK SHEET, MANUFACTURING METHOD THEREOF, AND SOLAR CELL MODULE |
JP5750226B2 (en) * | 2010-01-18 | 2015-07-15 | 富士フイルム株式会社 | Film for solar cell backsheet and manufacturing method thereof |
WO2013146355A1 (en) | 2012-03-29 | 2013-10-03 | 富士フイルム株式会社 | Heat-ray-shielding material and laminated structure |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2360216A (en) * | 1943-06-08 | 1944-10-10 | Eastman Kodak Co | Subbing photographic paper supports |
US2536657A (en) * | 1945-08-06 | 1951-01-02 | Noc Company Di | Drawing material |
BE584451A (en) * | 1958-11-19 | 1900-01-01 | ||
US3227576A (en) * | 1960-05-17 | 1966-01-04 | Du Pont | Drafting film |
US3115420A (en) * | 1961-06-16 | 1963-12-24 | Du Pont | Coated films |
-
1964
- 1964-01-24 US US339849A patent/US3353958A/en not_active Expired - Lifetime
-
1965
- 1965-01-22 BE BE658724A patent/BE658724A/xx unknown
- 1965-01-22 FR FR2978A patent/FR1422579A/en not_active Expired
-
1967
- 1967-09-25 GB GB2785/65A patent/GB1121859A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0019178A2 (en) * | 1979-05-16 | 1980-11-26 | Agfa-Gevaert AG | Process for the preparation of matting layers |
EP0019178A3 (en) * | 1979-05-16 | 1981-05-27 | Agfa-Gevaert Aktiengesellschaft | Process for the preparation of matting layers |
Also Published As
Publication number | Publication date |
---|---|
DE1571113A1 (en) | 1971-01-28 |
US3353958A (en) | 1967-11-21 |
BE658724A (en) | 1965-07-22 |
FR1422579A (en) | 1965-12-24 |
DE1571113B2 (en) | 1975-10-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB1121859A (en) | Improvements relating to drafting films | |
US4199421A (en) | Coating composition and a method for producing a synthetic resin molded product having an abrasion resistant surface | |
US4044176A (en) | Graphic arts and graphic media | |
US4144212A (en) | Air-curing copolymer latices | |
US4013615A (en) | Electrostatic spray coating powder pigment composition and process for producing the same | |
US5208282A (en) | Aqueous synthetic resin formulations | |
US5139882A (en) | Aqueous polyacrylate systems for varnishing plastic surfaces | |
JPS6017104B2 (en) | water resistant photo paper support | |
JPS6324619B2 (en) | ||
JPS63207681A (en) | Recording sheet | |
JPH03207475A (en) | Processing of base using aqueous compound for processing | |
US3666532A (en) | Dimensionally stable matte-surfaced polyester drafting film | |
US3819542A (en) | Method of making high opacity resin porous films and aqueous latex for producing said films | |
US4543269A (en) | Process for producing supports for photographic paper | |
US3804933A (en) | Chemical embossing | |
US4571379A (en) | Photographic polyester supports with copolymer subbing layer | |
US3984584A (en) | Opaque coatings and films produced by the hardening of synthetic resins with light | |
JP2625418B2 (en) | Sublimation type thermal transfer recording system | |
US3896138A (en) | High opacity resin coatings | |
JP2641196B2 (en) | Sublimation type thermal transfer recording system | |
US3823214A (en) | Method of chemical embossing | |
US4118366A (en) | Compositions for the production of opaque coatings by radiation | |
JP2641197B2 (en) | Sublimation type thermal transfer recording system | |
GB1208240A (en) | Coated film elements and coating compositions | |
JP3204462B2 (en) | Manufacturing method of resin for matte paint |