GB1118725A - Emulsion polymerised latexes and their production and use - Google Patents

Emulsion polymerised latexes and their production and use

Info

Publication number
GB1118725A
GB1118725A GB2792265A GB2792265A GB1118725A GB 1118725 A GB1118725 A GB 1118725A GB 2792265 A GB2792265 A GB 2792265A GB 2792265 A GB2792265 A GB 2792265A GB 1118725 A GB1118725 A GB 1118725A
Authority
GB
United Kingdom
Prior art keywords
emulsifier
styrene
maleic anhydride
copolymer
partial ester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2792265A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US380025A external-priority patent/US3396135A/en
Priority claimed from US380082A external-priority patent/US3396049A/en
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1118725A publication Critical patent/GB1118725A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/22—Polyalkenes, e.g. polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F267/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00
    • C08F267/02—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00 on to polymers of acids or salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D135/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least another carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D135/06—Copolymers with vinyl aromatic monomers
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L35/06—Copolymers with vinyl aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

An emulsion polymerized latex is produced by polymerizing an ethylenically unsaturated monomer in the presence, as sole emulsifier, of at least 10% by wt. of a salt of a partial ester of a copolymer of maleic anhydride and a vinylidene aromatic compound. The monomer may be styrene with optionally dibutyl fumarate, ethyl acrylate or up to 60% by wt. of butadiene, or methyl methacrylate. The emulsifier may be of molecular wt. 1000-20,000 and have the repeating units <FORM:1118725/C3/1> <FORM:1118725/C3/2> where groups of Formula I constitute 20-100% of the total groups, R is a C1- 20 organic radical, R1 is H, a C1- 5 alkyl radical, halogen or nitrile group, Ar is a radical of 1 or 2 benzene rings and X is an ammonium (which may be substituted) or an alkali metal ion. The emulsifier may comprise an aq. solution of the 2-butoxyethanol partial ester of a styrene-maleic anhydride copolymer and ammonium hydroxide. The polymerization may be carried out in the presence of an aq. solution of ammonium persulphate and sodium bisulphite as initiator.ALSO:A cellulosic substrate is coated with an emulsion polymerised latex produced by polymerising an ethylenically unsaturated monomer in the presence as sole emulsifier of at least 10% by wt. of a salt of a partial ester of a copolymer of maleic anhydride and a vinylidene aromatic compound. The monomer may be styrene with optionally dibutyl fumerate, ethyl acrylate or up to 60% by wt. of butadiene or methyl methacrylate. The latex may contain a siloxone polymer. The substrate may be a paper cup or plate, or a laminated cellulosic paper substrate.
GB2792265A 1964-07-02 1965-07-01 Emulsion polymerised latexes and their production and use Expired GB1118725A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US38007764A 1964-07-02 1964-07-02
US380025A US3396135A (en) 1964-07-02 1964-07-02 Coating composition containing styrenemaleic anhydride partial ester copolymer as emulsifier
US380082A US3396049A (en) 1964-07-02 1964-07-02 Cellulosic substrates coated with styrene interpolymer latexes

Publications (1)

Publication Number Publication Date
GB1118725A true GB1118725A (en) 1968-07-03

Family

ID=27409475

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2792265A Expired GB1118725A (en) 1964-07-02 1965-07-01 Emulsion polymerised latexes and their production and use

Country Status (1)

Country Link
GB (1) GB1118725A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0215640A2 (en) * 1985-09-19 1987-03-25 James River Graphics Limited Thermal transfer printing paper

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0215640A2 (en) * 1985-09-19 1987-03-25 James River Graphics Limited Thermal transfer printing paper
EP0215640A3 (en) * 1985-09-19 1988-08-31 The Wiggins Teape Group Limited Thermal transfer printing paper
US4803194A (en) * 1985-09-19 1989-02-07 The Wiggins Teape Group Limited Thermal transfer printing paper

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