GB1112888A - Copolymer latices and articles bonded therewith - Google Patents

Copolymer latices and articles bonded therewith

Info

Publication number
GB1112888A
GB1112888A GB28446/65A GB2844665A GB1112888A GB 1112888 A GB1112888 A GB 1112888A GB 28446/65 A GB28446/65 A GB 28446/65A GB 2844665 A GB2844665 A GB 2844665A GB 1112888 A GB1112888 A GB 1112888A
Authority
GB
United Kingdom
Prior art keywords
butadiene
acid
acrylonitrile
styrene
ester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28446/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
International Latex and Chemical Corp
Original Assignee
International Latex and Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by International Latex and Chemical Corp filed Critical International Latex and Chemical Corp
Publication of GB1112888A publication Critical patent/GB1112888A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/942—Polymer derived from nitrile, conjugated diene and aromatic co-monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/911—Emulsifying agents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2738—Coating or impregnation intended to function as an adhesive to solid surfaces subsequently associated therewith

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paper (AREA)

Abstract

A copolymer latex comprises a dispersion of a copolymer prepared by emulsion polymerization in an aqueous acid material of a monomeric material containing from 20 to 90% of monomer of at least one aliphatic conjugated diene, from 0.5 to 20% of at least one copolymerizable partial alkyl ester of an unsaturated polybasic acid or anhydride of the acid, the alkyl group containing 1 or 2 carbon atoms and the balance being from 10 to 75% of at least one monoolefinic monomer other than the ester. The preferred conjugated diene may be butadiene, isoprene,2-3-diemethyl butadiene, piperylene,2-neopentyl butadiene, 2-chlorobutadiene, 2-cyanobutadiene and others. Specified partial esters are the methyl or ethyl monoesters of fumaric, maleic, glutaconic, citraconic, itaconic, presaconic and aconitic acids-the monomethyl ester of itaconic acid being preferred. Preferred monolefinic monomers are nitriles, styrenes, and esters of an aliphatic alcohol containing from 1 to 6 carbon atoms and an acrylic or an alpha-substituted acrylic acid also vinyl naphthalene, vinyl pyridine, vinyl ethers and ketones and vinylidene chloride are also listed. The latex may also contain from 0.5 to 5% of a copolymerizable olefinically unsaturated monocarboxylic acid. The usual emulsifying agents e.g. the sodium salt of ethylene benzene sulphonate, chelating agents e.g. ethylene diamine tetraacetic acid, peroxide type indicators e.g. potassium persulphate and modifiers e.g. 17-dodecyl mercaptan may be present.ALSO:Fibrous articles comprise a unified mass of non-woven fibrous material internally bonded with a unifying composition comprising a copolymer prepared by emulsion polymerisation in an aqueous acid medium of a monomeric material containing from 20 to 90% of at least one aliphatic conjugated diene, from 0.5 to 20% of at least one partial alkyl ester of an unsaturated polybasic acid or anhydride thereof, the alkyl group containing 1 or 2 carbon atoms and the balance being from 10 to 75% of at least one monoolefinic monomer other than the partial ester (see Division C3). The fabrics may be made from fibres such as cotton, rayon, nylon, and polyester as well as applied to unified paper packings e.g. creped masking tape base, rope tape stock, and flow-tensile flatback base. In a typical example (II) sheets of creped masking tape base are saturated with a copolymer latex, squeezed, forced and cured - the copolymers being (a) butadiene/acrylonitrile / monomethyl itaconate (b) butadiene / acrylonitrile / itaconic acid (c) butadiene / acrylonitrile / methacrylic acid (d) butadiene / styrene / monomethyl itaconate (e) butadiene / styrene / itaconic acid (g) butadiene / styrene / methacrylic acid (g) butadiene / acrylonitrile / styrene / with monomethyl itaconate or itaconic acid or methacrylic acid.
GB28446/65A 1964-07-22 1965-07-05 Copolymer latices and articles bonded therewith Expired GB1112888A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US38453664A 1964-07-22 1964-07-22

Publications (1)

Publication Number Publication Date
GB1112888A true GB1112888A (en) 1968-05-08

Family

ID=23517710

Family Applications (1)

Application Number Title Priority Date Filing Date
GB28446/65A Expired GB1112888A (en) 1964-07-22 1965-07-05 Copolymer latices and articles bonded therewith

Country Status (8)

Country Link
US (1) US3422050A (en)
JP (1) JPS5136293B1 (en)
BE (1) BE667259A (en)
DE (1) DE1570118A1 (en)
FR (1) FR1511560A (en)
GB (1) GB1112888A (en)
LU (1) LU49130A1 (en)
NL (1) NL6509511A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998035085A1 (en) * 1995-09-28 1998-08-13 Gencorp Inc. Nonwoven fabric of non-cellulose fibers having improved wet tensile strength
WO2022193837A1 (en) * 2021-03-15 2022-09-22 北京化工大学 Fumarate/conjugated diene copolymer type bio-based rubber, preparation method therefor, and vulcanized rubber product thereof

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6110525A (en) * 1997-09-12 2000-08-29 Pro-Sol, Inc. Coating composition for protecting surfaces and method of using same
EP1731562B1 (en) * 2004-03-31 2010-06-09 Zeon Corporation Composition for dip forming and molding obtained by dip forming
CN112521553B (en) * 2019-09-19 2022-02-01 北京化工大学 Itaconate/styrene/butadiene copolymer, preparation method thereof and rubber composition

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2891039A (en) * 1954-06-05 1959-06-16 Bayer Ag Terpolymers of diolefins with halfesters of maleic acid and a monoolefinic monomer
US2959821A (en) * 1955-02-11 1960-11-15 Bayer Ag Dipping process wherein cross-linking agent is applied in coagulating bath
FR1147579A (en) * 1955-03-24 1957-11-27 Bayer Ag Process for the production of polymerization products
US2947733A (en) * 1957-04-19 1960-08-02 Firestone Tire & Rubber Co Process of curing a rubbery copolymer of a conjugated diene and a carboxylic acid oranhydride with dicyandiamide, and cured product obtained thereby
BE636527A (en) * 1958-08-01
BE634919A (en) * 1962-07-12 1964-01-13
US3300431A (en) * 1963-04-20 1967-01-24 Takeda Chemical Industries Ltd Non-woven fabric and adhesive composition therefor
US3345204A (en) * 1963-06-06 1967-10-03 Johnson & Johnson Process of impregnating an instantaneously wettable paper with a rubber latex
US3259601A (en) * 1963-07-31 1966-07-05 Koppers Co Inc Baked metal primers of ternary butadiene polymer and phosphoric acid
US3321432A (en) * 1963-10-04 1967-05-23 Dow Chemical Co Textile backing agent comprising an aqueous dispersion of a carboxylcontaining copolymer and the reaction product of epichlorohydrin with an alkylene polyamine

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998035085A1 (en) * 1995-09-28 1998-08-13 Gencorp Inc. Nonwoven fabric of non-cellulose fibers having improved wet tensile strength
WO2022193837A1 (en) * 2021-03-15 2022-09-22 北京化工大学 Fumarate/conjugated diene copolymer type bio-based rubber, preparation method therefor, and vulcanized rubber product thereof

Also Published As

Publication number Publication date
LU49130A1 (en) 1965-09-21
FR1511560A (en) 1968-02-02
DE1570118A1 (en) 1970-08-13
JPS5136293B1 (en) 1976-10-07
US3422050A (en) 1969-01-14
NL6509511A (en) 1966-01-24
BE667259A (en) 1966-01-24

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